Cyclohexylbenzene 环己基苯

CAS 827-52-1 MFCD00001451

化学结构图

827-52-1
SMILES: c1ccc(C2CCCCC2)cc1

化学属性

Mol. FormulaC12H16
Mol. Weight160.26
Refractive index1.5240 to 1.5270
Boiling Point239-240°C at 760 mmHg
Density0.95
Melting Point4-7°C
Flash Point98.89°C
TSCAYes
Solubility不溶

别名和识别编码

Chemical NameCyclohexylbenzene
Synonym Cyclohexylbenzene {LY} Cyclohexylbenzene {} {LY} Cyclohexylbenzene {} {} {LY} Cyclohexylbenzene {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexylbenzene {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001451
CAS Number827-52-1
PubChem Substance ID87565615
EC Number212-572-0
Beilstein Registry Number1906803
Chemical Name Translation环己基苯
Reaxys-RN1906803
Wiswesser Line NotationL6TJ AR
InChIKeyIGARGHRYKHJQSM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226747
Canonical SMILESC1(C2CCCCC2)=CC=CC=C1
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分类

  • {SNA} Arenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; alicycle; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Beilstein:5,503
  • Short: IV/18B
  • Short: II/5
  • Short: IV/1a
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCZ1330000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P331
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 3082 UN3082
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Hazard Codes 9
Hazard Class9
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 67 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Skin and Appendages - hair
REFERENCE :
   LIFSAK Life Sciences.  (Pergamon Press Inc., Maxwell House, Fairview Park,
   Elmsford, NY 10523) V.1-8, 1962-69; V.14-    1974- Volume(issue)/page/year:
   31,803,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 248 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Skin and Appendages - hair
REFERENCE :
   LIFSAK Life Sciences.  (Pergamon Press Inc., Maxwell House, Fairview Park,
   Elmsford, NY 10523) V.1-8, 1962-69; V.14-    1974- Volume(issue)/page/year:
   31,803,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >7940 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0545758

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZRAQ "Toxicology and Biochemistry of Aromatic Hydrocarbons," Gerarde, H.,
   New York, Elsevier, 1960  Volume(issue)/p

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:环己基苯(827-52-1)红外图谱(IR1) 环己基苯(827-52-1)质谱(MS) 环己基苯(827-52-1)核磁图( 1 HNMR) 环己基苯(827-52-1)Raman光谱 环己基苯(827-52-1)核磁图( 13 CNMR)
  • 毒性分级:中毒
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃;燃烧排放刺激烟雾
  • 用途二:用作高沸点溶剂,渗透剂,有机合成中间体。
  • 类别:易燃液体
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂分开存放
  • 不溶于水
  • Alfa Aesar:环己基苯,98% Cyclohexylbenzene, 98%(827-52-1)
  • 外观性质:无色油状液体, 有芳香气味。
  • TCI Shanghai:环己基苯 Phenylcyclohexane,>;97.0%(GC)(827-52-1)
  • Sigma Aldrich:827-52-1(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50: 3700 毫克/ 公斤; 口服- 小鼠 LD50: 2800 毫克/ 公斤
  • 环己基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010377 环己基苯 100ml 188元 2011/04/16 C0496 苯基环己烷 Phenylcyclohexane 500ML 2280元 2011/04/16 C0496 苯基环己烷 Phenylcyclohexane 25ML 245元
  • 方法一:在激烈搅拌下,将新蒸馏的环己烯滴加入苯和硫酸的混合物中,温度保持在15±5℃,约0.5-1h加完,加完后,继续保温反应1h。分去硫酸层,油层依次用水、碱液及水洗涤,分馏,先馏出未反应的苯,然后收集230-260℃馏分,并重新分馏收集正沸点馏分,得产品环己基苯。
  • 刺激数据:皮肤- 兔子 500 毫克/ 24小时 中度
  • Acros Organics:Cyclohexylbenzene(827-52-1)
  • MOL 文件:827-52-1.mol
  • MSDS 信息:环己基苯(827-52-1).msds
  • 下游产品:酸性红 3B
  • 用途一:用作高沸点溶剂和渗透剂,也用于有机合成
  • 上游原料:环己烯
  • 灭火剂:泡沫、二氧化碳、干粉、砂土

系列性分类