3-Aminoquinoline 3-氨基喹啉

CAS 580-17-6 MFCD00006772

化学结构图

580-17-6
SMILES: Nc1cnc2ccccc2c1

化学属性

Mol. FormulaC9H8N2
Mol. Weight144
Melting Point91-94
TSCAYes
Density1.422
Solubility略溶于热水
Boiling Point137°C/1mmHg(lit.)

别名和识别编码

Chemical Name3-Aminoquinoline
CAS Number580-17-6
Alfabeta NameQUINOLINAMINE 3--
MDL NumberMFCD00006772
Synonym 3-AMINOQUINOLINE PURISS. GR, FO Quinoline, 3-amino- 3-AMINOQUINOLINE, FOR FLUORESCENCE 3-Quinolylamine 3-quinolylamine 3-AMINOQUINOLINE 氨基喹啉 TIMTEC-BB SBB004125 3-氨基喹诺啉 3-AQ 3-喹啉胺 Quinolin-3-ylamine 3-AQ 3-喹啉胺 3-Quinolinamine QUINOLIN-3-AMINE 3-AQ, 3-Quinolinamine 3-Aminoquinoline 3-Quinolineamine 3-Chinolylamin 3-氨基喹啉 3-Aminoquinoline,98% 3-amino-quinolin 3-Amino-chinolin 3-Aminochinolin 3-氨基喹啉,98% 3-aminoquinoline 3-AMINOQUINOLINE, MATRIX SUBSTANCE FOR M ALDI-MS 3-氨基氮杂萘 3-Aminoquinoline, 99+% 3-QUINOLINAMINE
PubChem Substance ID11375
EC Number209-455-1
Beilstein Registry Number113317
Reaxys-RN113317
Chemical Name Translation3-氨基喹啉
Wiswesser Line NotationT66 BNJ DZ
LabNetwork Molecule IDLN00135708
InChIInChI=1S/C9H8N2/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H,10H2
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分类

  • Building Blocks, C8 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Quinolines
  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Analytical Reagents, Analytical/Chromatography, Fluorophores, Glycan Labeling, Mass Spectrometry (MS), Matricies for Mass Spectroscopy Analysis of Glycans,

相关文献及参考

  • Beil. 22 ,V,10,233
  • Aldrich MSDS 1 , 113:C / Corp MSDS 1 (1), 223:D / FT-IR 2 (3), 3916:C / FT-IR 1 (2), 862:D / FT-NMR 1 (3), 436:B / NMR-Reference 2 (2), 739:D / RegBook 1 (2), 2619:L / Sax 6 , 250 / Structure Index 1 , 413:B:5 / Vapor Phase 3 , 1570:D
  • Short: III/35D3 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 3: Heterocycles Author: Gupta, R.R.; Jain, M.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D3 Year: 2007 Keyword: C-13; NMR; carbon-13; chemical shifts; coupling constants; heterocycles; nuclear magnetic resonance ISBN: 978-3-540-29731-4 ISBN: 3-540-29731-6 Internet Resource: DOI: 10.1007/978-3-540-47067-0 RefComment: VIII, 342 p., 1 illus., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. NMR is now a leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, and subvolume III/35G contains the nucleus Se-77. More nuclei are planned for future

安全信息

Warnings 危化品目录(2015) IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 6.1 Xn
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSVA9622000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Storage condition Air Sensitive
Packing GroupIII
UN Number 2811
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOAO Farmakologiya i Toksikologiya (Moscow).  For English translation, see
   PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-   
   1939-  Volume(issue)/page/year: 41,708,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03890

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 187,191,1987

Restrict 危险品

其他信息

  • 急性毒性:腹腔- 小鼠 LD50: 150 毫克/ 公斤; 静脉-小鼠LD50: 180 毫克/公斤
  • 外观性质:灰白色结晶粉末。
  • 存储注意事项:空气敏感;氩气保护
  • 毒性分级:高毒
  • 上游原料:氨 --> 硫酸铜五水合物 --> 3-溴喹啉
  • MOL 文件:580-17-6.mol
  • 敏感性:Air Sensitive
  • 图谱信息:3-氨基喹啉(580-17-6)核磁图( 13 CNMR) 3-氨基喹啉(580-17-6)红外图谱(IR3) 3-氨基喹啉(580-17-6)质谱(MS) 3-氨基喹啉(580-17-6)红外图谱(IR2) 3-氨基喹啉(580-17-6)红外图谱(IR1)
  • 3-氨基喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0418 3-氨基喹啉 3-Aminoquinoline 5G 709元 2014/06/02 A0418 3-氨基喹啉 3-Aminoquinoline 25G 2180元 2010/06/21 213780050 3-氨基喹啉 3-Aminoquinoline 99+% 5 GR 683元
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • Sigma Aldrich:580-17-6(sigmaaldrich)
  • MSDS 信息:3-氨基喹啉(580-17-6).msds
  • 海关编码:29334990
  • Acros Organics:3-氨基喹啉 3-Aminoquinoline, 99+%(580-17-6)
  • F:2-10
  • 类别:有毒物品
  • Alfa Aesar:3-氨基喹啉,98% 3-Aminoquinoline, 98%(580-17-6)
  • 可燃性危险特性:明火可燃; 高热放出有毒氮氧化物气体
  • TCI Shanghai:3-氨基喹啉 3-Aminoquinoline,>;98.0%(GC)(T)(580-17-6)
  • 灭火剂:干粉、泡沫、二氧化碳、砂土、雾状水。

系列性分类


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