1,1,1,2-Tetrachloroethane Standard 1,1,1,2-四氯乙烷

CAS 630-20-6 MFCD00000807

化学结构图

630-20-6
SMILES: ClCC(Cl)(Cl)Cl

化学属性

Mol. FormulaC2H2Cl4
Mol. Weight167.84
Refractive index1.4810 to 1.4830
Boiling Point131°C
Density0.7915
Solubility不溶于水,溶于乙醇、乙醚等。

别名和识别编码

Chemical Name1,1,1,2-Tetrachloroethane Standard
Synonym {uni_hamburg} 1,1,1,2-TETRACHLOROETHANE, 1X1ML, MEOH 5 000UG/ML 1,1,1,2-Tetrachlorethan 1,1,1,2-TETRACHLOROETHANE 1'1'1'2-Tetrachlorethan 1,1,1,2-TETRACHLOROETHANE, STANDARD FOR GC 1,1,1,2-tetrachloroethane RCRA waste number U208 R-130a 1,1,1,2-Tetrachlor-ethan 1,1,1,2-四氯乙烷 1,1,1,2,-tetrachlorethane Rcra waste number U208 1,1,1,2-Tetrachloroethane unsym-tetrachloroethane 1,1,1,2-TETRACHLOROETHANE, 1000MG, NEAT (Chloromethyl)trichloromethane Tetrachloroethane 1,1,1,2-tetrachloro-ethan F130a 1,1,1,2-TETRACHLOROETHANE, 1X1ML, MEOH, 200UG/ML NCI-C52459 Ethane, 1,1,1,2-tetrachloro- CH2ClCCl3 1,1,1,2-四氯乙烷 rcrawastenumberu208 不對稱四氯乙烷 freon130a 1,1,2,2-TETRACHLOROETHANE, 1000MG, NEAT 1,1,1,2-tetrachloro-ethane F 130a 偏四氯乙烷 HCC130a ethane,1,1,1,2-tetrachloro- HCC 130a freon 130a TCA
MDL NumberMFCD00000807
CAS Number630-20-6
PubChem Substance ID12418
EC Number211-135-1
Beilstein Registry Number1,86
Reaxys-RN1733216
Chemical Name Translation1,1,1,2-四氯乙烷
LabNetwork Molecule IDLN01743686
InChIInChI=1S/C2H2Cl4/c3-1-2(4,5)6/h1H2
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分类

  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chloro, Chromatography, Environmental Standards, Fumigants, Halogenated, Insecticides, Pesticides, Pesticides & Metabolites, T, T-Z, TA - TE, Volatiles/ Semivolatiles
  • {SNA} Alpha Sort, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, T-Z, Volatiles/ Semivolatiles
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards,

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/20A Title: Vapor Pressure and Antoine Coeffic

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H332
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P308+P313
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P310
Signal word Danger
RTECSKI8450000
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24 Avoid contact with skin 避免皮肤接触;
Hazard Codes Xn Xn,T,F
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition 0-10 储存温度2-8℃ 0-10°C Refrigerator
UN Number 2810 UN 2810 6.1/PG 3 1230
Packing GroupIII
Hazard Class6.1
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2100 ppm/4H
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 35,593,1974

{hazard_com

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 35,593,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 35,593,1974

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 670 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 35,593,1974

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 158 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 200 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 200 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 125 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 201,401,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 15,101,1987

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 250 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 201,401,1988

其他信息

  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 挥发性有机化合物(VOCs)单组分标准液 US EPA方法:502.2,524.2,8021,8021A,8021B,624,8240B,8260B
  • 类别:有毒物质
  • 1,1,1,2-四氯乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0695 1,1,1,2-四氯乙烷 1,1,1,2-Tetrachloroethane 10G 489元 2014/06/02 S0647 1,1,1,2-四氯乙烷(1mg/ml的甲醇溶液)[用于水分析] 1,1,1,2-Tetrachloroethane (1mg/ml in Methanol) [for Water Analysis] 1ML 240元
  • 毒性分级:中毒
  • 可燃性危险特性:在特殊条件下可燃; 火场产生有毒氯化物辛辣刺激烟雾; 水解生成盐酸
  • 急性毒性:口服- 大鼠 LD50: 670毫克/ 公斤; 口服- 小鼠 LD50: 1500 毫克/ 公斤
  • MOL 文件:630-20-6.mol
  • 图谱信息:1,1,1,2-四氯乙烷(630-20-6)质谱(MS) 1,1,1,2-四氯乙烷(630-20-6)红外图谱(IR1) 1,1,1,2-四氯乙烷(630-20-6)Raman光谱 1,1,1,2-四氯乙烷(630-20-6)核磁图( 13 CNMR) 1,1,1,2-四氯乙烷(630-20-6)核磁图( 1 HNMR)
  • MSDS 信息:偏四氯乙烷(630-20-6).msds
  • TCI Shanghai:1,1,1,2-四氯乙烷(1mg/ml的甲醇溶液)[用于水分析] 1,1,1,2-Tetrachloroethane (1mg/ml in Methanol) [for Water Analysis](630-20-6)
  • 挥发性有机化合物(VOCs)单组分标准液
  • 灭火剂:干粉、泡沫、砂土
  • 刺激数据:皮肤-兔 500 毫克/24小时 阳性; 眼睛- 兔子 100 毫克 重度
  • 外观性质:无色、有似氯仿气味的液体。
  • Sigma Aldrich:630-20-6(sigmaaldrich)

系列性分类


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