N,N’-Diphenyl-p-phenylenediamine N,N-二苯基-1,4-苯二胺

CAS 74-31-7 MFCD00003015

化学结构图

74-31-7
SMILES: c1ccc(Nc2ccc(Nc3ccccc3)cc2)cc1

化学属性

Mol. FormulaC18H16N2
Mol. Weight260.34
Boiling Point220-225°C at 760 mmHg
Melting Point143-145°C
Density1.2
TSCAYes
Flash Point220-225°C/1mm
Solubility<0.1 g/100 mL at 20 °C

别名和识别编码

Chemical NameN,N’-Diphenyl-p-phenylenediamine
CAS Number74-31-7
Alfabeta NameDIPHENYLBENZENEDIAMINE NN1414---,,
MDL NumberMFCD00003015
Synonym N1,N4-Diphenylbenzene-1,4-diamine {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} { {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene-1,4-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1,N4-Diphenylbenzene
PubChem Substance ID6319
EC Number200-806-4
Beilstein Registry Number2215944
Merck Number3329
Chemical Name TranslationN,N-二苯基-1,4-苯二胺
Reaxys-RN2215944
Wiswesser Line NotationRMR DMR
LabNetwork Molecule IDLN00176265
InChIInChI=1S/C18H16N2/c1-3-7-15(8-4-1)19-17-11-13-18(14-12-17)20-16-9-5-2-6-10-16/h1-14,19-20H
Canonical SMILESC1=CC(=CC=C1NC2=CC=CC=C2)NC3=CC=CC=C3
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分类

  • {SNA} Amine Monomers, Monomers, Polymer Science, Secondary Amines, 材料科学
  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Secondary Amines
  • {SA} Amine Monomers, Materials Science, Monomers, Polymer Science, Secondary Amines

相关文献及参考

  • Merck: 14,3329
  • Merck: 14,3329 Beilstein: 13,IV,116

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany1
Hazard statements
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xi
RTECSST2275000
Precautionary statements
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P352+P333+P313+P362+P364
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P405 Store locked up. 上锁保管。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
Signal word
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R52/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 10(3),49,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2370 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,485,1986

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 30 mg/L
REFERENCE :
   SWEHDO Scandinavian Journal of Work, Environment and Health. (Haartmaninkatu
   1, SF-00290 Helsinki, 29, Finland)  V.1-    1975- Volume(issue)/page/year:
   9(Suppl 2),27,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   PCBRD2 Progress in Clinical and Biological Research.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1975- Volume(issue)/page/year:
   141,407,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 1800 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 241,175,1990

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 450 mg/kg
SEX/DURATION            : female 14 day(s) pre-mating
                          female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - parturition
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 4,796,1956

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4176 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - extra-embryonic structures
   (e.g., placenta, umbilical cord)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2500 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   AJANA2 American Journal of Anatomy.  (Alan R. Liss, Inc., 41 E. 11th St.,
   New York, NY 10003) V.1-192, 1901-91.  Volume(issue)/page/year: 110,29,1962

其他信息

  • 外观性质:银白色片状结晶或灰褐色粉末。
  • 上游原料:氨基苯
  • 用途三:在橡胶工业中用作抗氧剂
  • 灭火剂:干粉, 二氧化碳; 1211; 泡沫
  • 爆炸物危险特性:能与氧化剂起反应; 弱过敏剂
  • 图谱信息:N,N'-二苯基-1,4-苯二胺(74-31-7)核磁图( 1 HNMR) N,N'-二苯基-1,4-苯二胺(74-31-7)核磁图( 13 CNMR) N,N'-二苯基-1,4-苯二胺(74-31-7)红外图谱(IR1) N,N'-二苯基-1,4-苯二胺(74-31-7)质谱(MS)
  • N,N'-二苯基-1,4-苯二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0609 N,N'-二苯基-1,4-苯二胺 N,N'-Diphenyl-1,4-phenylenediamine 500G 3090元 2014/06/02 D0609 N,N'-二苯基-1,4-苯二胺 N,N'-Diphenyl-1,4-phenylenediamine 25G 318元 2014/06/02 D0906 N,N'-二苯基-1,4-苯二胺 N,N'-Diphenyl-1,4-phenylenediamine 25G 587元
  • Sigma Aldrich:74-31-7(sigmaaldrich)
  • TCI Shanghai:N,N'-二苯基-1,4-苯二胺 N,N'-Diphenyl-1,4-phenylenediamine,>;98.0%(GC)(T)(74-31-7)
  • 用途一:用于天然丁苯、丁腈、顺丁、丁基、聚异戊二烯等橡胶、胶乳中,可使其具有良好的耐多次挠曲性和防龟裂性能。提高定伸强力,增强对热氧、臭氧以及铜墙铁壁锰等有害金属的防护作用,对硫化无影响。与防老剂D并用可解决深色橡胶制品的多种老化问题。此外,也用作聚乙稀、聚丙稀?
  • 毒性分级:中毒
  • 可燃性危险特性:受热, 明火较易燃; 受热分解有毒氮氧化物烟雾;致畸剂
  • 类别:易燃液体
  • Acros Organics:N,N'-二苯基-1,4-苯二胺 N,N'-Diphenyl-p-phenylenediamine, 97%(74-31-7)
  • MSDS 信息:防老剂PPD(74-31-7).msds
  • 用途二:用于天然、丁苯、丁腈、顺丁、丁基、丁羟、聚异戊二烯等橡胶及胶乳中
  • 刺激数据:眼睛-兔子 500 毫克/24小时 重度
  • 急性毒性:口服-大鼠 LD50: 2370 毫克/公斤; 口服-小鼠 LD50: 18000 毫克/公斤
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运存放
  • MOL 文件:74-31-7.mol
  • Alfa Aesar:N,N'-二苯基对苯二胺,97% N,N'-Diphenyl-p-phenylenediamine, 97%(74-31-7)

系列性分类


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