Methanesulfonamide 甲基磺酰胺

CAS 3144-09-0 MFCD00007940

化学结构图

3144-09-0
SMILES: CS(N)(=O)=O

化学属性

Mol. FormulaCH5NO2S
Mol. Weight95.12
Melting Point85-89°C
TSCAT
Density1.422
Boiling Point208.2°C at 760 mmHg

别名和识别编码

Chemical NameMethanesulfonamide
CAS Number3144-09-0
Alfabeta NameMETHANESULFONAMIDE
MDL NumberMFCD00007940
Synonym Methanesulfonamide {LY} Methanesulfonamide {} {LY} Methanesulfonamide {} {} {LY} Methanesulfonamide {} {} {} {LY} Methanesulfonamide {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methanesulfonamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number221-553-6
Beilstein Registry Number1740835
PubChem Substance ID72879
Reaxys-RN1740835
Chemical Name Translation甲基磺酰胺
InChIKeyHNQIVZYLYMDVSB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115495
InChIInChI=1S/CH5NO2S/c1-5(2,3)4/h1H3,(H2,2,3,4)
Canonical SMILESCS(=O)(N)=O
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分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 除草剂中间体
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonamides/Sulfinamides, Sulfur Compounds
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/20c Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zr ... Bi. Diagrams, Structure formulas, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20c Year: 1989 Keyword: NQR ISBN: 3-540-18490-2 ISBN: 978-3-540-18490-4 Internet Resource: DOI:10.1007/b35374 RefComment: 562 figs., IX,802 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7

安全信息

Warnings IRRITANT
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

其他信息

  • 甲基磺酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0461203 甲烷硫胺 250g 1170元 2011/04/16 M0915 甲基磺酰胺 Methanesulfonamide 500G 2410元 2011/04/16 M0915 甲基磺酰胺 Methanesulfonamide 25G 319元
  • 上游原料:甲基磺酰氯
  • 方法一:其制备方法是由甲基磺酰氯与氨反应而制得。以甲苯为溶剂 CH 3 SO 2 Cl+NH 3 →CH 3 SO 2 NH 2 +HCl
  • TCI Shanghai:甲基磺酰胺 Methanesulfonamide,>;98.0%(N)(3144-09-0)
  • Alfa Aesar:甲磺酰胺,98+% Methanesulfonamide, 98+%(3144-09-0)
  • TSCA:T
  • 图谱信息:甲基磺酰胺(3144-09-0)红外图谱(IR2) 甲基磺酰胺(3144-09-0)核磁图( 13 CNMR) 甲基磺酰胺(3144-09-0)质谱(MS) 甲基磺酰胺(3144-09-0)红外图谱(IR1) 甲基磺酰胺(3144-09-0)核磁图( 1 HNMR)
  • 用途一:用作药物中间体
  • 海关编码:29350090
  • Hazard Note:Irritant
  • Acros Organics:甲烷磺酰胺 Methanesulfonamide, 98%(3144-09-0)
  • Sigma Aldrich:3144-09-0(sigmaaldrich)
  • 下游产品:氟磺胺草醚 --> 安吖啶 --> N-(Δ-溴代戊酰基)甲磺酰胺
  • 用途三:甲基磺酸胺是除草剂氟磺胺草醚的中间体。
  • 用途二:用于生产农田除草剂
  • MSDS 信息:Methanesulfonamide(3144-09-0).msds
  • MOL 文件:3144-09-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonamides/Sulfinamides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfides/Disulfides