2-Propyn-1-ol, 3-(trimethylsilyl)- 3-(三甲基硅基)丙炔醇

CAS 5272-36-6 MFCD00002913

化学结构图

5272-36-6
SMILES: C[Si](C)(C)C#CCO

化学属性

Mol. FormulaC6H12OSi
Mol. Weight128.24
Density0.865
Boiling Point76
Refractive index1.4500 to 1.4530
Flash Point67°C(lit.)
TSCAYes
Stability对光线敏感，对湿度敏感，对空气敏感

别名和识别编码

Chemical Name3-(Trimethylsilyl)propargyl alcohol
Synonym 1-TRIMETHYLSILYLPROPARGYL ALCOHOL 2-Propyn-1-ol, 3-(trimethylsilyl)- 3-(TRIMETHYLSILYL)PROPARGYL ALCOHOL 3-(Trimethylsilyl)-2-propyn-1-ol {Chemicalbook} 3-(Trimethylsilyl)propargyl alcohol, 98+% 3-(trimethylsilyl)-2-propyn-1-o 3-(三甲基硅基)-2-丙炔-1-醇 3-(三甲基硅基)-2-丙炔-1-醇, 98+% 3-(三甲基硅基)丙炔醇 3-TRIMETHYLSILANYL-PROP-2-YN-1-OL 3-TRIMETHYLSILYL-2-PROPYN-1-OL 3-TRIMETHYLSILYL-2-PROPYNE-1-OL 3-Trimethylsilylpropargylalcohol3-Trimethylsilyl-2-propyn-1-ol 3-三甲基硅基-2-丙炔-1-醇 3-三甲硅基-2-丙炔-1-醇 3-三甲硅基丙炔醇 TIMTEC-BB SBB009061 TRIMETHYLSILYLPROPARGYL ALCOHOL {} {Chemblink} 3-(Trimethylsilyl)propargyl alcohol 三甲基硅基-2-丙炔-1-醇 葡聚糖
Beilstein Registry Number1902505
PubChem Substance ID78930
CAS Number5272-36-6
EC Number226-094-5
MDL NumberMFCD00002913
Reaxys-RN1902505
Chemical Name Translation3-(三甲基硅基)丙炔醇
InChIKeyZVGCJDPEKKEYES-UHFFFAOYSA-N
LabNetwork Molecule IDLN00335171
InChIInChI=1S/C6H12OSi/c1-8(2,3)6-4-5-7/h7H,5H2,1-3H3
Canonical SMILESOCC#C[Si](C)(C)C
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分类

  • Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks
  • {SNA} Alkynes, Building Blocks, Chemical Synthesis, Internal, Organic Building Blocks

相关文献及参考

  • Reduction with Sodium bis(2-methoxyethoxy)­aluminum hydride, A13292, gives stereoselectively (E)-3-TMS-2-propen-1-ol: Org. Synth. Coll., 7, 524 (1990). For titanocene dichloride-promoted hydromagnesiation reaction with isobutylmagnesium bromide, see: Org. Synth. Coll., 8, 507, (1993). See Bis(cyclopentadienyl)­titanium dichloride, A11456.

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Signal word
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number UN2810 2810
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R25 Toxic if swallowed 吞咽有毒
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Storage condition 2-8°C Moisture Sensitive 充氩保存
Packing GroupIII
Hazard Codes Xi
Hazard Class6.1
GHS Symbol

其他信息

  • Alfa Aesar:3-(三甲基硅基)-2-丙炔-1-醇,98+% 3-(Trimethylsilyl)propargyl alcohol, 98+%(5272-36-6)
  • Acros Organics:3-三甲基硅基-2-丙炔-1-醇 3-Trimethylsilyl-2-propyn-1-ol, 99%(5272-36-6)
  • Sigma Aldrich:5272-36-6(sigmaaldrich)
  • 三甲硅基丙炔醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1500 3-三甲基硅基-2-丙炔-1-醇 3-Trimethylsilyl-2-propyn-1-ol 5ML 759元 2010/06/21 313890010 葡聚糖 3-Trimethylsilyl-2-propyn-1-ol 99% 1 GR 497元 2010/05/25 L09649 3-(三甲基硅基)-2-丙炔-1-醇, 98+% 3-(Trimethylsilyl)propargyl alcohol, 98+% 25g 3346元
  • TCI Shanghai:3-三甲基硅基-2-丙炔-1-醇 3-Trimethylsilyl-2-propyn-1-ol,>;94.0%(GC)(5272-36-6)
  • F:8-10
  • MOL 文件:5272-36-6.mol
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkynes 炔
  5. Internal - Alkynes
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Acetylenes 炔烃

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