N-(Bromomethyl)phthalimide N-溴甲基邻苯二甲酰亚胺

CAS 5332-26-3 MFCD00005897

化学结构图

5332-26-3
SMILES: O=C1c2ccccc2C(=O)N1CBr

化学属性

Mol. FormulaC9H6BrNO2
Mol. Weight240.05
Melting Point152-155°C
TSCAYes
Solubility分解
Appearance 白色粉末
Boiling Point318.9°C at 760 mmHg

别名和识别编码

Chemical Name2-(Bromomethyl)Isoindoline-1,3-Dione
MDL NumberMFCD00005897
CAS Number5332-26-3
Synonym 2-(Bromomethyl)isoindoline-1,3-dione {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)isoindoline-1,3-dione {} {} {} {} {} {} {} {}
PubChem Substance ID79244
Beilstein Registry Number21,476
EC Number226-239-2
Alfabeta NameBROMOMETHYLPHTHALIMIDE N()-
Reaxys-RN140943
Chemical Name TranslationN-溴甲基邻苯二甲酰亚胺
LabNetwork Molecule IDLN00009028
InChIKeyUUSLLECLCKTJQF-UHFFFAOYSA-N
InChIInChI=1S/C9H6BrNO2/c10-5-11-8(12)6-3-1-2-4-7(6)9(11)13/h1-4H,5H2
Canonical SMILESO=C1N(CBr)C(C2=C1C=CC=C2)=O
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Cyclic Imides, Organic Building Blocks

相关文献及参考

  • Arbuzov reaction with triethyl phosphite followed by cleavage with hydrazine hydrate provides a route to diethyl (aminomethyl)phosphonate. Protection as the benzylidene derivative permits the use of this phosphonate in the Wadsworth-Emmons reaction: Org. Synth. Coll., 8, 451 (1993) and references therein.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen Moisture & Light Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, pro
Hazard Codes Xi
Warnings IRRITANT

其他信息

  • F:8-10-21
  • MSDS 信息:N-(Bromomethyl)phthalimide(5332-26-3).msds
  • 图谱信息:N-溴甲基邻苯二甲酰亚胺(5332-26-3)质谱(MS) N-溴甲基邻苯二甲酰亚胺(5332-26-3)红外图谱(IR1) N-溴甲基邻苯二甲酰亚胺(5332-26-3)核磁图( 13 CNMR) N-溴甲基邻苯二甲酰亚胺(5332-26-3)红外图谱(IR2) N-溴甲基邻苯二甲酰亚胺(5332-26-3)核磁图( 1 HNMR)
  • N-溴甲基邻苯二甲酰亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1192 N-(溴甲基)邻苯二甲酰亚胺 N-(Bromomethyl)phthalimide 5G 292元 2014/06/02 P1192 N-(溴甲基)邻苯二甲酰亚胺 N-(Bromomethyl)phthalimide 25G 844元 2010/06/21 403070250 N-溴甲基邻苯二甲酰亚胺 N-(Bromomethyl)phthalimide 97% 25 GR 1515元
  • 敏感性:Moisture & Light Sensitive
  • Sigma Aldrich:5332-26-3(sigmaaldrich)
  • MOL 文件:5332-26-3.mol
  • Alfa Aesar:N-(溴甲基)邻苯二甲酰亚胺,95% N-(Bromomethyl)phthalimide, 95%(5332-26-3)
  • Acros Organics:N-(溴甲基)苯邻二甲酰亚胺 N-(Bromomethyl)phthalimide, 97%(5332-26-3)
  • 海关编码:29251995
  • TCI Shanghai:N-溴甲基邻苯二甲酰亚胺 N-(Bromomethyl)phthalimide,>;96.0%(T)(5332-26-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Cyclic Imides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids
  6. C9

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