Dibenzylamine 二苄胺

CAS 103-49-1 MFCD00004770

化学结构图

103-49-1
SMILES: c1ccc(CNCc2ccccc2)cc1

化学属性

Mol. FormulaC14H15N
Mol. Weight197.28
Density1.026
Refractive index1.5740 to 1.5770
Flash Point143°C
TSCAYes
Boiling Point300°C at 760 mmHg
Melting Point-26°C
Solubility0.05 G/L (20 ºC)
Appearance 无色油状液体,有氨臭。 易溶于乙醇及乙醚,不溶于水。
pH:A

别名和识别编码

Chemical NameDibenzylamine
MDL NumberMFCD00004770
CAS Number103-49-1
EC Number203-117-7
Beilstein Registry Number909664
Synonym Dibenzylamine {LY} Dibenzylamine {} {LY} Dibenzylamine {} {} {LY} Dibenzylamine {} {} {} {LY} Dibenzylamine {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibenzylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Merck Number3011
PubChem Substance ID87566880
Alfabeta NameDIBENZYLAMINE
Chemical Name Translation二苄胺
Reaxys-RN909664
LabNetwork Molecule IDLN00180965
InChIInChI=1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
Canonical SMILESC1(CNCC2=CC=CC=C2)=CC=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C14, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 检定钴、铁和氰酸盐。

相关文献及参考

  • Merck:14,3011 Beilstein:12,1035
  • Can be alkylated with alkyl halides in the presence of anhydrous K2CO3 in diglyme. The resulting tertiary amines undergo hydrogenolysis, for example by catalytic transfer using Ammonium formate, A10699, to give primary amines. This sequence thus provides a convenient and milder alternative to the classical Gabriel synthesis: J. Org. Chem., 56, 457 (1991).
  • Short: III/38B
  • Short: IV/20C
  • Short: IV/6
  • Short: IV/16
  • Short: IV/18B
  • Merck:14,3011

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P332+P313+
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
UN Number 2735 UN2735
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C Xn Xn,Xi,C
Warnings IRRITANT
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Store at room temperature {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, pr
Hazard Class8

其他信息

  • MOL 文件:103-49-1.mol
  • 用途一:常用于测定钴、铁及氰酸盐等
  • 检测方法:GC
  • 海关编码:29214980
  • 方法一:由氯苄与液氨在乙醇中反应而得。
  • 用途二:二苄胺是重要的有机合成中间体,可用来合成青霉素和橡胶、塑料固化的熟化剂,主要用来生产高效无毒的硫化促进剂二硫化四苄基秋兰姆(TBZTD)和二苄基二硫代氨基甲酸锌(ZBEC)。
  • TCI Shanghai:二苄胺 Dibenzylamine,>;97.0%(GC)(103-49-1)
  • 二苄胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0152 二苄胺 Dibenzylamine 25G 142元 2014/06/02 D0152 二苄胺 Dibenzylamine 500G 669元 2010/06/21 112612500 二苄胺 Dibenzylamine 98% 250 ML 612元
  • 图谱信息:二苄胺(103-49-1)红外图谱(IR2) 二苄胺(103-49-1)红外图谱(IR1) 二苄胺(103-49-1)核磁图( 1 HNMR) 二苄胺(103-49-1)Raman光谱 二苄胺(103-49-1)红外图谱(IR3) 二苄胺(103-49-1)核磁图( 13 CNMR) 二苄胺(103-49-1)质谱(MS)
  • MSDS 信息:Dibenzylamine(103-49-1).msds
  • Sigma Aldrich:103-49-1(sigmaaldrich)
  • 用途三:检定钴、铁和氰酸盐。
  • Alfa Aesar:二苄胺,98% Dibenzylamine, 98%(103-49-1)
  • Acros Organics:二苄胺 Dibenzylamine, 98%(103-49-1)
  • Hazard Note:Irritant/Corrosive
  • 有氨臭。溶于乙醇和乙醚,几乎不溶于水。有腐蚀性。
  • 上游原料:氨

系列性分类


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