Tetramethylsilane 四甲基硅烷

CAS 75-76-3 MFCD00008274

化学结构图

75-76-3
SMILES: C[Si](C)(C)C

化学属性

Mol. FormulaC4H12Si
Mol. Weight88.23
Density0.648
Refractive index1.3570 to 1.3600
Autoignition Point842 °F
Boiling Point26°C
Vapor Pressure11.66 psi ( 20 °C)
Melting Point-99
Flash Point-27°C(lit.)
TSCAYes
Solubility0.02 G/L (25 ºC)
Appearance colorless liq.

别名和识别编码

Chemical NameTetramethylsilane
Synonym tetramethylsilane TETRAMETHYLSILANE 99.9+% NMR GRADE & (CH3)4Si Silane, tetramethyl- 四甲矽 TMS TETRAMETHYLSILANE, ACS, CALIBRATION STD FOR NMR-SPECTROSCOPY SILICON TETRAMETHYL Tetramethylsilane, 99.9% Tetramethylsilicane TETRAMETHYLSILANE GAUGING SUBSTANCE FO& 四甲[單]矽烷 四甲基矽烷 TETRAMETHYLSILANE Siliciumtetramethyl TMS (silane derivative) 四甲基硅 tetramethyl-silan TETRAMETHYLSILANE, 99.9+%, NMR GRADE, A. C.S. REAGENT 四甲基硅烷 溶液 silane, tetramethyl- 四甲基硅烷 TetramethylsilaneNMRgrade TETRAMETHYLSILANE, 99.99+%, ELECTRONIC G RADE Silicon, tetramethyl- {Ch
CAS Number75-76-3
EC Number200-899-1
Beilstein Registry Number4,625
MDL NumberMFCD00008274
PubChem Substance ID87576152
Merck Number9229
Chemical Name Translation四甲基硅烷
Reaxys-RN1696908
LabNetwork Molecule IDLN00193857
InChIInChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, NMR, NMR Reference Standards,
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Others, Silicon,

产品应用

  • 用于NMR

相关文献及参考

  • Short: II/25C
  • Merck: 14,9229
  • Merck: 14,9229 Beilstein:4,625
  • Internal standard for NMR spectroscopy.
  • Short: II/2

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P241+P242+P243
  • P403+P235
Hazard statements
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSVV5706000
Packing GroupI
UN Number 2749
Hazard Codes
Storage condition 0-10 储存温度2-8℃ 0-10°C 0-6°C
Hazard Class3
Warnings 危化品目录(2015) 危险化学品

其他信息

  • Alfa Aesar:四甲基硅烷,99.9% Tetramethylsilane, 99.9%(75-76-3)
  • 用途一:用于NMR
  • MOL 文件:75-76-3.mol
  • Acros Organics:四甲基硅烷 Tetramethylsilane, 99%(75-76-3)
  • Sigma Aldrich:75-76-3(sigmaaldrich)
  • 四甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0154 四甲基硅烷[用于核磁共振] Tetramethylsilane [for NMR] 25ML 642元 2014/06/02 T0154 四甲基硅烷[用于核磁共振] Tetramethylsilane [for NMR] 500ML 5480元 2010/06/21 427331000 四甲基硅烷 Tetramethylsilane 99%, AcroSeal® 100 ML 909元
  • 图谱信息:四甲基硅烷(75-76-3)红外图谱(IR1) 四甲基硅烷(75-76-3)红外图谱(IR2)
  • MSDS 信息:四甲基硅烷(75-76-3).msds
  • F:10
  • 无色液体，易挥发。不溶于水，溶于大多数有机溶剂。
  • TCI Shanghai:四甲基硅烷[用于核磁共振] Tetramethylsilane [for NMR],>;99.0%(GC)(75-76-3)
  • 外观性质:无色液体，易挥发。
  • 下游产品:三甲基氯硅烷 --> 乙酸三甲基硅(醇)酯
  • 蒸气压:11.66 psi ( 20 °C)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. NMR - Spectroscopy
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TA - TE - T
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Silicon - CVD and ALD Precursors by Metal
  1. Analytical & Chromatography 分析化学与色谱
  2. NMR Spectrometry
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organolithium 有机锂
  4. Others Organosilicon 其他有机硅
  1. CVD & ALD Precursors
  2. Silicon

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