2-Chloroethanesulfonyl Chloride 2-氯乙基磺酰氯

CAS 1622-32-8 MFCD00007461

化学结构图

1622-32-8
SMILES: O=S(=O)(Cl)CCCl

化学属性

Mol. FormulaC2H4Cl2O2S
Mol. Weight163.02
Boiling Point203°C(lit.)
TSCAT
Density1.56
Refractive index1.4900 to 1.4940
Flash Point152°C
Vapor Pressure15 mmHg ( 84 °C)
Stability对热、湿度敏感

别名和识别编码

Chemical Name2-Chloroethanesulfonyl Chloride
CAS Number1622-32-8
Alfabeta NameCHLOROETHANESULFONYLCHLORIDE 2-
MDL NumberMFCD00007461
Synonym (2-chloroethyl)sulphonyl chloride 2-CHLOROETHANESULPHONYL CHLORIDE 2-Chlorethansulfonsäurechlorid 2-Chloroethanesulfonyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number216-594-1
Beilstein Registry Number4(2)526
Reaxys-RN1751202
PubChem Substance ID87566171
Chemical Name Translation2-氯乙基磺酰氯
InChIKeyVHCSBTPOPKFYIU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00335397
InChIInChI=1S/C2H4Cl2O2S/c3-1-2-7(4,5)6/h1-2H2
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分类

  • Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds

相关文献及参考

  • Short: III/20a
  • In the presence of a base, converts alcohols to vinyl sulfonates: J. Am. Chem. Soc., 68, 1797 (1946); Angew. Chem. Int. Ed., 4, 300 (1965). These electrophilic alkenes readily undergo conjugate addition reactions with various nucleophiles:
  • Reaction with pentafluorophenol, in the presence of Et3N, gives PFP vinylsulfonate, which can be converted to a sulfonamide via tin-mediated radical addition of alkyl halides to the olefinic bond, followed by displacement of the PFP group with an amine: Org. Lett., 42549 (2002).
  • Short: III/38B

安全信息

Warnings TOXIC BY INHALATION, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T+
RTECSKI8060000
Precautionary statements
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P403+P233
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Signal word
UN Number 2927
Storage condition 0-10 0-10°C Moisture Sensitive No Data Available Refrigerator 储存温度2-8℃ 储存温度2-8℃,充氩保存
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
Packing GroupII
Hazard Class6.1/8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(6),59,1971

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 420 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(6),59,1971

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 15(6),59,1971

其他信息

  • 2-氯乙烷磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1142 2-氯乙基磺酰氯 2-Chloroethanesulfonyl Chloride 500G 3140元 2014/06/02 C1142 2-氯乙基磺酰氯 2-Chloroethanesulfonyl Chloride 25G 429元 2010/06/21 404610050 2-氯乙烷磺酰氯 2-Chloroethanesulfonyl chloride 95% 5 GR 370元
  • TCI Shanghai:2-氯乙基磺酰氯 2-Chloroethanesulfonyl Chloride,>;95.0%(GC)(T)(1622-32-8)
  • 蒸气压:15 mm Hg ( 84 °C)
  • Sigma Aldrich:1622-32-8(sigmaaldrich)
  • 毒性分级:高毒
  • MOL 文件:1622-32-8.mol
  • 急性毒性:口服- 大鼠 LD50: 240 毫克/ 公斤; 吸入-小鼠 LD50: 250 毫克/立方米/4小时
  • 可燃性危险特性:可燃; 火场分解有毒氯化氢， 硫氧化物气体
  • 储运特性:库房低温, 通风, 干燥 ; 防火; 与氧化剂, 食品原料分开存放
  • F:10-19
  • 职业标准:STEL 0.3 毫克/立方米
  • Alfa Aesar:2-氯乙烷磺酰氯,98% 2-Chloroethanesulfonyl chloride, 98%(1622-32-8)
  • Acros Organics:2-Chloroethanesulfonyl chloride, 95%(1622-32-8)
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 类别:有毒物质
  • 2-氯乙烷磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C1142 2-氯乙基磺酰氯 2-Chloroethanesulfonyl Chloride 500G 2590元 2011/04/16 C1142 2-氯乙基磺酰氯 2-Chloroethanesulfonyl Chloride 25G 354元 2010/06/21 404610050 2-氯乙烷磺酰氯 2-Chloroethanesulfonyl chloride 95% 5 GR 370元
  • 敏感性:Moisture Sensitive
  • 图谱信息:2-氯乙烷磺酰氯(1622-32-8)红外图谱(IR1) 2-氯乙烷磺酰氯(1622-32-8)核磁图( 13 CNMR) 2-氯乙烷磺酰氯(1622-32-8)质谱(MS) 2-氯乙烷磺酰氯(1622-32-8)核磁图( 1 HNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonium/Sulfoxonium Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Organic Triflates
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物
  1. sulfonyl halide

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