2,4,6-Trichloropyrimidine 2,4,6-三氯嘧啶

CAS 3764-01-0 MFCD00006063

化学结构图

3764-01-0
SMILES: Clc1cc(Cl)nc(Cl)n1

化学属性

Mol. FormulaC4HCl3N2
Mol. Weight183.42
Boiling Point212.7°C at 760 mmHg
Melting Point23-25°C
TSCAT
Refractive indexn20/D 1.57(lit.)
Density1.595
Flash Point113°C
Appearance 白色晶体,熔点23-25℃,沸点210-215℃
pH:A

别名和识别编码

Chemical Name2,4,6-Trichloropyrimidine
CAS Number3764-01-0
Alfabeta NameTRICHLOROPYRIMIDINE 246-,,
MDL NumberMFCD00006063
Synonym 2,4,6-Trichloropyrimidine {LY} 2,4,6-Trichloropyrimidine {} {LY} 2,4,6-Trichloropyrimidine {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Trichloropyrimidine {} {} {} {}
PubChem Substance ID77378
EC Number223-183-0
Beilstein Registry Number118284
Reaxys-RN118284
Chemical Name Translation2,4,6-三氯嘧啶
InChIKeyDPVIABCMTHHTGB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008319
Canonical SMILESClC1=CC(Cl)=NC(Cl)=N1
InChIInChI=1S/C4HCl3N2/c5-2-1-3(6)9-4(7)8-2/h1H
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分类

  • Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines

产品应用

  • Fungitoxic substance.

相关文献及参考

  • Beilstein:23,90
  • Coteron, J., et al.: J. Med. Chem., 53, 6129 (2010),
  • Read, M., et al.: Bioorg. Med. Chem., 18, 3885 (2010),
  • Selective Suzuki coupling with arylboronic acids has been reported to give 6-arylpyrimidines: J. Heterocycl. Chem., 43, 127 (2006).
  • Short: EINECS
  • Short: III/20a

安全信息

Warnings IRRITANT, AVOID SKIN CONTACT
GHS Symbol
WGK Germany3
Hazard Codes Xn,Xi,T Xn Xi
Hazard statements
  • H300 Fatal if swallowed 吞食致命
  • H302 Harmful if swallowed 吞食有害
  • H310 Fatal in contact with skin 皮肤接触致命
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P302+P361+P354
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number UN1759
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
Hazard Class8
Storage condition -20°C, sealed storage, away from moisture {LY} -20°C, sealed storage, away from moisture {} {LY} -20°C, sealed storage, away from moisture {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed

其他信息

  • TCI Shanghai:2,4,6-三氯嘧啶 2,4,6-Trichloropyrimidine,>;98.0%(GC)(3764-01-0)
  • MSDS 信息:2,4,6-Trichloropyrimidine(3764-01-0).msds
  • 图谱信息:2,4,6-三氯嘧啶(3764-01-0)核磁图( 1 HNMR) 2,4,6-三氯嘧啶(3764-01-0)核磁图( 13 CNMR) 2,4,6-三氯嘧啶(3764-01-0)质谱(MS) 2,4,6-三氯嘧啶(3764-01-0)红外图谱(IR1)
  • 检测方法:GC
  • 下游产品:4,6-二甲氧基嘧啶-2-磺酰氯 --> 2,4-二氨基-6-氟嘧啶 --> 4-氨基-2,6-二氟嘧啶 --> 2-氨基-4,6-二氟嘧啶
  • 用途一:用作染料中间体
  • 2,4,6-三氯嘧啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0417 2,4,6-三氯嘧啶 2,4,6-Trichloropyrimidine 500G 1380元 2014/06/02 T0417 2,4,6-三氯嘧啶 2,4,6-Trichloropyrimidine 25G 235元 2010/06/21 139491000 2,4,6-三氯嘧啶 2,4,6-Trichloropyrimidine 99% 100 GR 2629元
  • MOL 文件:3764-01-0.mol
  • Sigma Aldrich:3764-01-0(sigmaaldrich)
  • Acros Organics:2,4,6-Trichloropyrimidine, 99%(3764-01-0)
  • TSCA:T
  • Alfa Aesar:2,4,6-三氯嘧啶,98% 2,4,6-Trichloropyrimidine, 98%(3764-01-0)

系列性分类


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