2,6-Diaminotoluene 2,6-二氨基甲苯

CAS 823-40-5 MFCD00007800

化学结构图

823-40-5
SMILES: Cc1c(N)cccc1N

化学属性

Mol. FormulaC7H10N2
Mol. Weight122
Melting Point104.0 to 107.0 deg-C
TSCAYes
Boiling Point282°C(lit.)
Solubility60 G/L (15 ºC)
Density1.107
Appearance 梭柱状结晶,熔点 104-106 ;°C,沸点 289 °C

别名和识别编码

Chemical Name2,6-Diaminotoluene
CAS Number823-40-5
Synonym 1,3-Diamino-2-methylbenzene 2,6-DAT 2,6-DIAMINOTOLUENE 2,6-DIAMINOTOLUENE OEKANAL, 250 MG 2,6-Diamino-1-methylbenzene 2,6-Diaminotoluene 2,6-Diaminotoluene free 2,6-Toluylenediamine 2,6-Tolylenediamine 2,6-Tolylenediamine, 2-Methyl-m-phenylenediamine 2,6-diaminotoluene 2,6-diaminotoluene dihydrochloride 2,6-toluenediamine 2,6-二氨基甲苯 2,6-二氨基甲苯,97% 2,6-甲苯二胺 2,6-甲苯二胺 2-甲基间苯二胺 甲苯-2,6-二胺 2-METHYL-BENZENE-1,3-DIAMINE 2-METHYL-M-PHENYLENEDIAMINE 2-Methyl-m-phenylendiamin 2-methyl-3-benzenediamine 2-甲基间苯二胺 3-Benzenediamine,2-methyl-1 Diaminotoluene,98% Toluene-2,6-diamine Toluylen-2,6-diamin Tolylene-2,6-diamine 甲苯-2,6-二胺
MDL NumberMFCD00007800
PubChem Substance ID13205
Beilstein Registry Number13,148
EC Number212-513-9
Chemical Name Translation2,6-二氨基甲苯
Reaxys-RN2079476
Wiswesser Line NotationZR CZ B1
LabNetwork Molecule IDLN00224787
InChIInChI=1S/C7H10N2/c1-5-6(8)3-2-4-7(5)9/h2-4H,8-9H2,1H3
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分类

  • {SNA} Amine Monomers,
  • Mutagenesis Research Chemicals
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Alpha Sort, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chromatography, Environmental Standards, M, META - METH, Volatiles/ Semivolatiles
  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
  • {SNA} Amine Monome
  • {SNA} Additional Standards, Alpha Sort, Amines, Analytical Standards, Aromatics, Chemical Class, Chromatography, Environmental Standards,
  • {SNA} A

产品应用

  • Aromatic amines likely to have high carcinogenic potency. QSARs of aromatic amines.

相关文献及参考

  • Short: III/20a
  • Beilstein:13,148
  • Benigni, R., et al.: Chem. Rev., 105, 1767 (2005),
  • Short: EINECS
  • Benigni, R., et al.: Environ. Mol. Mutagen., 50, 152 (2009),
  • Franke, R., et al.: Carcinogenesis, 22, 1561 (2001),

安全信息

RTECSXS9750000
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
WGK Germany3
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number UN 3077 9/PG 3 UN2811 3077
Risk Statements
  • R51/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R50/53
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Hazard Codes
Hazard Class9
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   26,240,1995

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 300 mg/kg
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 12,2233,1991

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 265,45,1992

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 91,75,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ESKGA2 Eisei Kagaku.  Hygienic Chemistry.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  V.1-    1953-
   Volume(issue)/page/year: 31,113,1985

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Liver
DOSE/DURATION           : 10 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issu

其他信息

  • MSDS 信息:2,6-Diamino-1-methylbenzene(823-40-5).msds
  • Alfa Aesar:2,6-二氨基甲苯,97% 2,6-Diaminotoluene, 97%(823-40-5)
  • Sigma Aldrich:823-40-5(sigmaaldrich)
  • 用途一:主要用于医药、染料的中间体
  • TCI Shanghai:2-甲基-1,3-苯二胺 2,6-Diaminotoluene,>;98.0%(GC)(T)(823-40-5)
  • 图谱信息:2,6-二氨基甲苯(823-40-5)红外图谱(IR1) 2,6-二氨基甲苯(823-40-5)红外图谱(IR2) 2,6-二氨基甲苯(823-40-5)核磁图( 13 CNMR) 2,6-二氨基甲苯(823-40-5)质谱(MS)
  • 可燃性危险特性:明火可燃;高热分解有毒氮氧化物烟雾
  • 灭火剂:泡沫、雾状水、二氧化碳、砂土
  • 2,6-二氨基甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0124 2,6-二氨基甲苯 2,6-Diaminotoluene 25G 835元 2014/06/02 D0124 2,6-二氨基甲苯 2,6-Diaminotoluene 10G 492元 2010/06/21 164680250 2,6-二氨基甲苯 2,6-Diaminotoluene 98% 25 GR 1037元
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
  • Acros Organics:2,6-二氨基甲苯 2,6-Diaminotoluene, 98%(823-40-5)
  • MOL 文件:823-40-5.mol
  • 类别:有毒物品

系列性分类


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