Phenylarsonic Acid 苯胂酸

CAS 98-05-5 MFCD00002097

化学结构图

98-05-5
SMILES: O=[As](O)(O)c1ccccc1

化学属性

Mol. FormulaC6H7AsO3
Mol. Weight202.05
Melting Point158-162°C
TSCAYes
Stability对湿度敏感
Appearance 白色结晶性粉末。熔点158-162℃(分解),相对密度1.76。100g28℃的水能溶解该品3.3g,84℃水能溶解24g;100g乙醇中能溶解15.5g,不溶于氯仿,对氧化剂稳定。
Density1,76 g/cm3

别名和识别编码

Chemical NamePhenylarsonic Acid
MDL NumberMFCD00002097
CAS Number98-05-5
Synonym {uni_hamburg} PHENYLARSONIC ACID Arsonicacid,phenyl- ai3-16050[qr] 苯砷酸 Kyselina benzenarsonova Benzolarsonsäure phenyl-arsonicaci 苯胂酸 PhenylArsonicAcidGr kyselinabenzenarsonova Phenylarsonicacid,97% arsonicacid,phenyl-[qr] Phenylarsonicacid,98% BENZENEARSONIC ACID phenylarsonic acid 苯基胂酸;苯砷酸 Benzenearsonic acid phenylarsonicacid[qr] Arsonic acid, phenyl- PhenylarsonicAcid99% 苯基胂酸 Phenylarsonic acid monophenylarsonicacid Phenylarsonsure Benzenearsonic acid: (Phenylarsonic acid) phenyl-arsonic acid Phenyldihydroxyarsine oxide PhenylArsonicAcidLr Monophenylarsonic acid Phenylarsonsäure phenylarsenicacid
EC Number202-631-9
Merck Number14,1067
Chemical Name Translation苯胂酸
Wiswesser Line NotationQ-AS-QO&R
Beilstein Registry Number2935741
LabNetwork Molecule IDLN01745640
PubChem Substance ID7365
InChIInChI=1S/C6H7AsO3/c8-7(9,10)6-4-2-1-3-5-6/h1-5H,(H2,8,9,10)
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用作分析试剂,测定铋、铌、钽、钍、锡和锆。检定铌、钽和锡。分离钍、钽和锆。

相关文献及参考

  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSCY3150000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S20/21 When using do not eat, drink or smoke 使用时,不得进食,饮水或吸烟;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number UN3465 3280
Risk Statements
  • R50/53
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition 密封保存。 储存温度2-8℃
Hazard Codes N-T
Hazard Class6.1
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 93,287,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 16 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 80,93,1944

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CLDND* Compilation of LD50 Values of New Drugs.  (J.R. MacDougal, Dept. of
   National Health and Welfare, Food and Drug Divisions, 35 John St., Ottawa,
   Ont., Canada)

Warnings 危化品目录(2015) 危险化学品

其他信息

  • 用途二:用作分析试剂,测定铋、铌、钽、钍、锡和锆。检定铌、钽和锡。分离钍、钽和锆。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 图谱信息:苯胂酸(98-05-5)红外图谱(IR2) 苯胂酸(98-05-5)红外图谱(IR1)
  • 可燃性危险特性:受热分解有毒砷化物烟雾
  • 苯胂酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80099660 苯胂酸 100g 93.6元 2010/06/21 224061000 苯胂酸 Phenylarsonic acid 97% 100 GR 4466元 2010/06/21 224060250 苯胂酸 Phenylarsonic acid 97% 25 GR 1697元
  • 方法一:由苯胺重氮化后与亚砷酸反应则制得。
  • 毒性分级:剧毒
  • 上游原料:三氧化二砷
  • 急性毒性:口服-大鼠 LD50: 50 毫克/公斤; 口服-小鼠 LD50: 0.27 毫克/公斤
  • Sigma Aldrich:98-05-5(sigmaaldrich)
  • MOL 文件:98-05-5.mol
  • 对氧化剂稳定。微溶于水,极溶于乙醇,不溶于氯仿。有毒,最小致死量(大鼠,经口)50mg/kg。有刺激性。
  • 下游产品:氧化苯胂
  • 用途一:用作分析试剂。
  • Alfa Aesar:苯砷酸,97% Phenylarsonic acid, 97%(98-05-5)
  • 灭火剂:二氧化碳、砂土、水
  • 职业标准:TWA 0.2 毫克 (砷)/立方米; STEL 0.6 毫克 (砷)/立方米
  • Acros Organics:苯胂酸 Phenylarsonic acid, 97%(98-05-5)
  • 类别:有毒物品

系列性分类


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