Cyclopropanecarbonyl Chloride 环丙甲酰氯
CAS 4023-34-1 MFCD00001277
化学结构图
SMILES: O=C(Cl)C1CC1
化学属性
| Mol. Formula | C4H5ClO |
|---|---|
| Mol. Weight | 104.53 |
| Density | 1.15 |
| Refractive index | 1.4510 to 1.4540 |
| Boiling Point | 119 |
| Flash Point | 23°C(lit.) |
| TSCA | Yes |
| Solubility | 分解 |
| Appearance | 1.4520，相对密度 1.152，f.p.23℃，溶于醚、氯仿和苯。 20 D 本品为无色液体，有刺激味，n |
别名和识别编码
| Chemical Name | Cyclopropanecarbonyl Chloride |
|---|---|
| CAS Number | 4023-34-1 |
| Alfabeta Name | CYCLOPROPANECARBOXYLICACIDCHLORIDE |
| MDL Number | MFCD00001277 |
| Synonym | CPCCI CYCLOPROPANECARBONYL CHLORIDE CYCLOPROPANECARBOXYLIC ACID CHLORIDE CYCLOPROPYLCARBOXYL CHLORIDE Cyclopropancarbonsäurechlorid Cyclopropanecarbonyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalb {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} cyclopropylcarbonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} cyclopropionyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} cyclopropanecarbonyl chloride |
| EC Number | 223-684-4 |
| Beilstein Registry Number | 471286 |
| PubChem Substance ID | 87566092 |
| Chemical Name Translation | 环丙甲酰氯 |
| Reaxys-RN | 471286 |
| InChIKey | ZOOSILUVXHVRJE-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00237940 |
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分类
- {uni_hamburg} no charge; carbocycle; alicycle; 3ring; carbonyl chloride; 1fragment
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
- {Chemicalbook} 农药中间体: 植物生长调节剂中间体
相关文献及参考
- Short: II/24C Title: Molecular Constants mostly from Micr
- Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
- Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S8 Keep container dry 保持容器干燥；
- R10 Flammable 易燃
- R25 Toxic if swallowed 吞咽有毒
- R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
其他信息
- MOL 文件:4023-34-1.mol
- 下游产品:甲氰菊酯
- 海关编码:29162000
- 环丙基甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1059 环丙基甲酰氯 Cyclopropanecarbonyl Chloride 25G 495元 2014/06/02 C1059 环丙基甲酰氯 Cyclopropanecarbonyl Chloride 500G 3530元 2010/06/21 111630250 环丙基甲酰氯 Cyclopropanecarboxylic acid chloride 98% 25 GR 671元
- 方法一:其制备方法是将环丙烷羧酸与氯化亚砜在60℃左右反应4h，蒸去多余的氯化亚砜，再蒸出产品。
- Sigma Aldrich:4023-34-1(sigmaaldrich)
- MSDS 信息:Cyclopropanecarbonyl chloride(4023-34-1).msds
- 上游原料:环丙甲酸
- 用途二:环丙烷甲酰氯是植物生长调节剂抗倒酯的中间体。
- F:10-21
- TCI Shanghai:环丙基甲酰氯 Cyclopropanecarbonyl Chloride,>;97.0%(T)(4023-34-1)
- 敏感性:Moisture Sensitive
- Alfa Aesar:环丙甲酰氯,98% Cyclopropanecarbonyl chloride, 98%(4023-34-1)
- 用途一:用作医药及农药中间体
- Acros Organics:环丙烷甲酰氯 Cyclopropanecarboxylic acid chloride, 98%(4023-34-1)
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