N,N-Dimethylpiperazine 1,4-二甲基哌嗪

CAS 106-58-1 MFCD00006156

化学结构图

106-58-1
SMILES: CN1CCN(C)CC1

化学属性

Mol. FormulaC6 H14 N2
Mol. Weight114.19
Refractive index1.4450 to 1.4480
Boiling Point
Density0.844
Flash Point25°C(lit.)
TSCAYes
Melting PointNo Data Available
SolubilityMISCIBLE

别名和识别编码

Chemical NameN,N-Dimethylpiperazine
CAS Number106-58-1
PubChem Substance ID7818
EC Number203-412-0
MDL NumberMFCD00006156
Reaxys-RN103022
Beilstein Registry Number103022
Synonym 1,4-dimethyl-piperazin 1,4-dimethyl-piperazine Lupetazine N,N'-Dimethylpiperazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation1,4-二甲基哌嗪
Wiswesser Line NotationT6N DNTJ A1 D1
LabNetwork Molecule IDLN00117026
InChIInChI=1S/C6H14N2/c1-7-3-5-8(2)6-4-7/h3-6H2,1-2H3
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分类

  • {SNA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines
  • Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines
  • {uni_hamburg} no charge; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; 1fragment

产品应用

  • 聚氨酯泡沫的催化剂和阳离子表面活性剂的中间体。

相关文献及参考

  • Beil. 23 ,7
  • Aldrich MSDS 1 , 795:D / Corp MSDS 1 (1), 1409:A / FT-IR 1 (1), 371:D / FT-IR 2 (1), 579:C / FT-NMR 1 (1), 582:B / IR-Spectra (3), 220:C / IR-Spectra (2), 197:H / NMR-Reference 2 (1), 327:A / RegBook 1 (1), 391:N / Structure Index 1 , 56:D:4 / Vapor Phase 3 , 463:D
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Y

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 3 F,C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTL5945000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2924
Risk Statements
  • R10 Flammable 易燃
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
Hazard Class3/8
Storage condition -20 -20°C -20℃ Flammables area
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   THERAP Therapie.  (Doin, Editeurs, 8, Place de l'Odeon, F-75006 Paris,
   France)  V.1-    1946-  Volume(issue)/page/year: 9,314,1954

Restrict 危险品

其他信息

  • Alfa Aesar:N,N'-二甲基哌嗪,98% 1,4-Dimethylpiperazine, 98%(106-58-1)
  • MSDS 信息:1,4-二甲基哌嗪(106-58-1).msds
  • TCI Shanghai:N,N'-二甲基哌嗪 N,N'-Dimethylpiperazine,>;98.0%(GC)(T)(106-58-1)
  • 毒性分级:中毒
  • 海关编码:29335995
  • 急性毒性:皮下- 小鼠 LD50: 2500 毫克/ 公斤
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有毒氮氧化物烟雾
  • 图谱信息:1,4-二甲基哌嗪(106-58-1)红外图谱(IR2) 1,4-二甲基哌嗪(106-58-1)核磁图( 13 CNMR) 1,4-二甲基哌嗪(106-58-1)质谱(MS) 1,4-二甲基哌嗪(106-58-1)Raman光谱 1,4-二甲基哌嗪(106-58-1)红外图谱(IR1) 1,4-二甲基哌嗪(106-58-1)核磁图( 1 HNMR)
  • 类别:易燃液体
  • Acros Organics:N,N'-二甲基哌嗪 N,N'-Dimethylpiperazine, 98.50%(106-58-1)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • MOL 文件:106-58-1.mol
  • 外观性质:无色挥发性液体。
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 存储注意事项:热敏感
  • 1,4-二甲基哌嗪价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010336 N,N-二甲基哌嗪 100ml 300元 2011/04/16 D0787 N,N'-二甲基哌嗪 N,N'-Dimethylpiperazine 500ML 1200元 2011/04/16 D0787 N,N'-二甲基哌嗪 N,N'-Dimethylpiperazine 25ML 233元
  • 用途一:用作医药中间体及表面活性剂
  • Sigma Aldrich:106-58-1(sigmaaldrich)

系列性分类


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