N,n,n,n-tetramethylbenzidine N,N,N',N'-四甲基联苯胺

CAS 366-29-0 MFCD00008310

化学结构图

366-29-0
SMILES: CN(C)c1ccc(-c2ccc(N(C)C)cc2)cc1

化学属性

Mol. FormulaC16H20N2
Mol. Weight240.34
Melting Point193-195 °C
Boiling Point373.06 °C at 760 mmHg

别名和识别编码

Chemical NameN,n,n,n-tetramethylbenzidine
Synonym N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N4,N4,N4',N4'-tetramethyl-[1,1'-b
MDL NumberMFCD00008310
CAS Number366-29-0
PubChem Substance ID9702
EC Number206-676-5
Chemical Name TranslationN,N,N',N'-四甲基联苯胺
Reaxys-RN1242377
Beilstein Registry Number13,221
InChIKeyYRNWIFYIFSBPAU-UHFFFAOYSA-N
LabNetwork Molecule IDLN01111944
InChIInChI=1S/C16H20N2/c1-17(2)15-9-5-13(6-10-15)14-7-11-16(12-8-14)18(3)4/h5-12H,1-4H3
Canonical SMILESCN(C)C1=CC=C(C2=CC=C(N(C)C)C=C2)C=C1
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分类

  • {SNA} Biochemicals and Reagents, Detection Substrates, ELISA Substrates, Enzyme Substrates, Enzymes, Inhibitors, and Substrates, Peroxidase, Powders
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Biochemicals and Reagents, Detection Substrates, ELISA Substrates, Enzyme Substrates, Peroxidase, Powders, 酶、抑制剂和底物
  • {SNA} Detection Substrates, ELISA Substrates, Enzyme Substrates, Peroxidase, Powders, 生化试剂, 酶、抑制剂和底物

相关文献及参考

  • Short: IV/4 Title: High-Pressure Properties of Matter Author: Beggerow, G. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/4 Year: 1980 ISBN: 3-540-09370-2 ISBN: 978-3-540-09370-1 Internet Resource: DOI:10.1007/b90280 RefComment: 589 figs., VIII, 427 pages. Hardcover Abstract: The main topics are pressure dependences of phase equilibria, compressibility, thermal and caloric properties, transport phenomena, static and magnetic properties, optical phenomena, kinetic phenomena, and systems in the neighbourhood and above the critical area.
  • Short: IV/7a Title: Liquid Crystals: One-Ring Systems and Two-Ring Systems without Bridging Groups Author: Vill, V. Editor: Thiem, J. Source: Landolt-Börnstein, New Series Volume: IV/7a Year: 1992 Keyword: organic compounds; enthaly of fusion; melting point; phase transition; liquid crystals; glass transition ISBN: 3-540-55503-X ISBN: 978-3-540-55503-2 Internet Resource: DOI:10.1007/b46098 RefComment: 10 figs., VIII, 268 pages.
  • Short: LC Title: LiqCryst 4.6 - Database of Liquid Crystals Author: Vill, V. Year: 2005 Keyword: Flüssigkristalle; LCD; Phasenumwandlung Internet Resource: http://liqcryst.chemie.uni-hamburg.de/
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSDD1752100
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 nmol/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10,263,1987

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:366-29-0(sigmaaldrich)
  • 图谱信息:N,N,N',N'-四甲基联苯胺(366-29-0)核磁图( 13 CNMR) N,N,N',N'-四甲基联苯胺(366-29-0)质谱(MS) N,N,N',N'-四甲基联苯胺(366-29-0)红外图谱(IR2) N,N,N',N'-四甲基联苯胺(366-29-0)核磁图( 1 HNMR) N,N,N',N'-四甲基联苯胺(366-29-0)红外图谱(IR1)
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • 储运特性:库房通风低温干燥
  • MOL 文件:366-29-0.mol
  • TCI Shanghai:N,N,N',N'-四甲基联苯胺 N,N,N',N'-Tetramethylbenzidine,>;98.0%(T)(366-29-0)
  • 上游原料:乙醚 --> 碳酸钾 --> 过氧化氢 --> N,N-二甲基苯胺 --> 溴化亚铜
  • Acros Organics:N,N,N',N'-四甲基联苯胺 N,N,N',N'-Tetramethylbenzidine, 97.50%(366-29-0)
  • N,N,N',N'-四甲基联苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0141 N,N,N',N'-四甲基联苯胺 N,N,N',N'-Tetramethylbenzidine 5G 1010元 2014/06/02 T0141 N,N,N',N'-四甲基联苯胺 N,N,N',N'-Tetramethylbenzidine 1G 351元 2010/06/21 138380050 N,N,N',N'-四甲基联苯胺 N,N,N',N'-Tetramethylbenzidine 97.5% 5 GR 863元
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类


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