6-Benzylaminopurine 6-苄基腺嘌呤

CAS 1214-39-7 MFCD00005572

化学结构图

1214-39-7
SMILES: c1ccc(CNc2ncnc3nc[nH]c23)cc1

化学属性

Mol. FormulaC12
Mol. Weight225
Density1.393
Melting Point230-233
TSCAT
Flash Point103 °F
Boiling Point145 °C(lit.)
SolubilityH2O: soluble
Refractive indexn20/D 1.418(lit.)

别名和识别编码

Chemical Name6-Benzylaminopurine
CAS Number1214-39-7
Alfabeta NameBENZYLAMINOPURINE 6-
MDL NumberMFCD00005572
Synonym 2-PROPENOIC ACID BUTYL ESTER 2-苄氨基嘌呤 6-BA 6-BAP 6-BENZYLAMINOPURINE 6-Benzyladenine 6-苄基腺嘌呤 6-苄氨基嘌呤 6-苄氨基嘌呤/苄基腺嘌呤 6-苯甲基腺嘌呤,6-(N-苄基)氨基嘌呤,6-苄基氨基嘌呤 ACRYLIC ACID N-BUTYL ESTER BA BA BAP N6-苄基腺嘌呤 BA, N6-Benzyladenine BAP (growth stimulant) BENZYL-(7H-PURIN-6-YL)-AMINE BENZYLADENINE BENZYLAMINOPURINE, 6- Benzylaminopurine N-(Phenylmethyl)-1H-purin-6-amine N6-BENZYLADENINE N6-苄基腺嘌呤 SD 4901 丙烯酸丁脂 丙烯酸丁酯 丙烯酸酯 苄胺嘌呤
PubChem Substance ID62389
Beilstein Registry Number616790
EC Number214-927-5
Reaxys-RN616790
Chemical Name Translation6-苄基腺嘌呤
LabNetwork Molecule IDLN00173405
InChIInChI=1S/C12H11N5/c1-2-4-9(5-3-1)6-13-11-10-12(15-7-14-10)17-8-16-11/h1-5,7-8H,6H2,(H2,13,14,15,16,17)
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分类

  • {SNA} A - D, Alphabetical, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, B, BA - BH, Chromatography,
  • {SNA} Cytokinin
  • {SNA} A - D, Alphabetical, Alphabetical Index of Analytical Standards, Analytical Standards, B, BA - BH, Chromatography, Life Sciences Standards, Natural Compounds, Phytopharma Standards, 分析/色谱
  • {
  • {SNA} Auxins, 分子生物学, 植物生物技术, 植物生长调节剂, 植物组织培养
  • {SNA} A - D,
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks,

产品应用

  • 6-BA是第一个人工合成的细胞分裂素。具有抑制植物叶内叶绿素、核酸、蛋白质的分解,保绿防老;将氨基酸、生长素、无机盐等向处理部位调运等多种效能,广泛用在农业、果树和园艺作物从发芽到收获的各个阶段。

相关文献及参考

  • Tepe B, Sokmen A., Production and optimisation of rosmarinic acid by Satureja hortensis L. callus cultures. Nat. Prod. Res. 21 , 1133-1144, (2007) 摘要
  • Tariq M, Ali G, Hadi F, et al., Callus induction and in vitro plant regeneration of rice (Oryza sativa L.) under various conditions. Pak. J. Biol. Sci. 11 , 255-259, (2008) 摘要
  • Rathore MS, Chikara J, Shekhawat NS., Plantlet regeneration from callus cultures of selected genotype of Aloe vera L.--an ancient plant for modern herbal industries. Appl. Biochem. Biotechnol. 163 , 860-868, (2011) 摘要
  • Rosnow J, Offermann S, Park J, et al., In vitro cultures and regeneration of Bienertia sinuspersici (Chenopodiaceae) under increasing concentrations of sodium chloride and carbon dioxide. Plant Cell Rep. , (2011)

安全信息

Warnings IRRITANT
RTECSAU6252200
WGK Germany2
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H303+H313
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xi
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 阴凉干燥处保存 2-8°C
UN Number UN 2348 3/PG 3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2125 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   TOIZAG Toho Igakkai Zasshi.  Journal of Medical Society of Toho University.
   (Toho Daigaku Igakkai, 21-16, Omori-nishi, 5-chome, Ota-ku, Tokyo 143,
   Japan)  V.1-    1954-  Volume(issue)/page/year: 19,336,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOIZAG Toho Igakkai Zasshi.  Journal of Medical Society of Toho University.
   (Toho Daigaku Igakkai, 21-16, Omori-nishi, 5-chome, Ota-ku, Tokyo 143,
   Japan)  V.1-    1954-  Volume(issue)/page/year: 19,336,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   TOIZAG Toho Igakkai Zasshi.  Journal of Medical Society of Toho University.
   (Toho Daigaku Igakkai, 21-16, Omori-nishi, 5-chome, Ota-ku, Tokyo 143,
   Japan)  V.1-    1954-  Volume(issue)/page/year: 19,336,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOIZAG Toho Igakkai Zasshi.  Journal of Medical Society of Toho Univers

