N,N-Diethylethylenediamine N,N-二乙基乙二胺

CAS 100-36-7 MFCD00008176

化学结构图

100-36-7
SMILES: CCN(CC)CCN

化学属性

Mol. Formula(CH3CH2)2NCH2CH2NH2
Mol. Weight116
Refractive index1.4330 to 1.4370
Boiling Point145-147
Density0.827
Flash Point40°C(lit.)
TSCAYes
Melting Point< -70
Solubility和水混溶，溶于醚、醇、甲苯和四氯化碳。
Stability对空气敏感
pH:A

别名和识别编码

Chemical NameN,N-Diethylethylenediamine
Synonym beta-Diethylaminoethylamine N，N-二乙基乙烯二胺 (DIETHYLAMINO)ETHYLAMINE DEAEA N,N-Diethylethylenediamine β-diethylaminoethylamine 二乙基乙二胺 N1,N1-Diethyl-ethane-1,2-diamine β-(Dimethylamino)ethylamine 2-Aminotriethylamine N,N-diethyl-ethylenediamine 2-aminoethyldiethylamine {Chemi N',N'-diethylenediamine {Chem 2-Diethylaminoethylami N,N-Diethyl-1,2-ethanediamine N,N-(Diethylethyl)diamine 2-(Diethylamino)ethylamine 1-Amino-2-(diethylamino)ethane N,N-diethyl-ethane-1,2-diamine β-(Diethylamino)ethylamine 2-(Diethylamino)ethanamine 2 N-[2-(Diethylamino)ethyl]amine
CAS Number100-36-7
PubChem Substance ID60993
EC Number202-844-7
Beilstein Registry Number605299
MDL NumberMFCD00008176
Reaxys-RN605299
Chemical Name TranslationN,N-二乙基乙二胺
Wiswesser Line NotationZ2N2&2
LabNetwork Molecule IDLN00005808
InChIInChI=1S/C6H16N2/c1-3-8(4-2)6-5-7/h3-7H2,1-2H3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards L - M, Pharmaceutical Standards, Pharmacopeia Standards
  • {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia Metrological Institutes Standards, 分析/色谱

产品应用

  • 有机合成中间体。

相关文献及参考

  • Short: EINECS
  • Beilstein:4,251
  • Short: III/35B

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C 8
RTECSKV3500000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word
UN Number 2685
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Storage condition Air Sensitive 密封保存。 对空气敏感，密封保存。 Flammables area
Packing GroupII
Hazard Class8/3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2830 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 820 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

Restrict 危险品

其他信息

  • N,N-二乙基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0505 N,N-二乙基乙二胺 N,N-Diethylethylenediamine 25ML 130元 2014/06/02 D0505 N,N-二乙基乙二胺 N,N-Diethylethylenediamine 500ML 701元 2010/06/21 150701000 N,N-二乙基乙二胺 N,N-Diethylethylenediamine 98+% 100 ML 249元
  • 和水混溶，溶于醚、醇、甲苯和四氯化碳。
  • 刺激数据:皮肤- 兔子 5 毫克/ 24小时; 眼- 兔子 50 微克 重度
  • 灭火剂:泡沫、干粉、二氧化碳
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放有毒氮氧化物烟雾
  • 下游产品:氯化二乙基硬脂酰乙基苄基铵 --> 二乙基油酰氨乙基胺盐酸盐
  • 用途二:N,N-二乙基乙二胺用作精细化学品的中间体，可生产抗心律失常药普鲁卡因胺、局部麻醉药盐酸地布卡因及酶抑宁等。也用来生产助剂产品，例如，用于制取色必明BCH（Sapamine BCH）。
  • 毒性分级:中毒
  • 用途一:在医药上用于合成盐酸普鲁卡因胺、盐酸氯普鲁卡因、辛可卡因、盐酸硫必利
  • 图谱信息:N,N-二乙基乙二胺(100-36-7)核磁图( 13 CNMR) N,N-二乙基乙二胺(100-36-7)核磁图( 1 HNMR) N,N-二乙基乙二胺(100-36-7)红外图谱(IR1) N,N-二乙基乙二胺(100-36-7)质谱(MS)
  • 类别:可燃物品
  • 上游原料:丙烯腈 --> 氨基乙腈
  • MSDS 信息:N,N-二乙基乙烯二胺(100-36-7).msds
  • TCI Shanghai:N,N-二乙基乙二胺 N,N-Diethylethylenediamine,>;98.0%(GC)(T)(100-36-7)
  • 方法一:由丙烯腈经水解、加成、降解而得；另一种生产方法是由乙二氨基乙腈加氢制得该品。
  • 急性毒性:口服- 大鼠 LD50: 2830 毫克/ 公斤; 腹腔- 小鼠 LD50: 300 毫克/ 公斤
  • 存储注意事项:氮气保护
  • MOL 文件:100-36-7.mol
  • 敏感性:Air Sensitive
  • 储运特性:包装完整、轻装轻卸; 库房通风、远离明火、高温、与氧化剂、酸分开存放
  • Acros Organics:N,N-二乙基乙二胺 N,N-Diethylethylenediamine, 98+%(100-36-7)
  • Alfa Aesar:N,N-二乙基乙二胺,99% N,N-Diethylethylenediamine, 99%(100-36-7)
  • 外观性质:无色液体。
  • Sigma Aldrich:100-36-7(sigmaaldrich)
  • 海关编码:29212900

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes

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