2-Iodobenzoylchloride 2-碘苯甲酰氯

CAS 609-67-6 MFCD00001040

化学结构图

609-67-6
SMILES: O=C(Cl)c1ccccc1I

化学属性

Mol. FormulaC7H4ClIO
Mol. Weight266.46 g/mol
Density1.932
Boiling Point105-106
Melting Point27-31
Flash Point>110°(230°F)
TSCAYes
Appearance 无色针状结晶。熔点35-38℃,沸点159℃(3.6kPa),135℃(2.53kPa),105-106℃(0.133kPa)。溶于乙醇、乙醚和苯。遇水分解。

别名和识别编码

Chemical Name2-Iodobenzoylchloride
CAS Number609-67-6
EC Number210-196-1
Beilstein Registry Number2042672
MDL NumberMFCD00001040
PubChem Substance ID87571755
Synonym 2-IODOBENZOYL CHLORIDE 2-Iodobenzoic acid chloride 2-Iodobenzoyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN2042672
Chemical Name Translation2-碘苯甲酰氯
InChIKeyMVIVDSWUOGNODP-UHFFFAOYSA-N
LabNetwork Molecule IDLN00198992
InChIInChI=1S/C7H4ClIO/c8-7(10)5-3-1-2-4-6(5)9/h1-4H
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupII
UN Number 3261 UN 3261 8/PG 2
Storage condition Moisture & Light Sensitive
Hazard Codes 8 C
Hazard Class8

其他信息

  • TCI Shanghai:2-碘苯甲酰氯 2-Iodobenzoyl Chloride,>;95.0%(GC)(T)(609-67-6)
  • 用途一:用于有机合成。该品有腐蚀性,有毒。
  • 方法一:由邻碘苯甲酸与氯化亚砜反应而得。将邻碘苯甲酸与新蒸馏的氯化亚砜按摩尔比1:1.3混合,在水浴上加热,搅拌反应1h,至不再逸出二氧化硫和氯化氢气体为止。常压下蒸出过量的氯化亚砜,然后减压蒸馏,收集133-135℃(2.53kPa)馏分,即得邻碘苯甲酰氯。收率94%。
  • 上游原料:二氧化硫 --> 2-碘苯甲酸
  • Acros Organics:2-碘苯甲酰氯 2-Iodobenzoyl chloride, 98+%(609-67-6)
  • 敏感性:Moisture & Light Sensitive
  • Sigma Aldrich:609-67-6(sigmaaldrich)
  • Alfa Aesar:2-碘苯甲酰氯,98% 2-Iodobenzoyl chloride, 98%(609-67-6)
  • MOL 文件:609-67-6.mol
  • F:21-19
  • 图谱信息:邻碘苯甲酰氯 (609-67-6)红外图谱(IR1) 邻碘苯甲酰氯 (609-67-6)质谱(MS) 邻碘苯甲酰氯 (609-67-6)核磁图( 1 HNMR)

系列性分类


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