1,4-Diaminoanthraquinone 1,4-二氨基蒽醌

CAS 128-95-0 MFCD00001224

化学结构图

128-95-0
SMILES: Nc1ccc(N)c2c1C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC14H10N2O2
Mol. Weight238.24
Melting Point265-269 °C
Density1.422
TSCAYes
Flash Point340 °C
Appearance 1,4-二氨基蒽醌(128-95-0)为深紫色针状结晶。熔点268℃。溶于乙醇、苯和硝基苯,微溶于水和热乙酸。
Solubility溶于苯、吡啶、硝基苯、苯胺,稍溶于热醋酸、乙醇。
Boiling Point380.84 °C at 760 mmHg

别名和识别编码

Chemical Name1,4-Diaminoanthraquinone
CAS Number128-95-0
Synonym 1,4-Diaminoanthraquinone {LY} 1,4-Diaminoanthraquinone 1,4-diaminoanthraquinone {} {LY} 1,4-Diaminoanthraquinone {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001224
Beilstein Registry Number14(4)458
EC Number204-922-6
Reaxys-RN2216556
PubChem Substance ID31420
Chemical Name Translation1,4-二氨基蒽醌
Wiswesser Line NotationL C666 BV IVJ DZ GZ
InChIInChI=1S/C14H10N2O2/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6H,15-16H2
LabNetwork Molecule IDLN00223623
Canonical SMILESC1=CC=C2C(=C1)C(=O)C3=C(C=CC(=C3C2=O)N)N
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; ketone; 1fragment
  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
  • {SNA} Amine Monomers, Monomers, Polymer Science, Primary Amines, 材料科学

产品应用

  • An anthraquinone derivative that is a potent and selective protein kinase CK1 delta inhibitor. Studies suggest that it has potential solar cell applications. Used in studies as a potential competitiv

相关文献及参考

  • Cozza, G. et al.: Bioorg. Med. Chem. Lett., 18, 5672 (2008); Brovelli, F. et al.: Polym. Bull., 58, 521 (2007); Brinkworth, R.I. et al.: Biochim. Biophys. Acta, Prot. Struct. Mol. Enzymol., 1253, 5 (1
  • Beil. 14 ,IV,458
  • FT-IR 1 (1), 90:C / RegBook 1 (2), 1691:L / Structure Index 1 , 268:D:7
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSCB6300000
WGK Germany2
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P333+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5790 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,121,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(12),27,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 12800 ug/L
REFERENCE :
   HEREAY Hereditas (Lund, Sweden).  (Gjoerloffsgatan 121, S-261 34 Landskrona,
   Sweden)  V.1-    1947-  Volume(issue)/page/year: 99,209,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,203,1976

Storage condition

其他信息

  • 用途三:用于涤纶的染色
  • 方法一:由对苯二酚与苯酐缩合得1,4-二羟基蒽醌,然后氨化得1,4-二氨基蒽醌隐色体,再以发烟硫酸氧化而得。原料消耗定额:苯酐2131kg/t、对苯二酚887kg/t、氨水(20%)10788kg/t、发烟硫酸3580kg/t。
  • TCI Shanghai:1,4-二氨基蒽醌 1,4-Diaminoanthraquinone,>;97.0%(N)(128-95-0)
  • 用途一:用作合成染料的中间体
  • 1,4-二氨基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0075 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 25G 967元 2014/06/02 D0075 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 1G 176元 2014/06/02 D3539 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 500G 1770元
  • Alfa Aesar:1,4-二氨基蒽醌,tech.90% 1,4-Diaminoanthraquinone, tech. 90%(128-95-0)
  • MOL 文件:128-95-0.mol
  • 用途二:用作染料中间体,广泛用于还原灰BG、分散翠蓝HBF及酸性染料等
  • 下游产品:兰雪醌 --> 还原黑 27 --> 分散紫 H-FRL --> 还原棕 1 --> 分散紫 26 --> 还原棕BR --> 活性分散蓝 R --> 分散紫 28 --> 分散蓝 60 --> 碱性蓝 47
  • 上游原料:氢氧化钠 --> 碳酸氢钠 --> 发烟硫酸 --> 硫磺 --> 1,4-苯二酚 --> 4-硝基苯胺 --> 1,4-二羟基蒽醌 --> 2,4-二氨基甲苯
  • 用途四:蒽醌还原染料、分散染料、酸性染料和中间体。本身为分散染料紫。
  • Sigma Aldrich:128-95-0(sigmaaldrich)

系列性分类


相关产品推荐