1-(Methylamino)anthraquinone 1-(甲氨基)蒽醌

CAS 82-38-2 MFCD00001197

化学结构图

82-38-2
SMILES: CNc1cccc2c1C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC15H11NO2
Mol. Weight237.26
Melting Point170-172 °C(lit.)
Appearance 红色粉末。溶于丙酮、乙醇、乙二醇乙醚、亚麻仁油。微溶于苯、四氯化碳。不溶于斯陶特溶剂。于浓硫酸中呈棕色,稀释后转呈暗橙色。

别名和识别编码

Chemical Name1-(Methylamino)anthraquinone
Synonym 1-(甲氨基)蒽醌 MACROLEX RED GS 烟雾红 9,10-Anthracenedione, 1-(methylamino)- { Macrolex Red G 1-甲基氨基蒽醌 abcolpinkr Solvent Red 111 Kayaset Red G 1-(methylamino)-9,10-anthracenedione 1-(methylamino)-anthraquinon Duranol Red GN 溶剂红GS C.I. Solvent Red 111 分散红 9 1-(N-Methylamino)-9,10-anthraquinone 1-(Methylamino)-9,10-anthraquinone 1-(Methylamino)anthraquinone 1-(N-Methylamino)anthraquinone 1-(Methylamino)anthra-9,10-quinone {hazard_c Celanthrene Red Y 透明红GS {uni_hamburg C.I. 60505 CI NO 60505 1-甲胺基蒽醌 1-Methylamino-anthrachinon 1-(methylamino)-10-anthracenedione Waxo N-Methyl-1-anthraquinonylamine {Chemical Oil Red ZMG Macro-lex Red G C.I. Disperse Red 9 Orient Oil Red 330 1-(Methylamino)anthraquinone; 1-(N- Waxoline Red MAA {Che α-Methylaminoanthraquinone 1-Methylaminoanthraquinone AMAPLAST RED AAP Smoke Red M 1-甲氨基蒽醌 Supracet Pink R Anthraquinone, 1-(methylamino)- 1-N-methylamino anthraquinone 1-(Methylamino)-9,10-anthracenedione Diacelliton Fast Pink R 1-Methylamineanthraquinone Waxoline Red MP Serilene Fast Pink BT Calco Oil Red ZMQ 1-(methylamino)anthraquinone Methane quinone 9,10-Anthracenedione,1-(methylamino)- 1-(METHYLAMINO)ANTHRAQUI 10-Anthracenedione,1-(methylamino
MDL NumberMFCD00001197
CAS Number82-38-2
EC Number201-417-2
PubChem Substance ID87572340
Reaxys-RN1973186
Beilstein Registry Number14(3)408
Chemical Name Translation1-(甲氨基)蒽醌
InChIKeySVTDYSXXLJYUTM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00193899
InChIInChI=1S/C15H11NO2/c1-16-12-8-4-7-11-13(12)15(18)10-6-3-2-5-9(10)14(11)17/h2-8,16H,1H3
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; ketone; 1fragment
  • {SNA} M, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • {SNA} Hematology and Histology, M, Stains & Dyes, A to Z, Stains and Dyes
  • {Chemicalbook} 染料: 溶剂染料: 溶剂染料

相关文献及参考

  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Hazard Codes Xi
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSCB0536600
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,499,1983

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : >8 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,499,1983

其他信息

  • MOL 文件:82-38-2.mol
  • TCI Shanghai:1-(甲氨基)蒽醌 1-(Methylamino)anthraquinone,>;97.0%(N)(82-38-2)
  • 方法一:以蒽醌-1-磺酸 (或 1-氯蒽醌、1-硝基蒽醌) 和甲胺为原料,将两者缩合得产物。经过滤、干燥得成品。
  • Sigma Aldrich:82-38-2(sigmaaldrich)
  • 用途二:用于涤纶及混纺织物的染色
  • 分散红 9价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0255 1-(甲氨基)蒽醌 1-(Methylamino)anthraquinone 500G 3780元 2014/06/02 M0255 1-(甲氨基)蒽醌 1-(Methylamino)anthraquinone 25G 417元
  • 方法二:向4L压热釜中加入399g(1.29mol)蒽醌-1-磺酸钠、45g(0.43mol)氯酸钠、780g(6.25mol)25%甲胺水溶液和1.2L水,搅拌加热,在130-135℃反应12h。冷却,过滤,热水洗涤,干燥,得180-199g1-甲氨基蒽醌,收率59-65%。
  • 图谱信息:分散红 9(82-38-2)核磁图( 1 HNMR) 分散红 9(82-38-2)红外图谱(IR1) 分散红 9(82-38-2)核磁图( 13 CNMR) 分散红 9(82-38-2)质谱(MS)
  • 上游原料:一甲胺 --> 1-氯蒽醌 --> 1-蒽醌磺酸 --> 蒽醌-1-磺酸钠
  • 用途三:用作染料中间体
  • 用途四:透明红 GS 用于各类塑料、油脂、蜡、油墨等的着色,也是重要的合成染料、有机颜料的中间体。
  • 用途一:用于聚氯乙烯及醋酸纤维的染色

系列性分类


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