2-Phenylindole 2-苯基吲哚

CAS 948-65-2 MFCD00005608

化学结构图

948-65-2
SMILES: c1ccc(-c2cc3ccccc3[nH]2)cc1

化学属性

Mol. FormulaC14H11N
Mol. Weight193.25
Density1.156
Melting Point188-190°C
TSCAYes
Boiling Point250 °C at 10 mmHg
Flash Point250°C/10mm
Appearance 黄色或酱红色叶状结晶。 溶于乙醚、苯、乙酸、氯仿和热二硫化碳,微溶于热水,不溶于稀无机酸。

别名和识别编码

Chemical Name2-Phenylindole
Synonym 2-Phenyl-1H-indole {LY} 2-Phenyl-1H-indole {} {LY} 2-Phenyl-1H-indole {} {} {LY} 2-Phenyl-1H-indole {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} { {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Phenyl-1H-indole {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00005608
CAS Number948-65-2
EC Number213-436-3
Beilstein Registry Number132356
PubChem Substance ID13698
Reaxys-RN132356
Chemical Name Translation2-苯基吲哚
LabNetwork Molecule IDLN00222486
InChIInChI=1S/C14H11N/c1-2-6-11(7-3-1)14-10-12-8-4-5-9-13(12)15-14/h1-10,15H
Canonical SMILESN1C(=CC2=C1C=CC=C2)C1=CC=CC=C1
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Building Blocks, C13 to C27, Chemical Synthesis, Heterocyclic Building Blocks, Indoles
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 1fragment

相关文献及参考

  • Short: II/3
  • Short: EINECS
  • Beilstein:20,467

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSNM1272500
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >6 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 10,44,1960

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:乙醇 --> 乙酸 --> 丙酮 --> 多聚磷酸 --> 乙酰苯 --> 苯肼 --> 联苯 --> 苯甲酰胺 --> 2-溴苯乙酮
  • Alfa Aesar:2-苯基吲哚,95% 2-Phenylindole, 95%(948-65-2)
  • Acros Organics:2-Phenylindole, 99%(948-65-2)
  • 2-苯基吲哚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0188 2-苯基吲哚 2-Phenylindole 250G 1320元 2014/06/02 P0188 2-苯基吲哚 2-Phenylindole 25G 228元 2010/06/21 130685000 2-苯基吲哚 2-Phenylindole 99% 500 GR 4401元
  • MOL 文件:948-65-2.mol
  • 图谱信息:2-苯基吲哚(948-65-2)核磁图( 1 HNMR) 2-苯基吲哚(948-65-2)红外图谱(IR2) 2-苯基吲哚(948-65-2)红外图谱(IR1) 2-苯基吲哚(948-65-2)核磁图( 13 CNMR) 2-苯基吲哚(948-65-2)质谱(MS)
  • 检测方法:HPLC
  • 用途二:该品主要作为阳离子染料中间体,用于生产阳离子橙2GL、阳离子红BL、阳离子红2GL,用于染料生产时往往先经甲基化,进一步制成N-甲基-2-苯基吲哚。甲基化剂为硫酸二甲酯,反应在氯苯溶剂中进行,在60-65℃反应,收率为83.5%。2-苯基吲哚也用作乳液法聚氯乙烯的热稳定剂。
  • MSDS 信息:2-Phenylindole(948-65-2).msds
  • Sigma Aldrich:948-65-2(sigmaaldrich)
  • 下游产品:阳离子黄 X-3RL
  • TCI Shanghai:2-苯基-1H-吲哚 2-Phenylindole,>;98.0%(GC)(948-65-2)
  • 用途一:用作PVC玻璃纸稳定剂及染料中间体
  • 方法一:由苯肼与苯乙酮缩合后,再在氯化锌存在下闭环而制得2-苯基吲哚。除上述的Fisher法外,可将溴代苯乙酮与过量的苯胺加热反应,或将N-(2-甲基苯基)苯甲酰胺和乙醇钠隔绝空气于360-380℃加热,都可制得2-苯基吲哚。原料消耗定额:苯乙酮(98%)735kg/t、苯肼(游离100%)675kg/t、二甲苯900kg/t、冰醋酸15kg/t、氯化锌1230kg/t、盐酸(30%)810kg/t。

系列性分类