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 32,29,1976

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 10 umol/L
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 32,29,1976

其他信息

  • 毒性:LD 50 2965mg/kg(大鼠,口授)。 各致突变试验均阴性。
  • MOL 文件:1214-39-7.mol
  • Acros Organics:6-苄氨基嘌呤 6-Benzylaminopurine, 99%(1214-39-7)
  • 毒性分级:中毒
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) 6-苄基腺嘌呤 食品 食品工业用加工助剂 / 食品工业用加工助剂一般应在制成最后成品之前出去,有规定食品中残留量的除外
  • 上游原料:甲醇 --> 丙烯酸 --> 卡波姆树脂
  • MSDS 信息:N-
  • TCI Shanghai:N-6-苄基腺嘌呤 N6-Benzyladenine,>;99.0%(LC)(T)(1214-39-7)
  • 参考质量标准:中国企标 含量 ≥98.0% 熔点 226℃ 杂质(薄层法) 检不出
  • 用途三:细胞分裂刺激素。
  • 蒸气压:3.3 mm Hg ( 20 °C)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 急性毒性:口服-大鼠 LD50: 2125 毫克/公斤; 口服-小鼠 LD50: 1300 毫克/公斤
  • 用途四:6-BA是第一个人工合成的细胞分裂素。具有抑制植物叶内叶绿素、核酸、蛋白质的分解,保绿防老;将氨基酸、生长素、无机盐等向处理部位调运等多种效能,广泛用在农业、果树和园艺作物从发芽到收获的各个阶段。
  • 海关编码:29335995
  • 储运特性:通风低温干
  • 下游产品:卡波姆树脂 --> 丙烯酸正丁酯 --> 丙酮酸乙酯 --> 丙酮酸 --> 涂料 --> 丙烯酸酯三元共聚物负载双硫铂配合物催化剂 --> 聚丙烯酸钠 --> 苯丙乳液 --> 二异氰酸酯改性的EAM树脂用作口腔正畸胶粘剂 --> 洛开酰胺 --> 苯磺酸阿曲库铵 --> 聚氨酯型光敏树脂预聚体 --> 网版感光胶 SF --> 丙烯酸树脂涂饰剂 --> 纯丙乳液 --> 无纺布胶 --> 6-苄氨基嘌呤 --> 1-异丙基-4-哌啶酮 --> N-(4-氯苯基)-1-(1-甲基乙基)-4-哌啶胺 --> 偶联剂NBC-1 --> 压敏胶 --> 热塑性丙烯酸树脂 --> 4-氯-N-[1-(1-甲基乙基)-4-亚哌啶基]苯胺 --> LHYJ-DS50型丁二烯树脂乳液 --> 502快干胶 --> 二氢茉莉酮 --> 甲基-2-(2′-羟基苯基)-3-甲氧基丙烯酸酯 --> FX-1 丙烯酸树脂乳液 --> 硅丙乳液 --> 电泳漆 --> BC-01建筑乳液 --> SB树脂 --> NBJ型喷水织机专用浆料 --> JT-22
  • Sigma Aldrich:1214-39-7(sigmaaldrich)
  • 用途二:是制造胶粘剂、合成树脂、特种橡胶和塑料的单体
  • 6-苄氨基嘌呤价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 65002931 6-(苄胺基)嘌呤(+4℃) 1g 12元 2011/08/23 65002936 6-(苄胺基)嘌呤(+4℃) 100g 600元 2011/04/16 B1088 N6-苄基腺嘌呤 N6-Benzyladenine 25G 2080元
  • 使用限量:GB 2760-96:发黄豆芽、绿豆芽用,0.01g/kg,残留量≤0.2mg/kg。
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • {Chemicalbook
  • 类别:农药
  • 图谱信息:6-苄氨基嘌呤(1214-39-7)核磁图( 13 CNMR) 6-苄氨基嘌呤(1214-39-7)质谱(MS) 6-苄氨基嘌呤(1214-39-7)红外图谱(IR2) 6-苄氨基嘌呤(1214-39-7)核磁图( 1 HNMR) 6-苄氨基嘌呤(1214-39-7)红外图谱(IR1)

系列性分类