1-Methyl-3-P-Tolyltriazene 1-甲基-3-对甲苯三氮烯

CAS 21124-13-0 MFCD00008282

化学结构图

21124-13-0
SMILES: CC1C=CC(=CC=1)/N=N/NC

化学属性

Mol. FormulaC8H11N3
Mol. Weight149
Melting Point75-80 °C(lit.)

别名和识别编码

Chemical Name1-Methyl-3-P-Tolyltriazene
Beilstein Registry Number16,705
PubChem Substance ID87572659
CAS Number21124-13-0
EC Number244-223-3
MDL NumberMFCD00008282
Reaxys-RN1841442
Synonym 3-Methyl-1-(4-methylphenyl)triazene 3-Methyl-1-(p-tolyl)-triazene 3-甲基-1-(对甲苯基)三氮烯
Chemical Name Translation1-甲基-3-对甲苯三氮烯
Wiswesser Line Notation1MNUNR D1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Others
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Other Nitrogen Compounds
  • {SA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Others

相关文献及参考

  • Beil. 16 ,H,705
  • Fieser 1 ,696 / Fieser 2 ,282
  • Aldrich MSDS 1 , 1315:D / Corp MSDS 1 (2), 2452:A / FT-IR 1 (1), 1265:D / FT-IR 2 (2), 2143:D / FT-NMR 1 (2), 563:B / IR-Spectra (2), 667:H / IR-Spectra (3), 759:C / NMR-Reference 2 (1), 1125:D / RegBook 1 (1), 1461:C / Sax 6 , 1938 / Structure Index 1 , 228:C:4

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H228 Flammable solid 易燃固体
Hazard Codes Xn
RTECSXY2785500
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
UN Number 1325
Storage condition 0-10 0-10°C
Packing GroupII
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Hazard Class4.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 380900 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NEOLA4 Neoplasma.  (Karger-Libri, P.O. Box, CH-4009 Basel, Switzerland) V.4-
      1957-  Volume(issue)/page/year: 25,153,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   42,1446,1982

系列性分类


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