4-Nitroaniline 4-硝基苯胺
CAS 100-01-6 MFCD00007858
化学结构图
SMILES: Nc1ccc([N+](=O)[O-])cc1
化学属性
| Mol. Formula | C6 |
|---|---|
| Mol. Weight | 138 |
| Density | 1.44 |
| Flash Point | 165°(329°F) |
| Solubility | 不溶于水，微溶于苯，溶于乙醇、乙醚、丙酮，易溶于醇。 |
| TSCA | Yes |
| Boiling Point | 332°C(lit.) |
| Melting Point | 147.0 to 150.0 deg-C |
| Stability | 对光敏感 |
| Appearance | crystalline |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | 4-Nitroaniline |
|---|---|
| CAS Number | 100-01-6 |
| MDL Number | MFCD00007858 |
| EC Number | 202-810-1 |
| Merck Number | 6584 |
| Beilstein Registry Number | 12,711 |
| Synonym | {uni_hamburg} 4-nitro-benzenamin 4-硝基苯胺;1-氨基-4-硝基苯 Naphtoelan Red GG Base { 冰染重氮组分37 Aniline, p-nitro- benzenamine, 4-nitro- 4-nitrobenzenamine P-AMINONITROBENZENE Azoamine Red ZH 1-Amino-4-nitrobenzene P-NITRANILINE p-Aminonitrobenzene PNA C.I. Developer 17 4-Nitrophenylamine 4-Nitro-1-aminobenzene p-Nitroaniline; p-Nitr C.I. Azoic Diazo Component 37 P-NITROANILINE 1-氨基-4-硝基苯 Nitrazol CF extra Diazo Fast Red GG 对硝基苯胺 aniline, p-nitro {uni_ham 4-nitro-anilin Sh 4-硝基苯胺，1-氨基-4-硝基苯 p-Nitraniline Aniline, p 4-Nitro-phenylamine Fast Red 2G Salt {u Fast Red P Salt {C Fast Red Base GG Fast Red GG Bas p-Nitrophenylamine 1-AMINO-4-NITROBENZENE Fast Red 2G Base Fast Red GG Salt Devol Red GG 4-硝基苯胺 Fast Red Base 2J 4-Aminonitrobenzene Azofix Red GG Salt 對硝基苯胺 4-nitro-aniline Fast Red P Base {Chemicalbook C.I. 37035 aniline 4-Nitroaminobenzol AURORA KA-7786 Shinnippon Fast Red GG Base 4-Nitro aniline p-Nitroaniline AKOS 92446 对硝基苯胺 4-NITRO Fast Red MP Base 4 (4-Nitro)aniline p-Nitraniline 对硝极苯胺 对硝基苯胺标准溶液 4-Amino-1-nitrobenzene Aniline, 4-nitro- |
| PubChem Substance ID | 87573507 |
| Chemical Name Translation | 4-硝基苯胺 |
| Wiswesser Line Notation | ZR DNW |
| LabNetwork Molecule ID | LN00196322 |
| Reaxys-RN | 508690 |
| InChI | InChI=1S/C6H6N2O2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H,7H2 |
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分类
- {SNA} Analytical Reagents, Analytical/Chromatography, Indicators, Indicators for non-aqueous titration, Metal Titration Indicators, Non-aqueous Titration Reagents, Titration
- {SNA} Amines, Building Blocks, C6, Chemical Synthesis, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials, 材料科学
- {Chemicalbook} 农药中间体: 杀鼠剂中间体
- Alpha Sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics,
- {SNA} Analytical Reagents,
- {SN
产品应用
- 产品的显色反应
相关文献及参考
- Short: II/25D
- Merck:14,6584
- Merck:14,6584 Beilstein: 12,IV,1613
- Short: II/27B
安全信息
- H301 Toxic if swallowed 吞食有毒
- H301+H311+H331
- H311 Toxic in contact with skin 皮肤接触中毒
- H331 Toxic if inhaled 吸入中毒
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
GHS Symbol
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P310+P330
- P302+P352+P312+P361+P364
- P304+P340+P311
- P308+P311
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S7 Keep container tightly closed 保存在严格密闭容器中；
- S1/2 None 上锁保管并避免儿童触及；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R52/53
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R33 Danger of cumulative effects 有累积作用的危险
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 51500 mg/kg/2Y-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Vascular - tumors REFERENCE : NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-418,1993
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 600 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,92,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - quail DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 450 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold REFERENCE : VKMGA7 Voprosy Kommunal'noi Gigieny. Problems of Communal Hygiene. (Kiev, USSR) V.6, 1966. For publisher information, see GNAMAP. Volume(issue)/page/year: 6,89,1966
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 810 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 42,417,1977
TYPE OF TES
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 173 mg/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 333 ug/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 5(Suppl 1),3,1983
TYPE OF TEST : Phage inhibition capacity TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 100 mmol/L REFERENCE : MDMIAZ Medycyna Doswiadczalna i Mikrobiologia. For English translation, see EXMMAV. (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland) V.1- 1949- Volume(issue)/page/year: 31,11,1979
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 5 mg/disc REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 170,11,1986
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Microorganism - not otherwise specified DOSE/DURATION : 1500 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 173,233,1986
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 50 ug/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 44,9,1977
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 9600 mg/kg SEX/DURATION : female 6-13 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Effects on Newborn - live birth index (measured after birth) Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight gain) REFERENCE : TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1980- Volume(issue)/page/year: 7,29,1987
TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE : 1764 mg/kg
SEX/DURATION : male 14 week(s) pre-mating
female 14 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Fertility - female fertility index (e.g. # females pregnant
per # sperm positive females; # females pregnant per # females mated)
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E.
