2-Hydroxy-1,4-Naphthoquinone 2-羟基-1,4-萘醌

CAS 83-72-7 MFCD00001678

化学结构图

83-72-7
SMILES: O=C1C=C(O)C(=O)c2ccccc21

化学属性

Mol. FormulaC10H6O3
Mol. Weight174.16
Density1.422
Melting Point192-195
TSCAYes
Solubility2 G/L (20 ºC)
Appearance 亮黄色棱状结晶。熔点195-196℃(分解)。溶于冰醋酸。

别名和识别编码

Chemical Name2-Hydroxy-1,4-Naphthoquinone
Synonym 2-HYDROXY-P-NAPHTHOQUINONE 2-Hydroxy-1,4-naphoquinone 2-Hydroxy-p-naphthochinon 2-hydroxy-1,4-naphthoquinone 2-hydroxy-4-naphthalenedione 2-hydroxynaphthoquinone 2-羟基-1,4-萘二酮 C.I. 75480; 2-Hydroxy-p-naphthoquinone Flower of Paradise Henna LAWSONE Mendi NATURAL ORANGE 6 NQ-2-OH NSC 8625 Natural Orange 6 c.i.naturalorange6 henna dye lawsone lawsone, sodium salt lawsonin sodium lawsonate 劳松黄
CAS Number83-72-7
EC Number201-496-3
Beilstein Registry Number8,300
MDL NumberMFCD00001678
Merck Number5393
PubChem Substance ID6755
Reaxys-RN1565260
Chemical Name Translation2-羟基-1,4-萘醌
Wiswesser Line NotationL66 BV EVJ CQ
LabNetwork Molecule IDLN00871952
InChIInChI=1S/C10H6O3/c11-8-5-9(12)10(13)7-4-2-1-3-6(7)8/h1-5,11H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; ketone; alcohol; 1fragment
  • {SNA} G-H-I, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes
  • {SNA} G-H-I, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学

产品应用

  • An antimicrobial antioxidant dye isolated from Henna.

相关文献及参考

  • Short: III/35D4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 4: Natural Products Author: Dobhal, M.P. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D4 Year: 2006 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-29732-1 ISBN: 3-540-29732-4 Internet Resource: DOI:10.1007/b13179 RefComment: VIII, 417 p., 1925 illus., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://e

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36 Irritating to eyes 刺激眼睛
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSQL8200000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi Xi,Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 26,570,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 343,61,1995

其他信息

  • Sigma Aldrich:83-72-7(sigmaaldrich)
  • 上游原料:氨基磺酸铵 --> 1,4-萘醌 --> 1,2-萘醌
  • 2-羟基-1,4-萘醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0285 2-羟基-1,4-萘醌 2-Hydroxy-1,4-naphthoquinone 25G 364元 2010/06/21 121630250 2-羟基-1,4-萘醌 2-Hydroxy-p-naphthoquinone 99%, pure 25 GR 452元 2010/06/21 121631000 2-羟基-1,4-萘醌 2-Hydroxy-p-naphthoquinone 99%, pure 100 GR 1263元
  • Alfa Aesar:2-羟基-1,4-萘醌,98+% 2-Hydroxy-1,4-naphthoquinone, 98+%(83-72-7)
  • 下游产品:尼罗红
  • 用途一:用于染发剂、杀菌剂
  • TCI Shanghai:2-羟基-1,4-萘醌 2-Hydroxy-1,4-naphthoquinone,>;98.0%(LC)(T)(83-72-7)
  • 色指数:75480
  • MSDS 信息:2-Hydroxy-1,4-naphoquinone(83-72-7).msds
  • Acros Organics:2-羟基-1,4-萘醌 2-Hydroxy-p-naphthoquinone, pure, 94%(83-72-7)
  • 方法一:将1,2-萘醌-4-磺酸铵和硫在甲醇中反应,得到甲氧基萘醌,再用氢氧化钠水解,得到2-羟基-1,4-萘醌。收率58-65%。
  • MOL 文件:83-72-7.mol
  • 图谱信息:2-羟基-1,4-萘醌(83-72-7)核磁图( 1 HNMR) 2-羟基-1,4-萘醌(83-72-7)质谱(MS) 2-羟基-1,4-萘醌(83-72-7)核磁图( 13 CNMR) 2-羟基-1,4-萘醌(83-72-7)红外图谱(IR2) 2-羟基-1,4-萘醌(83-72-7)红外图谱(IR1)

系列性分类


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