Arsenic(Iii) Sulfide 硫化砷(III)

CAS 1303-33-9 MFCD00003435

化学结构图

1303-33-9
SMILES: S=[As]S[As]=S

化学属性

Mol. FormulaAs2S3
Mol. Weight246
Density3.43
Melting Point300°
TSCAYes
Boiling Point707°
SolubilityInsoluble in water. Soluble in alkali sulfides or carbonate, hot HCl
Flash Point707°C
Appearance 雌黄是砷硫化物矿物之一。单斜晶系，晶体呈短柱状、板状，集合体呈片状、杆状、粉末状或具放射状构造的肾状等。颜色呈柠檬黄色(略带绿色)。条痕鲜黄色。油脂光泽至金刚光泽。薄片透明具挠性。硬度1.5～2，密度3.4～3．5 g／cm 3 。不导电。木炭上烧之易熔，火焰呈蓝色，发白烟且有蒜臭味。易熔于氢氧化钾且无残留物。主要产于低温热液矿床，常与雄黄、辉锑矿、白铁矿、石英等共生。

别名和识别编码

Chemical NameArsenic(Iii) Sulfide
Synonym Auripigment CI PIGMENT YELLOW Arsenic sulfide (As0.4S0.6) ARSENIC SULFIDE King's Gold arsenicsesquisulphide ai3-01006 Arsenic Yellow C.I. Pigment Yellow 39 ARSENIC (OUS) SULFIDE arsenic (III) sulphide Arsenic sesquisulfide ARSENIC TRI SULPHIDE Sekio Pigment Yellow 39 Arsensulfid Arsenic sulfide (AsS1.5) 硫 arsenic trisulphide 硫化砷(III) C.I. 77086 arsenictersulfide Auripigmentum 雌黄 arsenicyellow ARSENIC SULFIDE YELLOW arsenicsulfide(as2s3) C.I.颜料黄 53 arsenicsulphide Arsenous sulfide Arsenic sulfi Arsenic Sulphide Arsenic sesquisulfide (As2S3) arsenioussulphide ARSENIC TRISULFIDE Arsen(III)-sulfi Orpiment Arsenic sulfide (As2S3) Arsenic(III) sulfide Arsenic sulphide Arsenic Sulfide Yellow 三硫化二砷 Arsenic trisulfide arsenicsulfide[as2s3] ARSENIC (III) SULFIDE 三硫化砷 Diarsenic trisulfide Arsenious sulphide Arsentrisulfid 正黄 硫化亚砷 arsenictersulphide arsenicsesquisulfide Arsenic trisulfide (As2S3) Arsenious sulfide 硫化砷, 99.9% (METALS BASIS) Arsenic sesquisulphide arsenicred Diarsenic trisulphide Arsenicsulfide,(As2S3) diarsenic trisulphide ars Shio
MDL NumberMFCD00003435
CAS Number1303-33-9
PubChem Substance ID24884190
EC Number215-117-4
Merck Number14,806
Chemical Name Translation硫化砷(III)
Wiswesser Line Notation.AS2.S3
LabNetwork Molecule IDLN02144196
InChIInChI=1S/As4S6/c5-1-6-3-8-2(5)9-4(7-1)10-3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {uni_hamburg} no charge; 5fragments; ionic
  • {SNA} Chalcogenides, Materials Science, Metal and Ceramic Science

