CAS 101-61-1 MFCD00008317-4,4′-Methylenebis(N,N-Dimethylaniline) 4,4-(对二甲氨基)二苯基甲烷 -LabNovo

4,4′-Methylenebis(N,N-Dimethylaniline) 4,4-(对二甲氨基)二苯基甲烷

CAS 101-61-1 MFCD00008317

化学结构图

SMILES: CN(C)c1ccc(Cc2ccc(N(C)C)cc2)cc1

化学属性

Mol. Formula	C17H22N2
Mol. Weight	254.38
Density	1.066
Melting Point	88-89°C
Flash Point	178°(352°F)
TSCA	Yes
Boiling Point	390 °C at 760 mmHg
Solubility	不溶
Stability	对湿度敏感

别名和识别编码

Chemical Name	4,4′-Methylenebis(N,N-Dimethylaniline)
CAS Number	101-61-1
Synonym	Bis(4-(N,N-dimethylamino)phenyl)methane {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(N,N-dimethylamino)phenyl)methane {} {} {} {} {} {} {} {} {} {
EC Number	202-959-2
Beilstein Registry Number	479956
MDL Number	MFCD00008317
PubChem Substance ID	87563515
Merck Number	6176
Reaxys-RN	479956
Chemical Name Translation	4,4-(对二甲氨基)二苯基甲烷
Wiswesser Line Notation	1N1&R D1R DN1&1
LabNetwork Molecule ID	LN00193520
InChI	InChI=1S/C17H22N2/c1-18(2)16-9-5-14(6-10-16)13-15-7-11-17(12-8-15)19(3)4/h5-12H,13H2,1-4H3
Canonical SMILES	CN(C)C1=CC=C(CC2=CC=C(C=C2)N(C)C)C=C1

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产品应用

其盐酸盐作铅试剂，染料中间体，与氧化剂作用时形成深蓝色氧化物检验铅、臭氧及其他氧化剂，沉淀钨。

安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R45 May cause cancer 可能致癌
R50/53
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P308+P313
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P510

RTECSBY5250000

Hazard statements

H303 May be harmfully swallowed 吞食可能有害
H350 May cause cancer 可能致癌
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Packing GroupIII

UN Number UN3077 UN 3077 9/PG 3

Hazard Codes T,N T,N,Xi

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class6.1(b)

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7744 mg/kg/59W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Endocrine - thyroid tumors
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 72,1457,1984

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 164 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-186,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8500 mg/kg/59W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-186,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 82 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-186,1979

TYPE OF TEST

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 90,260,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to
   the National Cancer Institute by Litton Bionetics, Inc.  (Bethesda, MD)
   Volume(issue)/page/year: NCI-E-C-72-3252,1973

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 2500 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12(Suppl 13),103,1988

TYPE OF TEST            : Host-mediated assay
TEST SYSTEM             : Rodent - mouse Bacteria - Salmonella typhimurium
DOSE/DURATION           : 125 mg/kg
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 62,911,1979

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - rabbit Lymphocyte
DOSE/DURATION           : 50 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,197,1981

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 100 ug/L
REFERENCE :
   IJCNAW International Journal of Cancer.  (International Union Against
   Cancer, 3 rue du Conseil- General, 1205 Geneva, Switzerland)  V.1-    1966-
   Volume(issue)/page/year: 19,642,1977

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 5 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 97,359,1982

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211

其他信息

上游原料:乙酸 --> 甲酸 --> N,N-二甲基苯胺 --> 多聚甲醛
用途一:用作染料中间体及测定铅、锰、臭氧等的灵敏试剂
Sigma Aldrich:101-61-1(sigmaaldrich)
概述:4'4 - 四甲基二氨基二苯甲烷常温下为白色或淡蓝白色片状结晶，能升华而不分解，易溶于热醇，能溶于醚、苯、二硫化碳及酸类，不溶于水，不能随水蒸气一同挥发。
用途二:其盐酸盐作铅试剂，染料中间体，与氧化剂作用时形成深蓝色氧化物检验铅、臭氧及其他氧化剂，沉淀钨。
Alfa Aesar:4,4'-亚甲基二(N,N-二甲基苯氨),98+% 4,4'-Methylenebis(N,N-dimethylaniline), 98+%(101-61-1)
TCI Shanghai:二(4,-二甲氨基苯基)甲烷 Bis[4-(dimethylamino)phenyl]methane,>;98.0%(GC)(T)(101-61-1)
能升华而不分解。易溶于热醇，能溶于醚、苯、二硫化碳及酸类，不溶于水。
海关编码:29215990
4,4'-(对二甲氨基)二苯基甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0483 双[4-(二甲氨基)苯基]甲烷 Bis[4-(dimethylamino)phenyl]methane 25G 293元 2014/06/02 B0483 双[4-(二甲氨基)苯基]甲烷 Bis[4-(dimethylamino)phenyl]methane 500G 1460元 2010/06/21 126741000 4,4'-(对二甲氨基)二苯基甲烷 4,4'-Methylenebis(N,N-dimethylaniline) 99+% 100 GR 765元
MSDS 信息:4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1).msds
Hazard Note:Harmful/Irritant
外观性质:白色或淡蓝白色片状结晶。能升华而不分解。易溶于热醇，能溶于醚、苯、二硫化碳及酸类，不溶于水。熔点:91 °C沸点:390 °C 闪点:178 °C
图谱信息:4,4'-(对二甲氨基)二苯基甲烷(101-61-1)质谱(MS) 4,4'-(对二甲氨基)二苯基甲烷(101-61-1)核磁图( 13 CNMR) 4,4'-(对二甲氨基)二苯基甲烷(101-61-1)红外图谱(IR1) 4,4'-(对二甲氨基)二苯基甲烷(101-61-1)Raman光谱 4,4'-(对二甲氨基)二苯基甲烷(101-61-1)红外图谱(IR2) 4,4'-(对二甲氨基)二苯基甲烷(101-61-1)核磁图( 1 HNMR)
MOL 文件:101-61-1.mol
Acros Organics:4,4'-甲基双(N,N-二甲苯胺) 4,4'-Methylenebis(N,N-dimethylaniline), 99+%(101-61-1)

4,4′-Methylenebis(N,N-Dimethylaniline) 4,4-(对二甲氨基)二苯基甲烷

CAS 101-61-1 MFCD00008317

化学结构图

化学属性

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化学结构图

化学属性

别名和识别编码

分类

产品应用

相关文献及参考

安全信息

其他信息

系列性分类

相关产品推荐

Products Indices

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