2-(METHYLAMINO)PYRIDINE 2-甲氨基吡啶

CAS 4597-87-9 MFCD00006250

化学结构图

4597-87-9
SMILES: CNc1ccccn1

化学属性

Mol. FormulaC6H8N2
Mol. Weight108.14
Density1.052 g/mL at 25 °C(lit.)
Refractive index1.5760 to 1.5800
Flash Point102°C(lit.)
TSCANo
Boiling Point200-201 °C at 760 mmHg
Melting Point15 °C

别名和识别编码

Chemical Name2-(METHYLAMINO)PYRIDINE
MDL NumberMFCD00006250
CAS Number4597-87-9
EC Number224-997-9
Beilstein Registry Number22(3/4)3847
PubChem Substance ID20727
Synonym N-Methylpyridin-2-amine {LY} N-Methylpyridin-2-amine {} {LY} N-Methylpyridin-2-amine {} {} {LY} N-Methylpyridin-2-amine {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Methylpyridin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation2-甲氨基吡啶
Reaxys-RN108188
Wiswesser Line NotationT6NJ BM1
InChIKeySVEUVITYHIHZQE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195317
InChIInChI=1S/C6H8N2/c1-7-6-4-2-3-5-8-6/h2-5H,1H3,(H,7,8)
Canonical SMILESCNC1=NC=CC=C1
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

安全信息

RTECSUT5500000
Packing GroupIII
UN Number UN2810
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xn
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
REFERENCE :
   APFRAD Annales Pharmaceutiques Francaises.  (SPPIF, B.P.22, F-41353 Vineuil,
   France)  V.1-    1943-  Volume(issue)/page/year: 26,345,1968

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:二氯甲烷 --> 硫酸钠 --> 氢氧化钾 --> 正己烷 --> 硅凝胶 --> 2-溴吡啶 --> N-甲基甲酰胺
  • Alfa Aesar:2-(甲氨基)吡啶,98% 2-(Methylamino)pyridine, 98%(4597-87-9)
  • 检测方法:GC
  • Sigma Aldrich:4597-87-9(sigmaaldrich)
  • TCI Shanghai:2-甲氨基吡啶 2-(Methylamino)pyridine,>;98.0%(GC)(T)(4597-87-9)
  • MOL 文件:4597-87-9.mol
  • 2-甲基氨基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0823 2-(甲氨基)吡啶 2-(Methylamino)pyridine 500G 7420元 2014/06/02 M0823 2-(甲氨基)吡啶 2-(Methylamino)pyridine 25G 928元 2010/05/25 B23589 2-(甲氨基)吡啶, 98% 2-(Methylamino)pyridine, 98% 25g 1778元

系列性分类