Methyl Phosphorodichloridate 二氯磷酸甲酯
CAS 677-24-7 MFCD00002068
化学结构图
SMILES: COP(=O)(Cl)Cl
化学属性
| Mol. Formula | CH3Cl2O2P |
|---|---|
| Mol. Weight | 148.91 |
| Refractive index | 1.4330 to 1.4370 |
| Boiling Point | 62-64 °C at 15 mmHg |
| Density | 1.488 g/mL at 25 °C(lit.) |
| Flash Point | >;230 °F |
| Melting Point | -59 °C |
别名和识别编码
| Chemical Name | Methyl Phosphorodichloridate |
|---|---|
| Synonym | Methyl dichlorophosphate {LY} Methyl dichlorophosphate {} {LY} Methyl dichlorophosphate {} {} {LY} Methyl dichlorophosphate {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl dichlorophosphate {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00002068 |
| CAS Number | 677-24-7 |
| PubChem Substance ID | 87572891 |
| EC Number | 211-639-1 |
| Chemical Name Translation | 二氯磷酸甲酯 |
| Reaxys-RN | 969710 |
| Beilstein Registry Number | 1,286 |
| InChIKey | SNVCRNWSNUUGEA-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01743052 |
| Canonical SMILES | O=P(Cl)(Cl)OC |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides
相关文献及参考
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
其他信息
- TCI Shanghai:二氯磷酸甲酯 Methyl Phosphorodichloridate,>;95.0%(T)(677-24-7)
- Sigma Aldrich:677-24-7(sigmaaldrich)
- MOL 文件:677-24-7.mol
- 用途一:核黄素磷酸酯钠合成原料。
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