Chloromethyltrimethylsilane 氯甲基三甲基硅烷

CAS 2344-80-1 MFCD00000878

化学结构图

2344-80-1
SMILES: C[Si](C)(C)CCl

化学属性

Mol. FormulaC4H11ClSi
Mol. Weight122.67
Density0.879
Refractive index1.4160 to 1.4180
Flash Point-
TSCAYes
Boiling Point
Vapor Pressure~25 mmHg ( 20 °C)
Solubility溶于部分有机溶剂。
Melting PointNo Data Available
Stability对湿度敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name(Chloromethyl)trimethylsilane
Synonym (CH3)3SiCH2Cl (Chlormethyl)-trimethylsilan (Chlormethyl)trimethylsilan (Chloromethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number-
CAS Number2344-80-1
EC Number219-058-5
Beilstein Registry Number906705
PubChem Substance ID75361
Reaxys-RN906705
Chemical Name Translation氯甲基三甲基硅烷
InChIKeyOOCUOKHIVGWCTJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01268178
InChIInChI=1S/C4H11ClSi/c1-6(2,3)4-5/h4H2,1-3H3
Canonical SMILES-
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分类

  • {SNA} 25mL Sure/Seal Reagents, Chemical Synthesis, Organometallic Reagents, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Beilstein:4(3)1844
  • For a review of the chemistry of chloromethyltrimethylsilane, see: Synthesis, 717 (1985).
  • Metallation gives useful precursors of various organosilicon compounds. For use of the Grignard in the olefination of ketones, see: J. Org. Chem., 39, 3264 (1974); 52, 281 (1987). For Ni-catalyzed reaction of the Grignard with allylic dithioacetals, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998); for an example with reaction scheme, see trans-Cinnamaldehyde, A14689.
  • Short: III/20a
  • Short: III/35F
  • Treatment with s-BuLi at -78o gives ɑ-lithio-ɑ-chloromethyltrimethylsilane which reacts with aldehydes and ketones to give ɑß-epoxy silanes, readily hydrolyzed to homologated aldehydes: Tetrahedron, 39, 867 (1983):
  • {} {

安全信息

Packing GroupII
UN Number 1993
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S29 Do not empty into drains 不要排入下水道；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S37 Wear suitable gloves 戴适当手套；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 4 4°C, Inert atmosphere Flammables area Moisture Sensitive 对湿度敏感
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+
  • P304+P340
  • P304+P340+P310
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,Xi,C
Hazard Class3/8
Warnings 危化品目录(2015)
Restrict -

其他信息

  • 海关编码:29310095
  • TCI Shanghai:(氯甲基)三甲基硅烷 (Chloromethyl)trimethylsilane,>;98.0%(GC)(2344-80-1)
  • Hazard Note:Irritant/Highly Flammable
  • 检测方法:GC
  • 存储注意事项:湿度敏感
  • 外观性质:无色液体。
  • Sigma Aldrich:2344-80-1(sigmaaldrich)
  • 不溶于水。
  • 氯甲基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0862 (氯甲基)三甲基硅烷 (Chloromethyl)trimethylsilane 25ML 536元 2014/06/02 C0862 (氯甲基)三甲基硅烷 (Chloromethyl)trimethylsilane 250ML 3220元 2010/06/21 194761000 氯甲基三甲基硅烷 Chloromethyltrimethylsilane 98+% 100 GR 3768元
  • 图谱信息:氯甲基三甲基硅烷(2344-80-1)质谱(MS) 氯甲基三甲基硅烷(2344-80-1)核磁图( 13 CNMR) 氯甲基三甲基硅烷(2344-80-1)红外图谱(IR1) 氯甲基三甲基硅烷(2344-80-1)核磁图( 1 HNMR)
  • F:10-21
  • 蒸气压:~25 mm Hg ( 20 °C)
  • Alfa Aesar:（氯甲基）三甲基硅烷,98% (Chloromethyl)trimethylsilane, 98%(2344-80-1)
  • Acros Organics:氯甲基三甲基硅烷 Chloromethyltrimethylsilane, 98+%(2344-80-1)
  • MSDS 信息:氯甲基三甲硅烷(2344-80-1).msds
  • 下游产品:三甲基硅烷化重氮甲烷 --> N-(甲氧甲基)-N-(三甲基硅甲基)苄胺
  • 敏感性:Moisture Sensitive
  • MOL 文件:2344-80-1.mol
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organolithium 有机锂
  4. Others Organosilicon 其他有机硅

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