o-Aminoazotoluene 邻氨基偶氮甲苯

CAS 97-56-3 MFCD00007733

化学结构图

97-56-3
SMILES: Cc1cc(/N=N/c2ccccc2C)ccc1N

化学属性

Mol. FormulaC14H15N3
Mol. Weight225.29
Density1.09
Melting Point101-102 °C
TSCAYes
Solubility不溶于水，溶于乙醇、氯仿、乙醚。
Boiling Point356.8 °C at 760 mmHg

别名和识别编码

Chemical Nameo-Aminoazotoluene
CAS Number97-56-3
EC Number202-591-2
Beilstein Registry Number6506005
MDL NumberMFCD00007733
Synonym 2-Methyl-5-(p-tolyldiazenyl)aniline {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methyl-5-(p-tolyldiazenyl)aniline {} {} {} {} {} {} {} {} {
PubChem Substance ID7340
Merck Number420
Reaxys-RN745567
Chemical Name Translation邻氨基偶氮甲苯
Wiswesser Line NotationZR B1 DNUNR B1
InChIKeyPFRYFZZSECNQOL-WUKNDPDISA-N
InChIInChI=1S/C14H15N3/c1-10-5-3-4-6-14(10)17-16-12-7-8-13(15)11(2)9-12/h3-9H,15H2,1-2H3
Canonical SMILESNC1=CC(/N=N/C2=CC=C(C=C2)C)=CC=C1C
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分类

  • {SNA} Additional Standards, All alphabetical sorted, Analytical Standards, Aromatics, Chemical Class, Chromatography, Colorant Standards, Colors, Food and Cosmetic Component Standards, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
  • {SNA} E-F, Stains & Dyes, A to Z, Stains and Dyes,
  • {SNA} 细胞化学产品, 细胞生物学, 血液学和组织学
  • {SNA} A, AM to AQ, All alphabetical sorted, Alphabetical Index of Analytica
  • {SNA} E-F, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学

相关文献及参考

  • Merck: 14,420 Beilstein: 16,344
  • Short: EINECS
  • Short: IV/20C

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R35 Causes severe burns 会导致严重灼伤
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P308+P313
  • P301+P312+P330
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P405 Store locked up. 上锁保管。
  • P333+P313
  • P302+P352+P333+P313+P362+P364
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P308+
RTECSXU8800000
Hazard statements
  • H350 May cause cancer 可能致癌
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T
Storage condition 2-8°C
UN Number UN 1789 8/PG 2 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 480 mg/kg
                          female 17-19 day(s) after conception
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
   Liver - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   46,203,1989

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15 gm/kg/57W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   3,387,1949

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 80 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   7,431,1947

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 34080 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   EKSODD Eksperimental'naya Onkologiya.  Experimental Oncology.  (V/O
   Mezhdunarodnaya Kniga, 113095 Mosow, USSR)  V.1-

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1315,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   10,927,1950

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   26,619,1966

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   10,927,1950

TYPE OF TEST            : Body fluid assay
TEST SYSTEM             : Rodent - rat Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 156,131,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Neurospora crassa
DOSE/DURATION           : 1000 ppm
REFERENCE :
   ANYAA9 Annals of the New York Academy of Sciences.  (New York Academy of
   Sciences, 2 E. 63rd St., New York, NY 10021)  V.1-    1877-
   Volume(issue)/page/year: 71,1072,1958

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 45 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 93,409,1982

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 200 nmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 136,255,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 ng/plate
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Non-mammalian species Cells - not otherwise specified
DOSE/DURATION           : 250 ug/L
REFERENCE :
   AOHYA3 Annals of Occupational Hygiene.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958- Volume(issue)/page/year:
   20,297,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 480 mg/kg
SEX/DURATION            : multigeneration
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - hepatobiliary system
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   46,203,1989

其他信息

  • 储运特性:库房通风低温干燥
  • 毒性分级:中毒
  • MOL 文件:97-56-3.mol
  • 邻氨基偶氮甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0261 2-氨基偶氮甲苯 2-Aminoazotoluene 500G 2710元 2014/06/02 T0261 2-氨基偶氮甲苯 2-Aminoazotoluene 25G 374元 2010/06/21 153260250 邻氨基偶氮甲苯 Fast Garnet GBC base 97% 25 GR 446元
  • MSDS 信息:邻氨基偶氮甲苯(97-56-3).msds
  • Acros Organics:邻氨基偶氮甲苯 Fast Garnet GBC base, 97%(97-56-3)
  • 急性毒性:口服-大鼠LDL0: 1500毫克/公斤; 口服小鼠LDL0: 800 毫克/公斤
  • TCI Shanghai:2,3'-二甲基-4'-氨基偶氮苯 2-Aminoazotoluene,>;97.0%(LC)(97-56-3)
  • Sigma Aldrich:97-56-3(sigmaaldrich)
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
  • 图谱信息:邻氨基偶氮甲苯(97-56-3)质谱(MS) 邻氨基偶氮甲苯(97-56-3)核磁图( 13 CNMR) 邻氨基偶氮甲苯(97-56-3)核磁图( 1 HNMR) 邻氨基偶氮甲苯(97-56-3)红外图谱(IR2) 邻氨基偶氮甲苯(97-56-3)红外图谱(IR1)
  • 外观性质:黄棕色粉末。
  • 类别:有毒物品

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Cytochemistry Products - Hematology and Histology
  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. E-F - Stains & Dyes, A to Z
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. A - Alphabetic
  5. AM to AQ - A
  1. Functional Group 官能团索引
  2. azo compound
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Biochemicals and Reagents
  4. Stains and Dyes
  5. Natural Dyes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Hematology and Histology
  4. Stains and Dyes
  5. Stains & Dyes, A to Z
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Hemotology and Histology
  4. Stains and Dyes
  5. Stains & Dyes, A to Z

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