1-Chloronaphthalene 1-氯萘

CAS 90-13-1 MFCD00003874

化学结构图

90-13-1
SMILES: Clc1cccc2ccccc12

化学属性

Mol. FormulaC10H7Cl
Mol. Weight162.62
Density1.194
Refractive index1.6300 to 1.6340
Flash Point121°C
TSCAYes
Boiling Point259
Melting Point-2.5
Solubility不溶. <0.1 G/100 ML AT 20 ºC

别名和识别编码

Chemical Name1-Chloronaphthalene
CAS Number90-13-1
EC Number201-967-3
Beilstein Registry Number970836
MDL NumberMFCD00003874
Synonym 1-Chloronaphthalene {LY} 1-Chloronaphthalene 1-Chloronaphthalene tech. 1-NAPHTHYL CHLORIDE 1-Naphthalenyl chloride 1-Naphthyl chloride 1-Naphthyl chloride; alpha-Chloronaphthalene 1-Naphthylchlorid 1-chloro-naphthalen 1-chloro-naphthalene 1-chloroaphthalene 1-chloronaphtalene 1-chloronaphthalene 1-naphthyl chloride 1-氯代萘 1-氯萘 1-氯萘, TECH 1-氯萘, TECH. 85%, REMAINDER 2-CHLORONAPHTHALENE 1-氯萘,90% 1-氯萘,TECH.85% A-CHLORONAPHTALENE ALPHA-CHLORONAPHTHALENE ALPHA-NAPHTHY {} {LY} 1-Chloronaphthalene {} {} {LY} 1-Chloronaphthalene {} {} {} {LY} 1-Chloronaphthalene {} {} {} {} {LY} 1-Chloronaphthalene {} {} {} {} {} {LY} 1-Chloronaphthalene {} {} {} {} {} {} {LY} 1-Chloronaphthalene
Merck Number2149
PubChem Substance ID87560835
Reaxys-RN970836
Chemical Name Translation1-氯萘
Wiswesser Line NotationL66J BG
LabNetwork Molecule IDLN00192963
InChIInChI=1S/C10H7Cl/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
Canonical SMILESClC1=C2C=CC=CC2=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Aryl, Bioactive Small Molecules, Building Blocks, C-CH, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks, 细胞生物学
  • {SNA} Aryl, Bioactive Small Molecules, Building Blocks, C-CH, C9 to C12, Cell Biology, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Aryl, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 显微镜测定结晶折光率用的浸液。油脂的溶剂。气相色谱固定液(最高使用温度75℃，溶剂为氯仿、甲醇)，分离和分析低级烃和卤代烃，选择性保留芳香族化合物，能分离二甲苯异构物。

相关文献及参考

  • Short: II/27B
  • Merck: 14,2149 Beilstein: 5,IV,1658
  • Merck: 14,2149
  • Short: II/3

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R51/53
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSQJ2100000
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 9
UN Number 3082
Packing GroupIII
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1091 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1540 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-72-62,1972

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 21),2,1992

其他信息

  • 用途二:用作油脂溶剂
  • 毒性分级:中毒
  • 可燃性危险特性:明火、高温可燃; 受高热分解有毒氯化物气体
  • Hazard Note:Irritant
  • 用途一:用于制1-萘酚，用于生产染料、木材防腐剂、杀菌剂、特种清洁剂等
  • 类别:有毒物品
  • 急性毒性:口服- 大鼠 LD50: 1540 毫克/ 公斤; 口服- 小鼠 LD50:1091 毫克/ 公斤
  • MOL 文件:90-13-1.mol
  • TCI Shanghai:1-氯萘 1-Chloronaphthalene,>;98.0%(GC)(90-13-1)
  • 灭火剂:泡沫、二氧化碳、砂土、雾状水、干粉。
  • Sigma Aldrich:90-13-1(sigmaaldrich)
  • 用途三:用于有机合成，制备1-萘酚，也可作为溶剂、分析试剂。
  • 上游原料:1-萘胺 --> 2-氯萘
  • 图谱信息:1-氯萘(90-13-1)核磁图( 1 HNMR) 1-氯萘(90-13-1)核磁图( 13 CNMR) 1-氯萘(90-13-1)红外图谱(IR1) 1-氯萘(90-13-1)质谱(MS) 1-氯萘(90-13-1)Raman光谱
  • Acros Organics:1-氯萘 1-Chloronaphthalene, 85%, remainder 2-Chloronaphthalene, tech.(90-13-1)
  • 有挥发性。能随水蒸气挥发。溶于苯、石油醚和乙醇，不溶于水。低毒，半数致死量(大鼠，经口)1540mg/kg。有刺激性。
  • 职业标准:TWA 0.2 毫克/ 立方米; STEL 0.6 毫克/ 立方米
  • 1-氯萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0212 1-氯萘 1-Chloronaphthalene 500G 909元 2014/06/02 C0212 1-氯萘 1-Chloronaphthalene 25G 158元 2014/06/02 C2310 1-氯萘 1-Chloronaphthalene 5G 487元
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • MSDS 信息:1-氯化萘(90-13-1).msds
  • Alfa Aesar:1-氯萘,tech.85%,remainder2-chloronaphthalene 1-Chloronaphthalene, tech. 85%, remainder 2-chloronaphthalene(90-13-1)
  • 下游产品:a-萘酚 --> 噻酚-2-羰基咪唑盐酸盐 --> 4,5-二乙氧基-N-甲基-1,8-萘二甲酰亚胺 --> 1,4-二氯萘 --> N-甲基-4-甲氧基-1,8-萘酰亚胺
  • 外观性质:无色或浅黄色油状液体。
  • 用途四:显微镜测定结晶折光率用的浸液。油脂的溶剂。气相色谱固定液(最高使用温度75℃，溶剂为氯仿、甲醇)，分离和分析低级烃和卤代烃，选择性保留芳香族化合物，能分离二甲苯异构物。
  • 方法一:由萘直接氯化而得：氯化反应以锌作催化剂，萘氯比为1：0.84-1.17，催化剂用量为萘重的0.4-0.5%，通氯时间3-6h，反应温度90-95℃，1-氯萘平均产率81.7%，经二次分馏，产品纯度96%。也可用碘作催化剂，在溶剂氯苯中反应，反应温度60-70℃，通氯6h即反应结束。直接氯化法同时生成2-氯萘，约占2-20%，两种异构体沸点相近（2-氯萘沸点264-266℃），化学性质较相似，很难分离。少量生产也可由甲萘胺经重氮化、置换而得。

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. C-CH - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C9 to C12 - Aryl
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C8
  1. Acyl halide
  2. acyl chloride

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