Aminoacetaldehyde Diethyl Acetal 氨基乙醛二乙缩醛

CAS 645-36-3 MFCD00008136

化学结构图

645-36-3
SMILES: CCOC(CN)OCC

化学属性

Mol. FormulaC6H15NO2
Mol. Weight133.19
Density0.916
Refractive index1.4160 to 1.4190
Boiling Point163°C at 760 mmHg
Flash Point45.6°C
TSCAYes
Solubility可溶
Melting Point-78 °C
pH:A

别名和识别编码

Chemical NameAminoacetaldehyde Diethyl Acetal
Synonym 2,2-Diethoxyethylamine {LY} 2,2-Diethoxyethylamine {} {LY} 2,2-Diethoxyethylamine {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Diethoxyethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2-Dietho
CAS Number645-36-3
EC Number211-439-4
Beilstein Registry Number506067
MDL NumberMFCD00008136
PubChem Substance ID69524
Reaxys-RN506067
Chemical Name Translation氨基乙醛二乙缩醛
InChIKeyHJKLEAOXCZIMPI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009455
InChIInChI=1S/C6H15NO2/c1-3-8-6(5-7)9-4-2/h6H,3-5,7H2,1-2H3
Canonical SMILESNCC(OCC)OCC
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于有机合成

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1989 2924
Hazard Codes 3
Hazard Class3/8
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Flammables area {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, pr

其他信息

  • Sigma Aldrich:645-36-3(sigmaaldrich)
  • 液体,易溶于水、醇、醚和氯仿。
  • 用途一:用于有机合成。
  • Acros Organics:氨基乙醛二乙缩醛 Aminoacetaldehyde diethyl acetal, 99%(645-36-3)
  • Alfa Aesar:氨基乙醛二乙基缩醛,98% Aminoacetaldehyde diethyl acetal, 98%(645-36-3)
  • 图谱信息:氨基乙醛缩二乙醇(645-36-3)核磁图( 13 CNMR) 氨基乙醛缩二乙醇(645-36-3)核磁图( 1 HNMR) 氨基乙醛缩二乙醇(645-36-3)质谱(MS) 氨基乙醛缩二乙醇(645-36-3)红外图谱(IR1)
  • Hazard Note:Irritant
  • 氨基乙醛缩二乙醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0247 氨基乙缩醛 Aminoacetal 250ML 2580元 2014/06/02 A0247 氨基乙缩醛 Aminoacetal 25ML 386元 2010/06/21 103070050 氨基乙醛缩二乙醇 Aminoacetaldehyde diethyl acetal 99% 5 ML 213元
  • MOL 文件:645-36-3.mol
  • 方法一:由二乙醇缩氯乙醛与氨反应而得。
  • 外观性质:液体,易溶于水、醇、醚和氯仿。沸点:162-163℃闪点:114 °F密度:0.916折光率:1.417
  • 下游产品:8-溴异喹啉 --> 2-硝基咪唑 --> 甲巯咪唑 --> 2-氨基咪唑
  • TCI Shanghai:氨基乙醛缩二乙醇 Aminoacetal,>;97.0%(GC)(T)(645-36-3)
  • 上游原料:二乙醇 --> 氯乙醛
  • MSDS 信息:2,2-Diethoxyethylamine(645-36-3).msds

系列性分类


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