p-Terphenyl 二苯基苯

CAS 92-94-4 MFCD00003061

化学结构图

92-94-4
SMILES: c1ccc(-c2ccc(-c3ccccc3)cc2)cc1

化学属性

Mol. FormulaC18H14
Mol. Weight230.31
Density1.23
Vapor Density7.95 (vs air)
Boiling Point389 °C at 760 mmHg
Melting Point212-213 °C
Flash Point207°(404°F)
TSCAYes
Solubility难溶

别名和识别编码

Chemical Namep-Terphenyl
MDL NumberMFCD00003061
CAS Number92-94-4
EC Number202-205-2
Beilstein Registry Number5,695
Synonym 1,1':4',1''-Terphenyl {LY} 1,1':4',1''-Terphenyl {} {LY} 1,1':4',1''-Terphenyl {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1':4',1''-Terphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,1'
PubChem Substance ID87576044
Chemical Name Translation二苯基苯
Reaxys-RN1908447
Wiswesser Line NotationRR DR
LabNetwork Molecule IDLN00197275
Canonical SMILESC1(C2=CC=C(C3=CC=CC=C3)C=C2)=CC=CC=C1
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分类

  • {SNA} Arenes, Biochemicals and Reagents, Building Blocks, Chemical Synthesis, Detection, Fluorescence/Luminescence Spectroscopy, Fluorescent Probes, Labels, Particles and Stains, Luminescent Compounds/Detection, Organic Building Blocks, Scintillation Reagents, Spectroscopy, Wavelength Index, 分析/色谱, 分析试剂
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Chemical Class, Chromatography, Environmental Standards,
  • {SNA} Light-Emitting Dopants and Fluorescent Dyes, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials, 材料科学
  • {SNA} Light

产品应用

  • 作为有机闪烁试剂，是闪烁计数器的发光物。 与联苯混合可用 作核电站的载热体。

相关文献及参考

  • Short: II/27B
  • Short: II/27C
  • Beilstein:5,695

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50/53
  • R36 Irritating to eyes 刺激眼睛
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSWZ6475000
Hazard Codes Xi,N Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number UN 3077 9/PG 3 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,26,1953

其他信息

  • 上游原料:盐酸 --> 乙醚 --> 碳酸钠 --> 硫酸钠 --> 苯 --> 镁 --> 溴苯 --> 联苯 --> 二乙酰丙酮镍 --> 1,4-二碘苯
  • 毒性分级:中毒
  • MOL 文件:92-94-4.mol
  • 储运特性:1.保持容器密闭。2.储存于阴凉、干燥的地方。
  • MSDS 信息:联三苯(92-94-4).msds
  • TCI Shanghai:对三联苯 p-Terphenyl,>;99.0%(GC)(92-94-4)
  • 图谱信息:对三联苯(92-94-4)质谱(MS) 对三联苯(92-94-4)红外图谱(IR3) 对三联苯(92-94-4)红外图谱(IR1) 对三联苯(92-94-4)核磁图( 1 HNMR) 对三联苯(92-94-4)核磁图( 13 CNMR) 对三联苯(92-94-4)红外图谱(IR2)
  • Sigma Aldrich:92-94-4(sigmaaldrich)
  • 职业标准:TWA 5 毫克/立方米
  • 类别:有毒物质
  • 用途三:作为有机闪烁试剂，是闪烁计数器的发光物。 与联苯混合可用 作核电站的载热体。
  • 急性毒性:口服-大鼠 LDL0: 500 毫克/公斤;
  • 灭火剂:喷水、化学干粉、酒精泡沫、二氧化碳、聚合泡？i
  • Alfa Aesar:对三联苯,99+% p-Terphenyl, 99+%(92-94-4)
  • 不溶于水和溶于热苯，微溶于乙醚和二硫化碳。极难溶于乙醇和醋酸。407℃升华。
  • 对三联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30074982 1.4-二苯基苯 25g 120元 2011/04/16 T0020 对三联苯 p-Terphenyl 25G 382元 2011/04/16 T0020 对三联苯 p-Terphenyl 500G 3220元
  • 检测方法:HPLC,NMR
  • 外观性质:片状或针状固体。
  • 用途二:用于有机合成；作为有机闪烁试剂，是闪烁计数器的发光物；与联苯等混合可用作核电站的载热体。
  • 可燃性危险特性:可燃; 火场释放辛辣刺激烟雾
  • Acros Organics:对三联苯 p-Terphenyl, pure, 99+%(92-94-4)
  • 方法一:工业上可从生产联苯的副产物中分离得到，采用升华法效果较好。
  • 蒸气密度:7.95 (vs air)
  • 用途一:液晶、医药中间体，闪烁试剂

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Fluorescent Probes, Labels, Particles and Stains - Biochemicals and Reagents
  4. Detection - Fluorescent Probes, Labels, Particles and Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Wavelength Index - Luminescent Compounds/Detection
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Materials Science 材料科学
  2. Products for Organic & Printed Electronics Research
  3. Photonic and Optical Materials - Organic and Printed Electronics
  4. Photoluminescent Materials - Photonic and Optical Materials
  5. Light-Emitting Dopants and Fluorescent Dyes - Photoluminescent Materials
  1. Materials Science 材料科学
  2. Electroluminescence
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Fluorescent Probes, Labels, Particles and Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Luminescent Compounds/Detection
  4. Fluorescent Probes, Labels, Particles and Stains

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