Silver Tetrafluoroborate 四氟硼酸银
CAS 14104-20-2 MFCD00003408
化学结构图
SMILES: F[B-](F)(F)F.[Ag+]
化学属性
| Mol. Formula | AgBF4 |
|---|---|
| Mol. Weight | 195 |
| Melting Point | 70-73 |
| TSCA | T |
| Density | 1.422 |
| Solubility | 可溶 |
| Stability | 对光线敏感，对湿度敏感 |
别名和识别编码
| Chemical Name | Silver Tetrafluoroborate |
|---|---|
| CAS Number | 14104-20-2 |
| Alfabeta Name | SILVERTETRAFLUOROBORATE |
| MDL Number | MFCD00003408 |
| Synonym | 四氟硼酸银 Silver tetrafluoroborate Silbertetrafluoroborat Silver(1+) tetrafluoroborate(1-) Silver(I) fluoroborate Silber(I)tetrafluoroborat Silbertetrafluorborat |
| EC Number | 237-956-5 |
| PubChem Substance ID | 87575928 |
| Beilstein Registry Number | 11547930 |
| Reaxys-RN | 11547930 |
| Chemical Name Translation | 四氟硼酸银 |
| InChIKey | CCAVYRRHZLAMDJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00119270 |
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分类
- {uni_hamburg}
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Silver Catalysts, Silver Complexes, Silver Salts, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts, Silver, Silver Complexes, Silver Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts,
相关文献及参考
- For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
- Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
- Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
- Short: EINECS
- In the presence of AgBF4, aceta
- Short: III/7a
- In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.
安全信息
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
- P303+P361+P353+P310+P363
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P405 Store locked up. 上锁保管。
- P304+P340
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340+P310
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 56 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#06756
其他信息
- 溶于水。
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