Silvex Solution 2,4,5-涕丙酸

CAS 93-72-1 MFCD00002646

化学结构图

93-72-1
SMILES: CC(Oc1cc(Cl)c(Cl)cc1Cl)C(=O)O

化学属性

Mol. FormulaC9H7Cl3O3
Mol. Weight270
Melting Point177-181°C
TSCANo
Density1.2085
Flash Point11 °C
Solubility微溶于水，溶于甲醇、丙酮。

别名和识别编码

Chemical NameSilvex Solution
Synonym 2，4，5-三氯苯氧丙酸 Fenormone 2-(2,4,5-Trichlorphenoxy)-propionsäure 2,4,5-TP 2,4,5-涕丙酸 Silvex® FENOPROP 'LGC' (1306) Kurosal G Fruitone T 2-(2,4,5-trichlorophenoxy)propionic acid propionic acid, 2-(2,4,5-trichlorophenoxy)- α-(2,4,5-trichlorophenoxy)propionic acid Acido 2-(2,4,5-tricloro-fe Amchem 2,4,5-TP Fenop α-(2,4,5-Trichlorophenoxy)-propionic acid 2-(2,4,5-Trichloor-fenoxy)-propionzu 2-(2,4,5-trichloor-fenoxy)-propionzuur[qr] 2-(2,4,5-trichloro-phenoxy)-propionic 2,4,5-trichlorophenoxypropionic acid Kwas 2,4,5-trojchlorofenoksypropionowy Prop 2-(2,4,5-trichlorophenoxy)-propionicaci 2,4,5-三氯苯氧 Kyselina 2-(2,4,5-trichlorfenoxy)propionova 2-(2,4,5-Trichloor-fenoxy)-propionzuur fenoprop (ISO) Acide 2-(2,4,5-trichloro-phenoxy) propionique {C 2 (2,4,5-Trichlorophenoxy)propionic 2-(2,4,5-TRICHLOROPHENOXY)PROPIONIC ACID 2-(2,4,5-trichlorophenoxy)propanoic acid 2-(2,4,5-TRICHLOROPHENOXY)PROPANOIC ACID 2-(2,4,5-trichlorophenoxy)propionicaci Sta-fast 2,4,5-TP 2-(2,4,5-三氯苯氧基)丙酸 LABOTEST-BB LT00044430 TIMTEC-BB SBB003043 (2,4,5-Trichlorophenoxy)propionic acid {h 2-(2,4,5-Trichlor-phenoxy)-propionsaeure 2,4,5-TP(R) alpha-(2,4,5-Trichlorophenoxy)propionic acid 涕丙酸,2.4.5 2-(2,4,5-三氯苯氧基)丙酸 溶液 Weed-B-gon Color-Set Propanoic acid, 2-(2,4,5-trichlorophenoxy)- RCRA waste number U233 SILVEX
MDL NumberMFCD00002646
PubChem Substance ID7158
Beilstein Registry Number1985768
CAS Number93-72-1
EC Number202-271-2
Chemical Name Translation2,4,5-涕丙酸
Merck Number13,8606
Wiswesser Line NotationQVY1&OR BG DG EG
LabNetwork Molecule IDLN01114427
InChIInChI=1S/C9H7Cl3O3/c1-4(9(13)14)15-8-3-6(11)5(10)2-7(8)12/h2-4H,1H3,(H,13,14)
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分类

  • {SNA} Analytical Standards, Phenoxy structure, Plant growth regulators, Q-Z, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {SNA} All Herbicide Standards, Analytical Standards, Phenoxy structure, Plant Growth Regulators, Q-Z, T-Z, 农残和代谢标准品, 分析/色谱, 按照字母排序, 灭草剂
  • {SNA} All alphabetically sorted,
  • Alpha sort, Alphabetic, Analytical Standards,
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards,

相关文献及参考

  • Beil. 6 ,III,721
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
RTECSUF8225000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
Hazard Codes Xn;N Xn,N,T,F Xn,N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Signal word Warning
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S37 Wear suitable gloves 戴适当手套；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number UN3077 UN 3077 9/PG 3 3077
Risk Statements
  • R38 Irritating to skin 刺激皮肤
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R52/53
Packing GroupIII
Hazard Class9
Storage condition 0-6°C
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   165,465,1969

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ANTCAO Antibiotics and Chemotherapy (Washington, DC).  (Washington, DC)
   V.1-12, 1951-62.  For publisher information, see CLMEA3.
   Volume(issue)/page/year: 9,715,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,173,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 276 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPZHAW Roczniki Panstwowego Zakladu Higieny.  (Ars Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 31,373,1980

TYPE OF TEST

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1617 mg/kg
SEX/DURATION            : female 12-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 6,33,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 1617 mg/kg
SEX/DURATION            : female 12-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 6,33,1977

其他信息

  • 可燃性危险特性:受热分解有毒氯化物气体
  • 灭火剂:砂土、干粉、泡沫
  • 图谱信息:2,4,5-涕丙酸(93-72-1)核磁图( 1 HNMR) 2,4,5-涕丙酸(93-72-1)质谱(MS) 2,4,5-涕丙酸(93-72-1)核磁图( 13 CNMR) 2,4,5-涕丙酸(93-72-1)红外图谱(IR2) 2,4,5-涕丙酸(93-72-1)红外图谱(IR1)
  • 急救治疗:误服立即催吐、洗胃。忌用温水洗胃，也可用活性炭与轻泻剂。对症治疗。 注意： 在我国未登记
  • 类别:农药
  • 毒性分级:高毒
  • MSDS 信息:2,4,5-涕丙酸(93-72-1).msds
  • 急性毒性:口服-大鼠 LD50: 650 毫克/公斤; 口服-小鼠 LD50: 276 毫克/公斤
  • MOL 文件:93-72-1.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 外观性质:无色结晶粉末。
  • Acros Organics:2-(2,4,5-Trichlorophenoxy)propionic acid, 97%(93-72-1)
  • 2,4,5-涕丙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 171700050 2,4,5-涕丙酸 2-(2,4,5-Trichlorophenoxy)propionic acid 97% 5 GR 1707元 2010/05/25 L08136 2-(2,4,5-三氯苯氧基)丙酸, 96% 2-(2,4,5-Trichlorophenoxy)propionic acid, 96% 5g 721元 2010/05/25 L08136 2-(2,4,5-三氯苯氧基)丙酸, 96% 2-(2,4,5-Trichlorophenoxy)propionic acid, 96% 25g 3220元
  • 中毒症状:代谢性酸中毒，恶心、呕吐，继后出现嗜睡，肢端感觉麻木，重者肌肉颤动 、抽搐、昏迷、呼吸衰竭。
  • Alfa Aesar:2-(2,4,5-三氯苯氧基)丙酸,96% 2-(2,4,5-Trichlorophenoxy)propionic acid, 96%(93-72-1)
  • 上游原料:乙醇 --> 甲醇 --> 硫酸 --> 钠 --> 石油醚 --> 苯 --> 氢化钠 --> 2-溴乙酸乙酯 --> 1,2,4,5-四氯苯
  • Sigma Aldrich:93-72-1(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C9 - Carboxylic Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Plant growth regulators - Pesticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. Q-Z - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EP - E
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. S - Alphabetic
  5. SA - SM - S
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids
  6. C8

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