2,​6-​Naphthalenedicarboxy​lic acid 萘-2,6-二甲酸

CAS 1141-38-4 MFCD00004105

化学结构图

1141-38-4
SMILES: O=C(O)c1ccc2cc(C(=O)O)ccc2c1

化学属性

Mol. FormulaC12H8O4
Mol. Weight216.19
Melting Point>;300 °C (lit.)
TSCAT
Appearance 白色针状结晶。熔点310-313℃(分解)。不溶于沸苯、甲苯和乙酸。
Density1.5
Boiling Point316.6 °C at 760 mmHg

别名和识别编码

Chemical Name2,​6-​Naphthalenedicarboxy​lic acid
CAS Number1141-38-4
Alfabeta NameNAPHTHALENEDICARBOXYLICACID 26--,
MDL NumberMFCD00004105
Synonym Naphthalene-2,6-dicarboxylic acid {LY} Naphthalene-2,6-dicarboxylic acid {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-2,6-dicarboxylic acid {} {} {} {} {} {}
PubChem Substance ID14357
EC Number214-527-0
Reaxys-RN2051257
Beilstein Registry Number7(3)4471
Chemical Name Translation萘-2,6-二甲酸
LabNetwork Molecule IDLN00118138
InChIInChI=1S/C12H8O4/c13-11(14)9-3-1-7-5-10(12(15)16)4-2-8(7)6-9/h1-6H,(H,13,14)(H,15,16)
Canonical SMILESOC(=O)C1=CC2=CC=C(C=C2C=C1)C(O)=O
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分类

  • {SNA} Building Blocks, C11 to C12, Carbonyl Compounds, Carboxyl
  • {SNA} Building Blocks, C11 to C12, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {SNA} Alternative Energy, Carboxylic Acid Monomers, Materials Science, Materials for Hy
  • Bioactive Small Molecules,

产品应用

  • A polybasic acid intended for use as components of resinous and polymeric coatings that contact food.

相关文献及参考

  • Beil. 9 ,921
  • FT-IR 2 (2), 2733:D / FT-NMR 1 (2), 1172:A / RegBook 1 (2), 1831:L / Structure Index 1 , 293:D:7

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard Codes Xi
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Acros Organics:2,6-萘二羧酸 2,6-Naphthalenedicarboxylic acid, 97%(1141-38-4)
  • TCI Shanghai:2,6-萘二羧酸 2,6-Naphthalenedicarboxylic Acid,>;98.0%(GC)(T)(1141-38-4)
  • 2,6-萘二羧酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0377 2,6-萘二羧酸 2,6-Naphthalenedicarboxylic Acid 25G 1160元 2011/04/16 N0377 2,6-萘二羧酸 2,6-Naphthalenedicarboxylic Acid 250G 2980元 2010/06/21 269160050 2,6-萘二羧酸 2,6-Naphthalenedicarboxylic acid 97% 5 GR 527元
  • TSCA:T
  • Sigma Aldrich:1141-38-4(sigmaaldrich)
  • 方法一:一种方法是以萘的一元或二元羧酸盐为原料,通过Henkel反应合成NDA/NDC;另一种是先合成出可用于氧化的2,6位取代萘,进而氧化成NDA,即2,6-二烷基萘法和2-烷基-6-酰基萘法。目前,世界上可工业化(包括半工业化)的生产方法仅有美国BP Amoco公司的邻二甲苯DMN法,日本MGC公司的2-甲基-6-乙酰基萘法和日本住金化工公司的2,6-二异丙基萘氧化法。
  • MOL 文件:1141-38-4.mol
  • Hazard Note:Irritant
  • Alfa Aesar:萘-2,6-二甲酸,98+% Naphthalene-2,6-dicarboxylic acid, 98+%(1141-38-4)
  • 用途一:该产品用于制造高强度和染色性能优良的聚酯纤维及F级绝缘材料,是高性能PEN、PBN、液晶聚合物(LCP)及聚氨酯树脂的重要单体,也是医药及精细化学品的重要原料。
  • 上游原料:1,2-二甲苯 --> 草酸 --> 二甲基萘 --> 2,6-二异丙基萘

系列性分类


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