1-Mercaptooctane 1-辛硫醇

CAS 111-88-6 MFCD00004912

化学结构图

111-88-6
SMILES: CCCCCCCCS

化学属性

Mol. FormulaC8 H18 S
Mol. Weight146.294
Refractive index1.4520 to 1.4560
Boiling Point-
Density0.84
Flash Point-
TSCAYes
Melting Point-49
Solubility溶于醇。
Stability对湿度敏感

别名和识别编码

Chemical Name1-Mercaptooctane
Synonym 1-MERCAPTOOCTANE 1-Mercaptooctane 1-Mercaptooctanen-Octyl mercaptan 1-OCTANETHIOL 1-Octanethiol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number111-88-6
PubChem Substance ID87574042
EC Number203-918-1
Beilstein Registry Number1(4)1767
MDL Number-
Reaxys-RN1733101
Chemical Name Translation1-辛硫醇
LabNetwork Molecule IDLN00163395
Canonical SMILES-
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分类

  • Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly and Lithography, Self-Assembly Materials, Thiols, 材料科学
  • {SNA} Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {uni_hamburg} no charge; thiol; 1fragment
  • {SNA} Alkyl Thiols, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols, 材料科学

相关文献及参考

  • Beilstein:1(4)1767
  • Short: II/27B
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 9
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P311
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
UN Number 3082 UN 1170 3/PG 2 UN3082
Packing GroupIII
Storage condition +4 +4°C 4 4°C, Inert atmosphere 4℃ 密封保存。
Hazard Class9
Warnings 危化品目录(2015) 危险化学品

其他信息

  • MOL 文件:111-88-6.mol
  • TCI Shanghai:1-辛硫醇 1-Octanethiol,>;95.0%(GC)(111-88-6)
  • 用途一:该品在合成橡胶生产中用作聚合调节剂及硫化调节剂，也用橡胶助剂、医药、染料、农药的生产。也可作表面活性剂和树脂的稳定剂。
  • 可燃性危险特性:明火可燃; 遇热放出有毒氧化硫气体
  • 有恶臭。溶于乙醇、乙醚、丙酮和苯，不溶于水。有毒。有刺激性。
  • 1-辛硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 O0025 1-辛硫醇 1-Octanethiol 25ML 151元 2014/06/02 O0025 1-辛硫醇 1-Octanethiol 500ML 406元 2010/06/21 157482500 1-辛硫醇 1-Octanethiol 97% 250 GR 341元
  • 海关编码:29309070
  • 毒性分级:中毒
  • 类别:易燃液体
  • 方法一:由溴辛烷与硫氢化钠在硫酸存在下反应而得。也可先由溴辛烷与硫脲缩合，再经水解而制得辛硫醇。
  • Alfa Aesar:1-辛硫醇,98% 1-Octanethiol, 98%(111-88-6)
  • 图谱信息:1-辛硫醇(111-88-6)红外图谱(IR1) 1-辛硫醇(111-88-6)核磁图( 1 HNMR) 1-辛硫醇(111-88-6)质谱(MS) 1-辛硫醇(111-88-6)核磁图( 13 CNMR) 1-辛硫醇(111-88-6)红外图谱(IR2)
  • MSDS 信息:辛硫醇(111-88-6).msds
  • 上游原料:硫脲 --> 硫氢化钠 --> 1-溴辛烷
  • 储运特性:库房通风低温干燥; 与食品、酸类、氧化剂分开储运
  • 灭火剂:泡沫、干粉、二氧化碳
  • 急性毒性:口服- 大鼠 LD50: 2000 毫克/ 公斤
  • Acros Organics:1-辛硫醇 1-Octanethiol, 97%(111-88-6)
  • Sigma Aldrich:111-88-6(sigmaaldrich)
  • 外观性质:水白色液体，略有气味。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  6. Alkyl Thiols - Thiols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts
  1. Functional Group 官能团索引
  2. alkylthiol