5-Bromosalicylaldehyde 5-溴水杨醛

CAS 1761-61-1 MFCD00003330

化学结构图

1761-61-1
SMILES: O=Cc1cc(Br)ccc1O

化学属性

Mol. FormulaC7H5BrO2
Mol. Weight201.02
Density1.422
Melting Point102-106°C
TSCAYes
Solubility不溶
Appearance 5-溴水杨醛(1761-61-1)为白色丝状结晶体。熔点102-105℃。
Stability对空气敏感
Boiling Point247.3°C at 760 mmHg

别名和识别编码

Chemical Name5-Bromosalicylaldehyde
CAS Number1761-61-1
Alfabeta NameBROMOHYDROXYBENZALDEHYDE 52---
MDL NumberMFCD00003330
Synonym 5-Bromosalicylaldehyde {LY} 5-Bromosalicylaldehyde {} {LY} 5-Bromosalicylaldehyde {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromosalicylaldehyde {} {} {} {} {} {} {} {} {} {} {} {}
EC Number217-167-2
Beilstein Registry Number774710
PubChem Substance ID87563864
Reaxys-RN774710
Chemical Name Translation5-溴水杨醛
LabNetwork Molecule IDLN00009089
InChIInChI=1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H
Canonical SMILESO=CC1=CC(Br)=CC=C1O
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分类

  • Aromatics
  • {SNA} Aldehydes, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • Miscellaneous Reagents

产品应用

  • It was used for chemical derivatization during amine quantiifcation in poly (ethylene terephthalate) (PET) film and PET scaffold.

相关文献及参考

  • For a review of the use of circular dichroism studies of salicylidene and 5-bromo-salicylidene derivatives of chiral amines in establishing their absolute configuration by means of the "salicylidene chirality rule", see: Chem. Rev., 83, 359 (1983).
  • Reacts with aromatic aldehydes and ammonia to give bromosalicylidene-derivatives of arylmethylenediamines, useful in heterocyclic synthesis: Synth. Commun., 18, 2289 (1988).

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi

其他信息

  • 用途一:用于医药、香料和染料等有机合成的中间体
  • Hazard Note:Irritant
  • Sigma Aldrich:1761-61-1(sigmaaldrich)
  • 敏感性:Air Sensitive
  • TCI Shanghai:5-溴水杨醛 5-Bromosalicylaldehyde,>;98.0%(GC)(T)(1761-61-1)
  • 海关编码:29130000
  • MOL 文件:1761-61-1.mol
  • Alfa Aesar:5-溴水杨醛,98% 5-Bromosalicylaldehyde, 98%(1761-61-1)
  • MSDS 信息:5-Bromosalicylaldehyde(1761-61-1).msds
  • 检测方法:HPLC
  • 5-溴水杨醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010095 5-溴水杨醛 100g 650元 2011/04/16 B0893 5-溴水杨醛 5-Bromosalicylaldehyde 25G 655元 2011/04/16 B0893 5-溴水杨醛 5-Bromosalicylaldehyde 500G 5600元
  • 图谱信息:5-溴水杨醛(1761-61-1)质谱(MS) 5-溴水杨醛(1761-61-1)核磁图( 1 HNMR) 5-溴水杨醛(1761-61-1)Raman光谱 5-溴水杨醛(1761-61-1)核磁图( 13 CNMR) 5-溴水杨醛(1761-61-1)红外图谱(IR1) 5-溴水杨醛(1761-61-1)红外图谱(IR2)
  • Acros Organics:5-溴水杨醛 5-Bromosalicylaldehyde, 98%(1761-61-1)
  • 下游产品:6-溴-3,4-二氢-3-硝基-2H-苯并吡喃 --> 5-溴-1-苯并呋喃-2-甲醛 --> 5-溴苯并呋喃-2-羧酸 --> 2-乙酰基-5-溴苯并[B]呋喃 --> 6-溴-3-丁酰-2H-苯并吡喃-2-酮
  • 存储注意事项:空气敏感

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  6. C7 - Aldehydes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic aldehyde<including acetal,hemiacetal>
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes
  6. C10 to C21

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