4-Methyl-2-nitroaniline 2-硝基-4-甲基苯胺

CAS 89-62-3 MFCD00007907

化学结构图

89-62-3
SMILES: Cc1ccc(N)c([N+](=O)[O-])c1

化学属性

Mol. FormulaCH3C6H3(NO2)NH2
Mol. Weight152
Melting Point115-116
Density1.164
Flash Point157°(314°F)
TSCAYes
Boiling Point140°C
RedoxOxidation

别名和识别编码

Chemical Name4-Methyl-2-nitroaniline
CAS Number89-62-3
Alfabeta NameMETHYLNITROANILINE 42---
MDL NumberMFCD00007907
Synonym 1-Amino-2-nitro-4-methylbenzene 2-Nitro-4-methylanilin 2-Nitro-p-toluidine, 4-Amino-3-nitrotoluene 2-硝基对甲苯胺 3-Nitro-4-aminotoluene 4-Amino-3-nitrotoluene 4-Methyl-2-nitroaniline 4-Methyl-2-nitrobenzenamine 4-Methyl-o-nitroaniline 4-氨基-3-硝基甲苯 4-甲基-2-硝基苯胺 o-Nitro-p-methylaniline Azoamine Azofix Red GL Salt Benzenamine, 4-methyl-2-nitro- C.I. Azoic Diazo Component 8 Devol Red G Fast Red 3NT Base Fast Red 3NT Salt Fast Red G Base Fast Red MGL Base Hiltonil Fast Red GL Base Hiltosal Fast Red GL Salt Lithosol Scarlet Base MB Lithosol Scarlet Base MBW MNPT {} {} {} {} {uni_ 邻硝基对甲苯胺
PubChem Substance ID6978
EC Number201-924-9
Beilstein Registry Number879506
Reaxys-RN879506
Chemical Name Translation2-硝基-4-甲基苯胺
LabNetwork Molecule IDLN00173088
InChIInChI=1S/C7H8N2O2/c1-5-2-3-6(8)7(4-5)9(10)11/h2-4H,8H2,1H3
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 该品是偶氮染料的重要中间体,是冰染染料的色基(红色基 GL),用于棉纤维和粘胶纤维的染色和印花显色,并可用于生产甲苯胺红、甲苯胺紫红、汉沙黄G等有机颜料。

相关文献及参考

  • Beilstein:12,1000
  • Dominguez, M., et al.: J. Agric. Food Chem., 56, 3721 (2008),
  • Short: EINECS
  • Short: IV/16
  • Short: IV/4

安全信息

Warnings 危化品目录(2015) IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311+H331
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T,N
RTECSXU8227250
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P304+P340+P311
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
UN Number 2660
Packing GroupIII
Storage condition 能随水蒸气挥发,密封保存
Hazard Class6.1
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,230,1954

Restrict 危险品

其他信息

  • 溶于乙醇和浓硫酸,微溶于水,能随水蒸气挥发。

系列性分类


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