CAS 534-22-5 MFCD00003248-2-Methylfuran 2-甲基呋喃 -LabNovo

2-Methylfuran 2-甲基呋喃

CAS 534-22-5 MFCD00003248

化学结构图

SMILES: CC1CCCO1

化学属性

Mol. Formula	C5H6O
Mol. Weight	82.10
Refractive index	n20/D 1.433(lit.)
Boiling Point	-
Density	0.91
Flash Point	-
TSCA	Yes
Melting Point	-88.68°C
Vapor Density	2.8 (vs air)
Vapor Pressure	139 mmHg ( 20 °C)
Solubility	微溶于水，可混溶于乙醇、乙醚、丙酮等。
Stability	对光敏感

别名和识别编码

Chemical Name	2-Methylfuran
CAS Number	534-22-5
Synonym	2-Methylfuran {LY} 2-Methylfuran {} {LY} 2-Methylfuran {} {} {LY} 2-Methylfuran {} {} {} {LY} 2-Methylfuran {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylfuran {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID	10797
EC Number	208-594-5
Beilstein Registry Number	103733
MDL Number	-
Reaxys-RN	103733
Chemical Name Translation	2-甲基呋喃
Wiswesser Line Notation	T5OJ B1
LabNetwork Molecule ID	LN00196662
InChI	InChI=1S/C5H6O/c1-5-3-2-4-6-5/h2-4H,1H3
Canonical SMILES	CC1=CC=CO1

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品牌质保精细包装现货库存一流品牌服务

产品应用

有机合成中间体，医药工业中用于制造维生素B1、磷酸氯喹和磷酸伯氨喹。

安全信息

GHS Symbol

WGK Germany1

Hazard Codes F,T F;T

Hazard statements

H330 Fatal if inhaled 吸入致命
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H331 Toxic if inhaled 吸入中毒

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSLU2625000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P305+P351+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P304+P340+P310
P501 Dispose of contents/container to..… 处理内容物/容器.....
P337+P313
P403+P233
P303+P361+P353
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P370+P378
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P403+P235
P304+P340+P312
P241+P242+P243
P305+P351+P338+P337+P313

Signal word

UN Number

Risk Statements

R11 Highly flammable 非常易燃
R23 Toxic by inhalation 吸入有毒
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R36 Irritating to eyes 刺激眼睛
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S20 When using do not eat or drink 使用时，不得进食，饮水；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S4 Keep away from living quarters 远离生活区；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；

Packing GroupII

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class3

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 455 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 46(2),68,1981

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   50,A359,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 730 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 46(2),68,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 46(2),68,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreporte

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 75300 umol/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   13,89,1981

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 160 ng/disc
REFERENCE :
   DFSCDX Developments in Food Science.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1978- Volume(issue)/page/year:
   13,353,1986

Restrict 危险品

其他信息

上游原料:氢 --> 重铬酸钠 --> 糠醛 --> 糠醇 --> 催化剂 --> 重铬酸钠 --> 硝酸铜 --> 加氢催化剂 --> 硝酸铜 --> 硝酸铜 --> 铜铝合金
Alfa Aesar:2-甲基呋喃,98+%,stab.with150-400ppmBHT 2-Methylfuran, 98+%, stab. with 150-400ppm BHT(534-22-5)
外观性质:无色液体，有醚样气味，在空气中或阳光照射下变黄至黑色。
刺激数据:眼睛- 兔子 500毫克/24小时轻度
TCI Shanghai:2-甲基呋喃 2-Methylfuran,>;98.0%(GC)(534-22-5)
有醚样气味，在空气中或阳光照射下变黄至黑色，能与多种有机溶剂混溶，微溶于水（0.3g/100g）。在空气中变黄，能被强碱分解。有麻醉作用。
2-甲基呋喃价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0226 2-甲基呋喃 2-Methylfuran 25ML 153元 2014/06/02 M0226 2-甲基呋喃 2-Methylfuran 500ML 480元 2010/06/21 126832500 2-甲基呋喃 2-Methylfuran 99%, stabilized 250 ML 1294元
海关编码:29321900
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
用途一:用于制取维生素B1、磷酸氯喹和磷酸伯氨喹等药物，合成菊酯类农药及香精香料，也是很好的溶剂
毒性分级:中毒
用途二:用作有机溶剂
类别:易燃液体
FEMA:4179
图谱信息:2-甲基呋喃(534-22-5)核磁图( 13 CNMR) 2-甲基呋喃(534-22-5)红外图谱(IR2) 2-甲基呋喃(534-22-5)质谱(MS) 2-甲基呋喃(534-22-5)核磁图( 1 HNMR) 2-甲基呋喃(534-22-5)红外图谱(IR1)
MSDS 信息:2-甲基呋喃(534-22-5).msds
Acros Organics:2-甲基呋喃 2-Methylfuran, stabilized, 99%(534-22-5)
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg） 2-甲基呋喃食品食品
急性毒性:口服- 大鼠
用途三:2-甲基呋喃是拟除虫菊酯烯丙菊酯、丙炔菊酯的中间体烯丙醇酮的原料，2-甲基呋喃又是良好的溶剂。
职业标准:STEL 1 毫克/ 立方米
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
方法一:其制备方法是由糠醛用铜铝或铜为催化剂加氢制得。加氢的最佳条件是压力300～500kPa，温度200～210
蒸气压:139 mm Hg ( 20 °
下游产品:4,5,6,7-四氢-2-甲基呋喃[2,3-C]并吡啶 --> 2-丙烯基-3-甲基-4-羟基-2-环戊烯-1-酮 --> 5-羟基-2-戊酮 --> 右旋烯丙菊酯 --> 5-甲基呋喃-2-硼酸 --> N,N-二甲基-5-甲基糠胺 --> 5-甲基-2-乙酰基呋喃 --> 2-甲基四氢呋喃 --> 2-乙基-6-甲基-3-羟基吡啶 --> 甲基环戊烯醇酮 --> 5-甲基呋喃醛 --> 2-甲基-3-呋喃硫醇
方法二:由糠醛（或糠醇）催化加氢制。加氢催化剂采用铜-铝合金，用碱作助催化剂，反应压力为0.3-0.5MPa，在200℃左右进行气相加氢，氢与糠醛摩尔比为10：1。反应产物经冷凝，蒸去水分，精馏而得成品。原料消耗定额：糠醛（96%）1400kg/t、氢气630m3kg/t、铜-铝催化剂114kg/t。

2-Methylfuran 2-甲基呋喃

CAS 534-22-5 MFCD00003248

化学结构图

化学属性

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化学结构图

化学属性

别名和识别编码

分类

产品应用

相关文献及参考

安全信息

其他信息

系列性分类

相关产品推荐

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