First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year:
15,607,1990其他信息
- 用途二:用作分析试剂和染料中间体
- 用途三:对硝基苯胺是杀鼠剂灭鼠安、灭鼠优的中间体。
- {
- 毒性分级:中毒
- Alfa Aes
- 4-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称
- color:yellow
- 用途一:是各种直接、酸性、分散染料及颜料的中间体，重要的农药中间体
- Hazard Note:Toxic
- MSDS 信息:对硝基苯胺(100-01-6).msds
- {Chemi
- 用途五:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体。
- 方法一:其制备方法是将对氯硝基苯与氨在催化剂存在下反应或进行过氨化反应。
- {Chemicalb
- 微有气味，易溶于甲醇，能溶于醇和醚，微溶于苯，不溶于水。溶于浓无机酸，几乎无色。1g溶于约1250ml水、45ml沸水、25ml乙醇、30ml乙醚。低毒，半数致死量（大鼠，经口）750mg/kg。有刺激性。
- 类别:有毒物品
- 下游产品:分散橙 29 --> 酸性绿A --> 6-氨基喹啉 --> 酸性黑 1 --> 对二硝基苯 --> 天狼黄 --> 安吖啶 --> 直接黑19 --> 2-溴-4-硝基苯胺 --> 弱酸性红棕 V --> 分散红 74 --> 5-溴-2-哌嗪基嘧啶 --> 直接耐晒黑G --> 6-硝基-3-氯喹啉 --> 灭鼠优 --> 直接深绿 2G --> 分散橙 73 --> 直接绿26 --> 酸性棕 75 --> 阳离子暗黄2RL --> 黑色盐K --> 分散红135 --> 直接灰D --> 酸性黑 210 --> 鲎试剂三肽 --> N-[5-[二(2-乙酰氧基)乙基]氨基]-2-[(2-氯-4-硝基苯基)偶氮]苯基丙酰胺 --> C.I.分散红17 --> 分散大红SE-R --> 黑色基LS --> 4-[(4-氨苯基)偶氮]-1-萘胺 --> 异氰酸对硝基苯 --> 阳离子可拔白性橙 D-3R --> 分散橙31号滤饼 --> 对硝基苯重氮氨基偶氮苯 --> 分散橙 25 --> 分散兰 183 --> 分散橙 2RL
- 用途六:该品即冰染
- MOL 文件:100-01-6.mol
- 用途六:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体。还可作农药和兽药的中间体，在医药工业中可用于生产氯硝柳胺、卡巴肿、硝基安定、喹啉脲硫酸盐等。还可用于生产对苯二胺、抗氧化剂和防腐剂等。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
- 检测方法:HPL
- 用途四:该品即冰染染料大红 GG色基，可作黑色盐 K，供棉麻织物染色、印花之用。但主要用作偶氮染料中间体，如用于生产直接墨绿B、酸性媒介棕G、酸性黑10B、酸性毛元ATT、毛
- 海关编码:29214210
- 4-硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80089814 4-硝基苯胺（易制爆） 25g 15元 2011/08/23 80089824 4-硝基苯胺（易制爆） 25g 12元 2010/06/21 128371000 4-硝基苯胺 4-Nitroaniline 99% 100
- TCI Shanghai:4-硝基苯胺 4-Nitroaniline,>;98.0%(GC)(100-01-6)
- 色指数:37035
- 防护措施:高毒。可引起比苯胺更强的血液中毒。如果同时存在有机溶剂或在饮酒后，这种作用更为强烈。急性中毒表现为开始头痛、颜面潮红、呼吸急促，有时伴有恶心、呕吐，之后肌肉无力、发绀、脉搏频弱及呼吸急促。
- 常规方法:内衬塑料袋、外套纤维板桶或铁桶包装，每桶30、35、40、45、50kg均可。贮运中防止曝晒、雨淋，防止压坏、碰破。贮存于干燥、通风处。按剧毒有机化合物规定贮运。
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