2-Nitrobenzyl Chloride 2-硝基苄氯

CAS 612-23-7 MFCD00007185

化学结构图

612-23-7
SMILES: O=[N+]([O-])c1ccccc1CCl

化学属性

Mol. FormulaC7H6ClNO2
Mol. Weight172
Boiling Point127-133
Melting Point46-48
Density1.556
Flash Point>110°(230°F)
TSCANo
Solubility不溶于水，溶于乙醇、乙醚、乙酸，易溶于丙酮、苯。

别名和识别编码

Chemical Name2-Nitrobenzyl Chloride
Synonym 1-(Chloromethyl)-2-nitrobenzene 1-(chloromethyl)-2-nitro-benzen 1-Chlor-2-nitrotoluol 1-Nitro-2-(chloromethyl)benzene 2-NITROBENZYL CHLORIDE 2-Nitrobenzyl chloride 2-硝基苯甲基氯, 98+% o-Nitrobenzyl chloride A-CHLORO-O-NITROTOLUENE ALPHA-CHLORO-O-NITROTOLUENE Benzene, 1-(chloromethyl)-2-nitro- O-NITROBENZYL CHLORIDE ORTHO-NITROBENZYLCHLORIDE Toluene, alpha-chloro-o-nitro- alpha-Chloro-2-nitrotoluene alpha-Chloro-o-nitrotoluene alpha-chloro-o-nitro-toluen o-Nitrobenzyl chloride à-chloro-2-nitrotoluene α-Chlor-o-nitrotoluol α-Chloro-2-nitrotoluene α-chloro-2-nitrotoluene α-氯-2-硝基甲苯 邻硝基氯化苄 邻硝基氯苄
CAS Number612-23-7
MDL NumberMFCD00007185
PubChem Substance ID11921
EC Number210-300-5
Beilstein Registry Number388396
Reaxys-RN388396
Chemical Name Translation2-硝基苄氯
Wiswesser Line NotationWNR B1G
LabNetwork Molecule IDLN00117197
InChIInChI=1S/C7H6ClNO2/c8-5-6-3-1-2-4-7(6)9(10)11/h1-4H,5H2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Has been used to introduce the photolabile 2-nitrobenzyl protecting group for the phenolic OH group of tyrosine: Int. J. Pept. Protein Res., 9, 91 (1977).
  • Short: IV/1a
  • Short: III/20b
  • Short: EINECS

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSXS9092000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number 3261 UN 3261 8/PG 2
Risk Statements
  • R34 Causes burns 会导致灼伤
Hazard Codes 8 C
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9(Suppl
   9),1,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 50 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

Restrict 危险品

其他信息

  • MSDS 信息:2-硝基氯化苄(612-23-7).msds
  • 2-硝基苄氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0182 2-硝基苄氯 2-Nitrobenzyl Chloride 5G 394元 2014/06/02 N0182 2-硝基苄氯 2-Nitrobenzyl Chloride 25G 1130元 2010/06/21 148160100 2-硝基苄氯 2-Nitrobenzyl chloride 98% 10 GR 1075元
  • TCI Shanghai:2-硝基苄氯 2-Nitrobenzyl Chloride,>;98.0%(GC)(T)(612-23-7)
  • 图谱信息:2-硝基苄氯(612-23-7)红外图谱(IR2) 2-硝基苄氯(612-23-7)红外图谱(IR1) 2-硝基苄氯(612-23-7)质谱(MS) 2-硝基苄氯(612-23-7)核磁图( 13 CNMR) 2-硝基苄氯(612-23-7)核磁图( 1 HNMR)
  • Acros Organics:2-硝基苄氯 2-Nitrobenzyl chloride, 98%(612-23-7)
  • 外观性质:浅黄色、有催泪性和恶臭的晶状固体。
  • Alfa Aesar:2-硝基苯甲基氯,98+% 2-Nitrobenzyl chloride, 98+%(612-23-7)
  • F:19-21
  • MOL 文件:612-23-7.mol
  • Sigma Aldrich:612-23-7(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Isocyanides