Rhodium(II) Acetate Dimer 乙酸铑(II)二聚体

CAS 15956-28-2 MFCD00003538

化学结构图

15956-28-2
SMILES: CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O

化学属性

Mol. FormulaRh2(OOCCH3)4
Mol. Weight441.99
Melting Point205 °C
TSCANo
SolubilitySlightly soluble in ethanol
Density1.422
Appearance greenish-black xtl.

别名和识别编码

Chemical NameRhodium(II) Acetate Dimer
Synonym Dirhodium tetraacetate {LY} Dirhodium tetraacetate {} {LY} Dirhodium tetraacetate {} {} {LY} Dirhodium tetraacetate {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dirhodium tetraacetate {} {} {} {} {} {} {} {}
MDL NumberMFCD00003538
PubChem Substance ID24852229
CAS Number15956-28-2
EC Number240-084-8
Reaxys-RN14201302
Beilstein Registry Number14201302
Chemical Name Translation乙酸铑(II)二聚体
Canonical SMILESO1=C([O-][Rh+2]234O=C([O-][Rh+2]14(O=C([O-]2)C)[O-]C(=O3)C)C)C
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分类

  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors
  • {SNA} C-H Activation, Cata
  • Materials Science, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Essential Chemicals, Metal and Ceramic Science, Micro/NanoElectronics, Research Essentials, Rhodium, Rhodium Salts, Salts, Solution Deposition Precursors, 材料科学

产品应用

  • 烯烃的环丙烷化,同源催化剂,高效催化剂,用于形成叶立德。

相关文献及参考

  • Catalyst for various cyclization reactions involving ɑ-diazo carbonyl groups. Promotes the formation of macrocyclic lactones via intramolecular cyclopropanation and carbon-hydrogen insertion: J. Am. Chem. Soc., 117, 7181 (1995). For a brief feature on uses of the reagent in synthesis, see: Synlett, 3169 (2005).
  • Sugimura, T.; Mori, A. et. al. Tetrahedron Asymmetry 14 , 881, (2003)
  • Zhu, S.; Liao, Y.; Zhu, S. Org. Lett. 6 , 377, (2004) 摘要
  • Beil. 2 ,124

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSVI9361000
Hazard Codes Xi
Safety Statements
  • S15 Keep away from heat 远离热源;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Signal word Warning
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
TYPE OF TEST            : LD10 - Lethal Dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 115 mg/kg
TOXIC EFFECTS :
   Tumorigenic - active as anti-cancer agent
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 20,943,1977

其他信息

  • 溶于水。微溶于乙醇。

系列性分类


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