2-Propanesulfonyl chloride 异丙基磺酰氯
CAS 10147-37-2 MFCD00007453
化学结构图
SMILES: CC(C)S(=O)(=O)Cl
化学属性
| Mol. Formula | C3H7ClO2S |
|---|---|
| Mol. Weight | 143 |
| Boiling Point | 74-75 |
| Density | 1.27 |
| Refractive index | 1.4530 to 1.4570 |
| Flash Point | 86°C(lit.) |
| TSCA | No |
| Melting Point | -47° |
| Autoignition Point | 865 °F |
| Vapor Density | 4 (vs air) |
| Vapor Pressure | 15.5 mmHg ( 25 °C) |
别名和识别编码
| Chemical Name | 2-Propanesulfonyl chloride |
|---|---|
| CAS Number | 10147-37-2 |
| Alfabeta Name | ISOPROPYLSULFONYLCHLORIDE |
| MDL Number | MFCD00007453 |
| Synonym | 2-Propanesulfonyl chloride Isopropylsulfonyl chloride isopropylsulphonyl chloride |
| EC Number | 233-415-2 |
| Beilstein Registry Number | 1747497 |
| PubChem Substance ID | 87571651 |
| Reaxys-RN | 1747497 |
| Chemical Name Translation | 异丙基磺酰氯 |
| InChIKey | DRINJBFRTLBHNF-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00118483 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds
相关文献及参考
- Reductive cleavage of a secondary alcohol to methylene has been achieved by reduction of the 2-propanesulfonyl ester with lithium triethylborohydride. Reduction of the mesylate and tosylate yielded only the starting alcohol: J. Am. Chem. Soc., 107, 4088 (1985).
- Short: III/20a
- Short: EINECS
- Reductive cleavage of a secondary alcohol to methylene has been achieved by reduction of the 2-propanesulfonyl ester with lithiu
- Short: III/38B
安全信息
- R34 Causes burns 会导致灼伤
- S1 Keep locked up 上锁；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P403+P235
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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