3,4-Epoxy-1-Butene 3,4-环氧-1-丁烯

CAS 930-22-3 MFCD00005149

化学结构图

930-22-3
SMILES: C=CC1CO1

化学属性

Mol. FormulaC4H6O
Mol. Weight70.09
Refractive index1.4150 to 1.4190
Boiling Point67°C(lit.)
Density0.870
Flash Point-50°C
TSCAYes
Melting Point-135°C

别名和识别编码

Chemical Name3,4-Epoxy-1-Butene
Synonym (±)-Vinyloxirane 1,2-EB 1,2-EPOXY-3-BUTENE 1,2-Epoxy-3-butene 1,2-Epoxy-3-butylene 1,2-Epoxybutene-3 1,2-epoxybutene 1,2-epoxybutene-3 1,3-BUTADIENE MONOEPOXIDE 1,3-Butadiene Monoepoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number930-22-3
PubChem Substance ID13586
EC Number213-210-4
Beilstein Registry Number17(1)13
MDL NumberMFCD00005149
Reaxys-RN103170
Chemical Name Translation3,4-环氧-1-丁烯
Wiswesser Line NotationT3OTJ B1U1
LabNetwork Molecule IDLN01742192
InChIInChI=1S/C4H6O/c1-2-4-3-5-4/h2,4H,1,3H2
Canonical SMILESC=CC1CO1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; ether; racemate; 1fragment
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beilstein:17(1)13
  • Reaction with allyl bromide, mediated by In metal, affords diallylmethanol: Tetrahedron Lett., 44, 2911 (2003):
  • Short: II/14a
  • Short: II/2
  • Short: II/25C

安全信息

GHS Symbol
WGK Germany2
Hazard Codes F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEM7350000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P303+P361+P353
  • P305+P351+P338
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number UN 1993 3/PG 2 1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
Storage condition 2-8°C 2-8°C, stored under nitrogen Moisture Sensitive 存储温度2-8℃
Packing GroupII
Hazard Class3
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 492 gm/kg/41W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   31,41,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 168 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   52,422,1980

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 80 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 391,233,1997

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Net

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   BBRCA9 Biochemical and Biophysical Research Communications.  (Academic
   Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1959-
   Volume(issue)/page/year: 80,298,1978

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 1 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 18,168

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 263,47,1991

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 33300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYP

其他信息

  • F:21
  • Sigma Aldrich:930-22-3(sigmaaldrich)
  • 环氧丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0337 1,3-丁二烯单环氧化物 1,3-Butadiene Monoepoxide 5G 1390元 2014/06/02 E0337 1,3-丁二烯单环氧化物 1,3-Butadiene Monoepoxide 1G 474元 2010/06/21 155790010 环氧丁烯 Butadiene monoxide 97% 1 GR 889元
  • 用途一:新型精细化工产品,可以进一步制成1,4-丁二醇、四氢呋喃,环丙胺等产品,在化纤,医药等行业有重要用途。
  • 无色透明至微黄色液体,不溶于水
  • TCI Shanghai:环氧丁烯 1,3-Butadiene Monoepoxide,>;97.0%(GC)(930-22-3)
  • 外观性质:无色透明至微黄色液体,不溶于水密度:0.87 熔点:-135 °C 沸点:65-66 °C 闪点:-50 °C 折光率:1.416-1.42
  • Alfa Aesar:环氧丁烷,98% Butadiene monoxide, 98%(930-22-3)
  • 敏感性:Moisture Sensitive
  • MOL 文件:930-22-3.mol
  • Acros Organics:环氧丁烯 Butadiene monoxide, 97%(930-22-3)

系列性分类


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