2-Vinylpyridine, 98%, stabilized with TBC 2-乙烯基吡啶

CAS 100-69-6 MFCD00006355

化学结构图

100-69-6
SMILES: C=Cc1ccccn1

化学属性

Mol. FormulaC7H7N
Mol. Weight105
Density0.975
Refractive index1.5480 to 1.5520
Boiling Point79-82
Vapor Pressure10 mmHg ( 44.5 °C)
Flash Point46°C(lit.)
TSCAYes
Melting Point-50
Solubility溶于水，溶于普通溶剂。
Stability对热和空气敏感

别名和识别编码

Chemical Name2-Vinylpyridine, 98%, stabilized with TBC
CAS Number100-69-6
EC Number202-879-8
Beilstein Registry Number104505
MDL NumberMFCD00006355
Synonym {uni_hamburg} 2-吡啶基乙烯 2-VINYLPYRIDINE 2-VINYLPYRIDINE, 97%, STAB. WITH 0.1% 4-TERT-BUTYLCATECHOL 2-乙烯基吡啶 2-Ethenylpryridine 2-Vinylpyridine (stabilized with TBC) 2-乙烯吡啶, 97%, STAB. WITH 0.1% 4-叔-丁基邻苯二酚 2-vinyl-pyridin Pyridine, 2-vinyl- 2-Vinylpyridine monomer 2-VINYLPYRIDINE MONOMER, STAB. (2-Pyridyl)-ethylen 2VP 2-乙烯基吡啶 单体 2-乙烯吡啶 2-乙烯吡啶, 97%, STAB. WITH 0.1% 4-TERT-BUTYLCATECHOL 2-ethenyl-pyridin 2- 乙烯基氮苯 2-vinylpyridine monomer α-Vinylpyridine 2-乙烯基氮苯 2-Ethenylpyridine alpha-Vinylpyridine 2-Vinylpyridine, stabilized, 97% Pyridine, 2-ethenyl- 2-Vinylpyridine 2-乙烯(基)吡啶 2-Vinylpyridine (monomer) 2-Pyridylethylene 2-vinyl-pyridine 2-Ethenyl-pyridin 2-丁吡 2-乙烯基吡啶,2-乙烯基氮苯 2-VINYLPYRIDINE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL 2-vinylpyridine 2-乙烯基吡
PubChem Substance ID7521
Reaxys-RN104505
Chemical Name Translation2-乙烯基吡啶
LabNetwork Molecule IDLN00008385
InChIInChI=1S/C7H7N/c1-2-7-5-3-4-6-8-7/h2-6H,1H2
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分类

  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学

产品应用

  • 该品与丁二烯、苯乙烯共聚可制成乙烯基吡啶改性的胶乳，也用于粘结剂。聚2-乙烯吡啶氧化得到防治矽肺病的药物克矽平；该品也是血管扩张药培他啶盐酸盐的中间体。还用于照相底片消晕层及高分子电解质。

相关文献及参考

  • Short: IV/6
  • Beilstein:20,256
  • Reacts with chlorocarbenes, generated photochemically, thermally or with ultrasound to give indolizines in one step: J. Chem. Soc., Chem. Commun., 509 (1994); e.g., chlor
  • Short: III/38B
  • Short: EINECS
  • Reacts with chlorocarbenes, generated photochemically, thermally or with ultrasound to give indolizines in one step: J. Chem. Soc., Chem. Commun., 509 (1994); e.g., chlorophenylcarbene, generated thermally from 3-chloro-3-phenyldiazirine:
  • Short: IV/18B

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R10 Flammable 易燃
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P301+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P233
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUU1040000
Packing GroupII
UN Number UN 3073 6.1/PG 2
Hazard Codes T C,N
Storage condition <;0 <0°C 2-8°C 储存温度-20℃
Hazard Class6.1/3, 8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 460 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(i

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 420 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 10(3),9,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,845,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 610 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 57(9-10),64,1992

Restrict 危险品

其他信息

  • 蒸气压:10 mm Hg ( 44.5 °C)
  • Sigma Aldrich:100-69-6(sigmaaldrich)
  • 下游产品:N-甲基-N-2-(2-吡啶基)胺 --> 丁吡胶乳
  • Acros Organics:2-乙烯基吡啶 2-Vinylpyridine, stabilized, 97%(100-69-6)
  • 上游原料:2-羟乙基吡啶
  • Hazard Note:Toxic
  • Alfa Aesar:2-乙烯吡啶,97%,stab.with0.1%4-tert-butylcatechol 2-Vinylpyridine, 97%, stab. with 0.1% 4-tert-butylcatechol(100-69-6)
  • TCI Shanghai:2-乙烯基吡啶(含稳定剂叔丁基邻苯二酚) 2-Vinylpyridine (stabilized with TBC),>;97.0%(GC)(100-69-6)
  • 用途一:主要用于合成丁苯吡胶乳，也用于制造克矽平、倍他定盐酸盐等药物
  • F:8-19
  • MOL 文件:100-69-6.mol
  • 存储注意事项:热敏感
  • 用途二:该品与丁二烯、苯乙烯共聚可制成乙烯基吡啶改性的胶乳，也用于粘结剂。聚2-乙烯吡啶氧化得到防治矽肺病的药物克矽平；该品也是血管扩张药培他啶盐酸盐的中间体。还用于照相底片消晕层及高分子电解质。
  • 类别:易燃物质
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 方法一:由2-羟乙基吡啶脱水而得。
  • 图谱信息:2-乙烯基吡啶(100-69-6)质谱(MS) 2-乙烯基吡啶(100-69-6)核磁图( 13 CNMR) 2-乙烯基吡啶(100-69-6)红外图谱(IR1) 2-乙烯基吡啶(100-69-6)核磁图( 1 HNMR)
  • 可燃性危险特性:明火可燃; 受热分解有毒氧化氮气体
  • 2-乙烯基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K9504001 2-乙烯吡啶单聚物 100ml 331元 2011/04/16 V0024 2-乙烯基吡啶(含稳定剂TBC) 2-Vinylpyridine (stabilized with TBC) 25ML 142元 2011/04/16 V0024 2-乙烯基吡啶(含稳定剂TBC) 2-Vinylpyridine (stabilized with TBC) 500ML 931元
  • 外观性质:无色液体, 有恶臭, 易挥发。
  • 无色液体。极易溶于乙醇、乙醚和氯仿，溶于稀酸、烃类、苯、丙酮、二氧六环，微溶于水。水中溶解度:2.5 g/100 ml (20°C)
  • MSDS 信息:2-乙烯吡啶(100-69-6).msds
  • 毒性分级:高毒
  • 灭火剂:干粉、二氧化碳、砂土、泡沫
  • 海关编码:29333999
  • 急性毒性:口服-大鼠 LD50: 100 毫克/公斤; 口服-小鼠 LD50: 420 毫克/公斤

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Vinyl Halides, Amines, Amides, and Other Vinyl Monomers - Monomers
  1. C6
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Vinyl Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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