相关文献及参考

  • Short: III/14b1 Title: Structure Data of Elements and Intermetallic Phases: Sulfides, Selenides, Tellurides, Part b1: Ag-Al-Cd-S ... Cu-Te-Yb Author: Eisenmann, B.; Schäfer, H. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/14b1 Year: 1986 ISBN: 3-540-15411-6 ISBN: 978-3-540-15411-2 Internet Resource: DOI:10.1007/b19991 RefComment: 216 figs., XXIII, 504 pages. Hardcover
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/23b Title: Electronic Structure of Solids: Photoemission Spectra and Related Data Author: Goldmann, A.; Ishii, T.; Manzke, R.; Naegele, J.R.; Skibowski, M. Editor: Goldmann, A. Source: Landolt-Börnstein, New Series Volume: III/23b Year: 1994 ISBN: 3-540-53705-8 ISBN: 978-3-540-53705-2 Internet Resource: DOI:10.1007/b91258 RefComment: 647 figs., VIII, 327 pages. Hardcover Abstract: Photoelectron spectroscopy has matured considerably during the last decade. The experimental techniques were improved markedly. Photon line sources and,in particular, synchrotron radiation sources are now routinely available in many places. The volume summarizes data on the bulk electronic structure of solids. Besides the photoelectron results, a limited set

安全信息

WGK Germany3
Precautionary statements
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSCG2638000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Packing GroupIII
UN Number UN1557 UN 1557 6.1/PG 2
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R50/53
Hazard Codes T,N
Hazard Class6.1
Storage condition Poison room 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratracheal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 73885 ug/kg/15W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   27,99,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   20,190,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 215 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(7),53,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 254 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(7),53,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 936 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(7),53,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 185 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle w

其他信息

  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 4.454×10-4/20℃
  • 方法二:将硫酸法钛白生产中的水合二氧化钛充分洗涤后，送入打浆罐中，并按一定比例加入具有足够活性的含镍和锑的化合物，以及可促进煅烧时晶型转化的处理剂后，按一定浓度混合均匀，经过滤后，将滤饼送入回转窑，在1000℃左右的温度下煅烧完全晶格转化。煅烧温度过高，会发生物料烧结而影响成品性能。故可根据不同用途作不同处理。
  • 急性毒性:口服-大鼠 LD50: 185 毫克/公斤; 口服-小鼠 LD50: 254 毫克/公斤
  • 毒性分级:高毒
  • 上游原料:水合二氧化钛 --> 二氧化钛 --> 处理剂 --> 雄黄
  • 可燃性危险特性:可燃; 燃烧产生有毒硫氧化物和砷化物烟雾; 与水或酸反应生成有毒可燃烟雾
  • 下游产品:镉黄 --> 铬酸锶钙
  • 职业标准:TWA 0.01 毫克 (砷)/立方米
  • 方法一:同“雄黄”。
  • 硫化砷(III)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 12371 硫化砷, 99.9% (metals basis) Arsenic(III) sulfide, 99.9% (metals basis) 25g 2240元 2010/05/25 12371 硫化砷, 99.9% (metals basis) Arsenic(III) sulfide, 99.9% (metals basis) 100g 8064元 2010/05/25 45522 Arsenic(III) sulfide, 99.999% (metals basis) 5g 882元
  • Alfa Aesar:硫化砷,99.999%(metalsbasis) Arsenic(III) sulfide, 99.999% (metals basis)(1303-33-9)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳
  • 用途二:同“雄黄”。
  • 爆炸物危险特性:与氧化剂,如过氧化氢或与硝酸钾和硫起激烈反应
  • 储运特性:通风低温干燥; 与库房食品原料和酸分开存放
  • 用途一:钛镍黄的耐候性及耐久性胜过金红石型钛白，可用于卷钢涂料、汽车涂料、车辆和航空涂料，亦用于标牌、路标用的涂料和塑料等。用于钛镍黄优异的稳定性，可用于在高温下应用的耐高温涂料，在高温下注塑的塑料和其它耐热涂料。钛镍黄化学稳定性好，可用于化工厂的设备和墙壁涂料、水泥涂料、乳胶涂料和酸固化氨基树脂涂料。钛镍黄无毒，可在玩具涂料和玩具塑料、食品包装塑料和食品罐的印刷油墨等方面应用。钛镍黄的主要缺点是色浅，着色力低，粒度远较钛白粉为粗，分散性差，不宜单独作为黄色颜料，多用于作为黄基和其它有机黄色颜料配合使用，用于浅色耐候性外用涂料。
  • MOL 文件:1303-33-9.mol
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Arsenic - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Chalcogenides - Metal and Ceramic Science

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