Cyclopentadienylmanganese(I) Tricarbonyl 三羰基环戊二烯合锰

CAS 12079-65-1 MFCD00001440

化学结构图

12079-65-1
SMILES: [Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1 |^1:7,8,9,10,11|

化学属性

TSCAYes
Mol. FormulaC5H5Mn(CO)3
Mol. Weight204
Appearance yellow xtl.
Stabilityair sensitive
Melting Point77°C

别名和识别编码

Chemical NameCyclopentadienylmanganese(I) Tricarbonyl
PubChem Substance ID24857312
EC Number235-142-4
Synonym Cyclopentadienyltricarbonylmanganese; Cymantrene; Manganese cyclopentadienyltricarbonyl Cyclopentadienylmangantricarbonyl Manganese cyclopentadienyltricarbonyl Manganese, tricarbonyl(η(5)-2,4-cyclopentadien-1-yl)- Manganese cyclopentadienyl tricarbonyl h5-Cyclopentadienylmanganese tricarbonyl Cyclopentadienylmanganese tricarbonyl Tricarbonylcyclopentadienylmanganese η5-Cyclopentadienylmanganese tricarbonyl Tricarbonyl(η5-2,4-cyclopentadien-1-yl)mangan Cymantrene Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- Cyklopentadientrikarbonylmanganium Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)- Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- p-Cyclopentadienylmanganese tricarbonyl Manganese, tricarbonyl-p-cyclopentadienyl- tricarbonyl(η-cyclopentadienyl)manganese 三羰基环戊二烯锰(I) Cyclopentadienyl-p-tricarbonylmanganese Manganese, tricarbonyl-pi-cyclopentadienyl- Tricarbonyl(η5-cyclopentadienyl)manganese(I) Tricarbonyl(h5-cyclopentadienyl)manganese Tricarbonyl-p-cyclopentadienylmanganese Cyclopentadienyl-manganese-tricarbonyl tricarbonyl(η cyclopentadienyl)manganese Tricarbonyl(η5-2,4-cyclopentadien-1-yl)manganese Cyclopentadienyltricarbonylmanganese
Chemical Name Translation三羰基环戊二烯合锰
Wiswesser Line NotationL5J A-MN-VHVHVH
MDL NumberMFCD00001440
CAS Number12079-65-1
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分类

  • {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; metal carbonyl; 1fragment; zwitterion
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • Beil. 16 ,IV,1777
  • Corp MSDS 1 (1), 983:A / FT-IR 2 (3), 4582:D / FT-NMR 1 (3), 779:B / RegBook 1 (2), 3135:C / Sax 6 , 842 / Structure Index 1 , 495:D:7
  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic

安全信息

RTECSOO9720000
WGK Germany3
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P310
Hazard statements
  • H300 Fatal if swallowed 吞食致命
Hazard Codes T+
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
UN Number UN3466
Risk Statements
  • R28 Very toxic if swallowed 吞咽极毒
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
Storage condition Air Sensitive
Packing GroupII
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 710 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#11285

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 14 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 34,341,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 22 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 34,341,1985

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/m3/2H
TOXIC EFFECTS :
   Vascular - BP lowering not characterized in autonomic section
   Blood - hemorrhage
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   30(4-6),40,1965

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