(R)-(-)-alpha-Methoxyphenylacetic acid (R)-(-)-alpha-甲氧基苯乙酸

CAS 3966-32-3 MFCD00004250

化学结构图

3966-32-3
SMILES: CO[C@@H](C(=O)O)c1ccccc1

化学属性

Mol. FormulaC9H10O3
Mol. Weight166.17
Density1.422
Melting Point66-68°C
TSCANo
Boiling Point283.8°C at 760 mmHg
Flash Point164-166°C/18mm
Refractive index-147 ° (C=0.5, EtOH)

别名和识别编码

Chemical Name(R)-(-)-α-Methoxyphenylacetic Acid
CAS Number3966-32-3
EC Number223-580-9
Beilstein Registry Number10(3)451
MDL NumberMFCD00004250
Synonym (R)-2-Methoxy-2-phenylacetic acid {LY} (R)-2-Methoxy-2-phenylacetic acid {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-2-Methoxy-2-phenylacetic acid {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID2724294
Reaxys-RN2209197
Chemical Name Translation(R)-(-)-alpha-甲氧基苯乙酸
InChIKeyDIWVBIXQCNRCFE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010561
InChIInChI=1S/C9H10O3/c1-12-8(9(10)11)7-5-3-2-4-6-7/h2-6,8H,1H3,(H,10,11)/t8-/m1/s1
Canonical SMILESCO[C@@H](C(O)=O)C1=CC=CC=C1
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分类

  • {SNA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {SNA} Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC,

相关文献及参考

  • Chiral derivatization agent for determination of absolute configuration of alcohols by NMR: Topics Stereochem ., 2, 199 (1967); J. Org. Chem., 51, 2370 (1986). Also used in determination of the absolute stereochemistry of chiral amines: J. Org. Chem., 60, 1538 (1995).

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:3966-32-3(sigmaaldrich)
  • (R)-(-)-alpha-甲氧基苯乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0830 (R)-(-)-α-甲氧基苯乙酸 (R)-(-)-alpha-Methoxyphenylacetic Acid 1G 665元 2014/06/02 M0830 (R)-(-)-α-甲氧基苯乙酸 (R)-(-)-alpha-Methoxyphenylacetic Acid 100MG 145元 2014/06/02 M0830 (R)-(-)-α-甲氧基苯乙酸 (R)-(-)-alpha-Methoxyphenylacetic Acid 5G 2250元
  • TCI Shanghai:(R)-(-)-α-甲氧基苯乙酸 (R)-(-)-alpha-Methoxyphenylacetic Acid,>;98.0%(GC)(T)(3966-32-3)
  • Alfa Aesar:(R)-(-)-α-甲氧基苯乙酸,99% (R)-(-)-alpha-Methoxyphenylacetic acid, 99%(3966-32-3)
  • MOL 文件:3966-32-3.mol
  • Acros Organics:?-(-)-alpha-甲氧基苯乙酸 (R)-(-)-alpha-Methoxyphenylacetic acid, 99%(3966-32-3)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Chiral Derivatization Reagents - Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. Chiral - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carboxylic Acid Salts 羧酸盐
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Chiral Derivatization
  4. Chiral GC Derivatization Reagents

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