Isopropyl nitrate 硝酸异丙酯

CAS 1712-64-7 MFCD00007041

化学结构图

1712-64-7
SMILES: CC(C)O[N+](=O)[O-]

化学属性

Mol. FormulaC3H7NO3
Mol. Weight105.11
Refractive indexn20/D 1.391(lit.)
Boiling Point101-102 °C(lit.)
Density1.040 g/mL at 20 °C(lit.)
Flash Point55 ºF
Solubility不溶于水。

别名和识别编码

Chemical NameIsopropyl nitrate
CAS Number1712-64-7
PubChem Substance ID15575
EC Number216-983-6
Beilstein Registry Number1701405
MDL NumberMFCD00007041
Synonym (CH3)2CHONO2 1-methylethyl nitrate 2-Nitrooxypropane 2-Propanol nitrate 2-Propyl nitrate 2-propanol nitrate 2-propyl nitrate ISOPROPYL NITRATE Isopropylester kyseliny dusicne Isopropylnitrat NITRICACID,1-METHYLETHYLE Nitric acid isopropyl Nitric acid, isopropyl ester Propan-2-ol nitrate Salpetersäureisopropylester isopriopyl nitrate isopropyl nitrate isopropylesterkyselinydusicne nitric acid isopropyl ester nitric acid, 1-methylethyl ester nitricacid,1-methylethylester nitricacid,isopropylester nitricacidisopropylester propane-2-nitrate salpetersaure-isopropyl ester {} {} {Che 梢酸异丙酯 {SNA}
Chemical Name Translation硝酸异丙酯
InChIKeyGAPFWGOSHOCNBM-UHFFFAOYSA-N
Wiswesser Line NotationWNOY1&1
LabNetwork Molecule IDLN00242371
InChIInChI=1S/C3H7NO3/c1-3(2)7-4(5)6/h3H,1-2H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Organic Nitrates/Nitrites
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Organic Nitrates/Nitrites
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Beil. 1 ,IV,1475
  • Corp MSDS 1 (1), 2039:B / FT-IR 1 (1), 397:D / FT-IR 2 (1), 629:B / FT-NMR 1 (1), 622:A / RegBook 1 (1), 431:B / Sax 6 , 1664 / Structure Index 1 , 63:A:2 / Vapor Phase 3 , 480:B
  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes O,F,Xn,Xi O;F;Xn O,F,Xn
RTECSQU8930000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number UN 1222 3/PG 2 1222
Safety Statements
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
  • S17 Keep away from combustible material 远离可燃物料;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R5 Heating may cause an explosion 加热会引起爆炸
  • R20 Harmful by inhalation 吸入有害
Packing GroupII
Hazard Class3.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 65 gm/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,78,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 29 gm/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOAO Farmakologiya i Toksikologiya (Moscow).  For English translation, see
   PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-   
   1939-  Volume(issue)/page/year: 33,110,1970

其他信息

  • MSDS 信息:硝酸异丙酯(1712-64-7).msds
  • 爆炸物危险特性:受热可爆
  • MOL 文件:1712-64-7.mol
  • 毒性分级:中毒
  • 用途一:用作医药中间体
  • 用途二:主要用作汽车燃料添加剂,喷气式飞机辅助推进剂。也用于医药中间体、溶剂。
  • 方法一:异丙醇与硝酸在尿素存在下直接酯化。经分离、水洗、中和、干燥、精馏等过程得成品硝酸异丙酯。
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • 类别:易燃液体
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 外观性质:无色液体。
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • Sigma Aldrich:1712-64-7(sigmaaldrich)
  • 急性毒性:吸入- 小鼠 LC50: 65000 毫克/ 立方米/ 2 小时
  • 职业标准:TWA 45毫克/ 立方米; STEL 78 毫克/ 立方米

系列性分类


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