1-Iodobutane 1-碘丁烷

CAS 542-69-8 MFCD00001098

化学结构图

542-69-8
SMILES: CCCCI

化学属性

Mol. FormulaC4 H9 I
Mol. Weight184.02
Refractive index1.4970 to 1.5010
Vapor Density~5 (vs air)
Boiling Point
Density1.617
Melting PointNo Data Available
Flash Point-
TSCAYes
Solubility不溶于水,溶于醇、醚。
Stability对光敏感, 对空气敏感

别名和识别编码

Chemical Name1-Iodobutane
Synonym 1-BUTYLIODIDE 1-Butyljodid 1-IODOBUTANE 1-IODOBUTANE, STAB. 1-Iodbutan 1-Iodobutane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number-
CAS Number542-69-8
PubChem Substance ID10962
EC Number208-824-4
Beilstein Registry Number1,123
Merck Number1573
Chemical Name Translation1-碘丁烷
Reaxys-RN1420755
Wiswesser Line NotationI4
LabNetwork Molecule IDLN00222867
InChIInChI=1S/C4H9I/c1-2-3-4-5/h2-4H2,1H3
Canonical SMILES-
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂。有机合成。

相关文献及参考

  • Short: II/25C
  • Short: II/27B
  • Merck:14,1573 Beilstein:1,123
  • Short: II/14a
  • Merck:14,1573

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEK4400000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupIII
UN Number 1993
Risk Statements
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Storage condition +4°C 4 4°C 4℃ Flammables area Light Sensitive 对光敏感,密封避光保存。
Hazard Codes
Hazard Class3
Warnings 危化品目录(2015)
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 480 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,1411,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 101 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6100 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 692 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

Restrict 危险品

其他信息

  • 海关编码:29033080
  • 毒性分级:中毒
  • 急性毒性:腹腔- 大鼠 LD50: 692 毫克/ 公斤; 腹腔- 小鼠 LD50: 101 毫克/ 公斤
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • Hazard Note:Harmful
  • 敏感性:Light Sensitive
  • MSDS 信息:碘代正丁烷(542-69-8).msds
  • 类别:易燃液体
  • 蒸气密度:~5 (vs air)
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒碘化物烟雾
  • 用途二:用于有机合成或用作分析试剂、溶剂和杀菌剂。
  • 图谱信息:碘丁烷(542-69-8)红外图谱(IR2) 碘丁烷(542-69-8)红外图谱(IR1) 碘丁烷(542-69-8)质谱(MS) 碘丁烷(542-69-8)核磁图( 13 CNMR) 碘丁烷(542-69-8)核磁图( 1 HNMR)
  • Sigma Aldrich:542-69-8(sigmaaldrich)
  • 下游产品:正丁基二(1-金刚烷基)膦 --> 四丁基硫酸氢铵 --> 光学活性硫代乙酸胺 --> 1-丁烷磺酸钠
  • 方法一:由正丁醇与碘在磷存在下反应而得。将赤磷与正丁醇混合,加热使其微微回流,缓缓加入碘。加完后继续回流4h,蒸馏,得粗品。依次用水、浓盐酸、水、10%碳酸钠溶液和含少量硫代硫酸钠和水洗涤。然后以无水氯化钙干燥,蒸馏,收集129-131℃馏分,即为1-碘丁烷。收率90%。
  • 用途一:用作溶剂
  • 碘丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80025826 碘代正丁烷 100ml 223元 2011/04/16 I0055 1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip) 25G 180元 2011/04/16 I0055 1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip) 500G 1480元
  • Acros Organics:1-碘丁烷 1-Iodobutane, stabilized, 98%(542-69-8)
  • TCI Shanghai:1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip),>;98.0%(GC)(542-69-8)
  • Alfa Aesar:1-碘丁烷,99%,stab.withcopper 1-Iodobutane, 99%, stab. with copper(542-69-8)
  • 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
  • MOL 文件:542-69-8.mol
  • F:8
  • 外观性质:无色液体。
  • 能与乙醇和乙醚混溶,几乎不溶于水,见光或久置变色。易燃。有刺激性。

系列性分类